Photochemical complexation reactions of M(CO)6 (M=Cr, Mo, W) and Re(CO)5Br with rhodanine (4-thiazolidinone-2-thioxo) and 5-substituted rhodanines

Elif Subasi; Ayse Ercag; Sema Sert; Ozan S. Senturk

doi:10.1080/15533170601028116

Photochemical complexation reactions of M(CO)₆ (M=Cr, Mo, W) and Re(CO)₅Br with rhodanine (4-thiazolidinone-2-thioxo) and 5-substituted rhodanines

Elif Subasi^*
, Ayse Ercag
, Sema Sert
, Ozan S. Senturk

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Dokuz Eylul University
Istanbul University
Ege University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

16 Atıf (Scopus)

Özet

The new complexes [M(CO)₅-DABRd] [M=Cr; 1, Mo; 2, W; 3], [cis-Re(CO)₄Br-DABRd] (4), [M(CO)₅-BRd] [M=Cr; 5, Mo; 6, W; 7] and [Mo(CO)₅-L] [L=Rd, 8; 2CBRd, 9; 2HNARd, 10; IBRd, 11] have been synthesized by the photochemical reactions of VIB and VIIB group metal carbonyls [M(CO)₆] [M=Cr, Mo, W] and [Re(CO)₅Br] with 5-(4-dimethylaminobenzylidene)rhodanine (DABRd), 5-benzylidenerhodanine (BRd), rhodanine (Rd), 5-(2-chlorobenzylidene)rhodanine (2CBRd), 5-(2- hydroxynaphtylidene)rhodanine (2HNARd), 5-(4-isopropylbenzylidene)rhodanine (IBRd) and characterized by elemental analysis, FT-IR, ¹H and ¹³C-{¹H}-NMR spectroscopy and by Mass spectrometry. The spectroscopic studies show that all rhodanine ligands act as monodentate ligands coordinating via the sulfur (CS) donor atom in (1-11).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	705-711
Sayfa sayısı	7
Dergi	Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
Hacim	36
Basın numarası	10
DOI'lar	https://doi.org/10.1080/15533170601028116
Yayın durumu	Yayınlandı - 1 Ara 2006

Finansman

We thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege and Dokuz Eylul University for funds. We thank TUBITAK for allocation of time at the Mass Spectra and Elemental Analyses. We thank Dr. Yurdanur Yayla for obtaining 1Hand 13C-f1Hg-NMR. spectra at Ege University. This work also supported by Research Fund of Istanbul University, Project Number: 818/190496, and Dokuz Eylul University, Project Number: 04.KB.FEN.106.

Finansörler	Finansör numarası
Research Foundation of Ege and Dokuz Eylul University
BP
Istanbul Üniversitesi	818/190496
Dokuz Eylül Üniversitesi	KB.FEN.106

Belgeye Erişim

10.1080/15533170601028116

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{c2dd6addb9504d45a209527e152f96f7,

title = "Photochemical complexation reactions of M(CO)6 (M=Cr, Mo, W) and Re(CO)5Br with rhodanine (4-thiazolidinone-2-thioxo) and 5-substituted rhodanines",

abstract = "The new complexes [M(CO)5-DABRd] [M=Cr; 1, Mo; 2, W; 3], [cis-Re(CO)4Br-DABRd] (4), [M(CO)5-BRd] [M=Cr; 5, Mo; 6, W; 7] and [Mo(CO)5-L] [L=Rd, 8; 2CBRd, 9; 2HNARd, 10; IBRd, 11] have been synthesized by the photochemical reactions of VIB and VIIB group metal carbonyls [M(CO)6] [M=Cr, Mo, W] and [Re(CO)5Br] with 5-(4-dimethylaminobenzylidene)rhodanine (DABRd), 5-benzylidenerhodanine (BRd), rhodanine (Rd), 5-(2-chlorobenzylidene)rhodanine (2CBRd), 5-(2- hydroxynaphtylidene)rhodanine (2HNARd), 5-(4-isopropylbenzylidene)rhodanine (IBRd) and characterized by elemental analysis, FT-IR, 1H and 13C-\{1H\}-NMR spectroscopy and by Mass spectrometry. The spectroscopic studies show that all rhodanine ligands act as monodentate ligands coordinating via the sulfur (CS) donor atom in (1-11).",

