Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

Elif Subasi; Hamdi Temel; Ozan S. Senturk; Fadime Ugur

doi:10.1080/00958970600571703

Photochemical reactions of metal carbonyls [M(CO)₆ (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

Elif Subasi^*, Hamdi Temel, Ozan S. Senturk, Fadime Ugur

^*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

11 Atıf (Scopus)

Özet

The complexes [M(CO)₄(η²-H₂L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)₆] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H₂L) in THF and characterized by elemental analyses, FTIR, ¹H NMR and mass spectra. The H₂L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1807-1811
Sayfa sayısı	5
Dergi	Journal of Coordination Chemistry
Hacim	59
Basın numarası	16
DOI'lar	https://doi.org/10.1080/00958970600571703
Yayın durumu	Yayınlandı - 10 Kas 2006
Harici olarak yayınlandı	Evet

Finansman

We thank BP (Turkey) for the provision of photochemical apparatus and the Research Foundation of Dokuz Eylul, Ege and Dicle Universities for funding. We thank EBILTEM_ and TUBITAK_ for allocation of time for recording NMR and mass spectra, and elemental analyses.

Finansörler	Finansör numarası
BP

Belgeye Erişim

10.1080/00958970600571703

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane",

abstract = "The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.",

keywords = "Metal carbonyls, N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane, Schiff base",

author = "Elif Subasi and Hamdi Temel and Senturk, {Ozan S.} and Fadime Ugur",

year = "2006",

month = nov,

day = "10",

doi = "10.1080/00958970600571703",

language = "English",

volume = "59",

pages = "1807--1811",

journal = "Journal of Coordination Chemistry",

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TY - JOUR

T1 - Photochemical reactions of metal carbonyls [M(CO)6 (M = Cr, Mo, W)] with N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

AU - Subasi, Elif

AU - Temel, Hamdi

AU - Senturk, Ozan S.

AU - Ugur, Fadime

PY - 2006/11/10

Y1 - 2006/11/10

N2 - The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.

AB - The complexes [M(CO)4(η2-H2L)] [M = Cr; 1, Mo; 2, W; 3] have been synthesized by photochemical reactions of VIB metal carbonyls [M(CO)6] [M = Cr, Mo, W] with N,N′- bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane (H2L) in THF and characterized by elemental analyses, FTIR, 1H NMR and mass spectra. The H2L ligand is coordinated to the central metal as a bidentate ligand via the central azomethine nitrogen atoms in 1-3.

KW - Metal carbonyls

KW - N,N′-bis(salicylidene)-1,2-bis-(o-aminophenoxy)ethane

KW - Schiff base

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DO - 10.1080/00958970600571703

M3 - Article

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