Photochemical reactions of metal carbonyls [M(CO)6 (M=Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)

Ozan Sanli Şentürk; Ümmühan Özdemir; Sema Sert; Nurcan Karacan; Fadime Uǧur

doi:10.1080/00958970600857029

Photochemical reactions of metal carbonyls [M(CO)₆ (M=Cr, Mo, W), Re(CO)₅Br, Mn(CO)₃Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)

Ozan Sanli Şentürk^*
, Ümmühan Özdemir
, Sema Sert
, Nurcan Karacan
, Fadime Uǧur

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Gazi University
Ege University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

31 Atıf (Scopus)

Özet

The new complexes, M(CO)₅(Hsalesh) (M∈=∈Cr (1), Mo (2), W (3)), Re(CO)₄Br(Hsalesh) (4) and Mn(CO)₃(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)₆ (M∈=∈Cr, Mo, W), Re(CO)₅Br, and Mn(CO)₃Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and ¹H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)₅(Hsalesh) (M∈=∈Cr, Mo, W) and Re(CO)₄Br(Hsalesh) and as a tridentate ligand in Mn(CO) ₃(salesh).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	229-235
Sayfa sayısı	7
Dergi	Journal of Coordination Chemistry
Hacim	60
Basın numarası	2
DOI'lar	https://doi.org/10.1080/00958970600857029
Yayın durumu	Yayınlandı - 20 Oca 2007

Finansman

This research was supported by Gazi University Research Found under Project No. 05-98/24. We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege. We thank TUBITAK_ for allocation of time at the NMR, mass spectra and elemental analyses.

Finansörler	Finansör numarası
Gazi University Research Found	05-98/24

Belgeye Erişim

10.1080/00958970600857029

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{20459da3eba044bbadf405994bdc4e87,

title = "Photochemical reactions of metal carbonyls [M(CO)6 (M=Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)",

abstract = "The new complexes, M(CO)5(Hsalesh) (M∈=∈Cr (1), Mo (2), W (3)), Re(CO)4Br(Hsalesh) (4) and Mn(CO)3(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M∈=∈Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)5(Hsalesh) (M∈=∈Cr, Mo, W) and Re(CO)4Br(Hsalesh) and as a tridentate ligand in Mn(CO) 3(salesh).",

keywords = "Hydrazone, Metal carbonyls, Salicylaldehyde ethanesulfonylhydrazone",

author = "{\c S}ent{\"u}rk, \{Ozan Sanli\} and {\"U}mm{\"u}han {\"O}zdemir and Sema Sert and Nurcan Karacan and Fadime Uǧur",

year = "2007",

month = jan,

day = "20",

doi = "10.1080/00958970600857029",

language = "English",

volume = "60",

pages = "229--235",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

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TY - JOUR

T1 - Photochemical reactions of metal carbonyls [M(CO)6 (M=Cr, Mo, W), Re(CO)5Br, Mn(CO)3Cp] with salicylaldehyde ethanesulfonylhydrazone (Hsalesh)

AU - Şentürk, Ozan Sanli

AU - Özdemir, Ümmühan

AU - Sert, Sema

AU - Karacan, Nurcan

AU - Uǧur, Fadime

PY - 2007/1/20

Y1 - 2007/1/20

N2 - The new complexes, M(CO)5(Hsalesh) (M∈=∈Cr (1), Mo (2), W (3)), Re(CO)4Br(Hsalesh) (4) and Mn(CO)3(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M∈=∈Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)5(Hsalesh) (M∈=∈Cr, Mo, W) and Re(CO)4Br(Hsalesh) and as a tridentate ligand in Mn(CO) 3(salesh).

AB - The new complexes, M(CO)5(Hsalesh) (M∈=∈Cr (1), Mo (2), W (3)), Re(CO)4Br(Hsalesh) (4) and Mn(CO)3(Hsalesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)6 (M∈=∈Cr, Mo, W), Re(CO)5Br, and Mn(CO)3Cp with salicylaldehyde ethanesulfonyl hydrazone (Hsalesh). The complexes have been characterized by elemental analysis, EI mass spectrometry, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that Hsalesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)5(Hsalesh) (M∈=∈Cr, Mo, W) and Re(CO)4Br(Hsalesh) and as a tridentate ligand in Mn(CO) 3(salesh).

KW - Hydrazone

KW - Metal carbonyls

KW - Salicylaldehyde ethanesulfonylhydrazone

UR - https://www.scopus.com/pages/publications/33845743016

U2 - 10.1080/00958970600857029

DO - 10.1080/00958970600857029

M3 - Article

AN - SCOPUS:33845743016

SN - 0095-8972

VL - 60

SP - 229

EP - 235

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 2

ER -