keywords = "5-benzylidenerhodanines, Metal carbonyl complexes, Organometallic compounds, Rhodanine (4-thiazolidinone-2-thioxo)",

author = "Elif Subasi and Ayse Ercag and Sema Sert and Senturk, \{Ozan S.\}",

year = "2006",

month = dec,

day = "1",

doi = "10.1080/15533170601028116",

language = "English",

volume = "36",

pages = "705--711",

journal = "Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry",

issn = "1553-3174",

number = "10",

}

Photochemical complexation reactions of M(CO)₆ (M=Cr, Mo, W) and Re(CO)₅Br with rhodanine (4-thiazolidinone-2-thioxo) and 5-substituted rhodanines. / Subasi, Elif; Ercag, Ayse; Sert, Sema et al.
In: Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, Hac. 36, No. 10, 01.12.2006, p. 705-711.

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

TY - JOUR

T1 - Photochemical complexation reactions of M(CO)6 (M=Cr, Mo, W) and Re(CO)5Br with rhodanine (4-thiazolidinone-2-thioxo) and 5-substituted rhodanines

AU - Subasi, Elif

AU - Ercag, Ayse

AU - Sert, Sema

AU - Senturk, Ozan S.

PY - 2006/12/1

Y1 - 2006/12/1

N2 - The new complexes [M(CO)5-DABRd] [M=Cr; 1, Mo; 2, W; 3], [cis-Re(CO)4Br-DABRd] (4), [M(CO)5-BRd] [M=Cr; 5, Mo; 6, W; 7] and [Mo(CO)5-L] [L=Rd, 8; 2CBRd, 9; 2HNARd, 10; IBRd, 11] have been synthesized by the photochemical reactions of VIB and VIIB group metal carbonyls [M(CO)6] [M=Cr, Mo, W] and [Re(CO)5Br] with 5-(4-dimethylaminobenzylidene)rhodanine (DABRd), 5-benzylidenerhodanine (BRd), rhodanine (Rd), 5-(2-chlorobenzylidene)rhodanine (2CBRd), 5-(2- hydroxynaphtylidene)rhodanine (2HNARd), 5-(4-isopropylbenzylidene)rhodanine (IBRd) and characterized by elemental analysis, FT-IR, 1H and 13C-{1H}-NMR spectroscopy and by Mass spectrometry. The spectroscopic studies show that all rhodanine ligands act as monodentate ligands coordinating via the sulfur (CS) donor atom in (1-11).

AB - The new complexes [M(CO)5-DABRd] [M=Cr; 1, Mo; 2, W; 3], [cis-Re(CO)4Br-DABRd] (4), [M(CO)5-BRd] [M=Cr; 5, Mo; 6, W; 7] and [Mo(CO)5-L] [L=Rd, 8; 2CBRd, 9; 2HNARd, 10; IBRd, 11] have been synthesized by the photochemical reactions of VIB and VIIB group metal carbonyls [M(CO)6] [M=Cr, Mo, W] and [Re(CO)5Br] with 5-(4-dimethylaminobenzylidene)rhodanine (DABRd), 5-benzylidenerhodanine (BRd), rhodanine (Rd), 5-(2-chlorobenzylidene)rhodanine (2CBRd), 5-(2- hydroxynaphtylidene)rhodanine (2HNARd), 5-(4-isopropylbenzylidene)rhodanine (IBRd) and characterized by elemental analysis, FT-IR, 1H and 13C-{1H}-NMR spectroscopy and by Mass spectrometry. The spectroscopic studies show that all rhodanine ligands act as monodentate ligands coordinating via the sulfur (CS) donor atom in (1-11).

KW - 5-benzylidenerhodanines

KW - Metal carbonyl complexes

KW - Organometallic compounds

KW - Rhodanine (4-thiazolidinone-2-thioxo)

UR - https://www.scopus.com/pages/publications/33845328064

U2 - 10.1080/15533170601028116

DO - 10.1080/15533170601028116

M3 - Article

AN - SCOPUS:33845328064

SN - 1553-3174

VL - 36

SP - 705

EP - 711

JO - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

JF - Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry

IS - 10

ER -