TY - JOUR
T1 - Oxidative polymerization of pyrrole in polymer matrix
AU - Saraç, A. Sezai
AU - Ustamehmetoǧlu, Belkis
AU - Mustafaev, Mamed I.
AU - Erbil, Candan
AU - Uzelli, Gülay
PY - 1995/7/30
Y1 - 1995/7/30
N2 - The oxidative matrix polymerization of pyrrole (Py) by Ce(IV) in the presence of Polyacrylic acid (PAA) has been studied to obtain water‐soluble and insoluble products. The role of the PAA, Pyrrole, and Ce(IV) concentration, order of component addition, the structure of polymer matrix (PAA, Hydroxy Ethyl Cellulose (HES), Poly‐N‐vinylpyrrolidone (PVP)], and model unit of PAA (propionic acid), on the polymerization system were investigated. Interaction of PAA with insoluble polypyrrole (PPy) and the interpolymer complex formation were investigated along with the aggregation of PPy onto the matrix polymer followed by spectral shifts. FTIR results of insoluble products obtained from the PAA–Py–Ce(IV) system and solubility of the system is explained in light of the mechanism of the polymerization of pyrrole on the polymer matrix. © 1995 John Wiley & Sons, Inc.
AB - The oxidative matrix polymerization of pyrrole (Py) by Ce(IV) in the presence of Polyacrylic acid (PAA) has been studied to obtain water‐soluble and insoluble products. The role of the PAA, Pyrrole, and Ce(IV) concentration, order of component addition, the structure of polymer matrix (PAA, Hydroxy Ethyl Cellulose (HES), Poly‐N‐vinylpyrrolidone (PVP)], and model unit of PAA (propionic acid), on the polymerization system were investigated. Interaction of PAA with insoluble polypyrrole (PPy) and the interpolymer complex formation were investigated along with the aggregation of PPy onto the matrix polymer followed by spectral shifts. FTIR results of insoluble products obtained from the PAA–Py–Ce(IV) system and solubility of the system is explained in light of the mechanism of the polymerization of pyrrole on the polymer matrix. © 1995 John Wiley & Sons, Inc.
KW - chemical synthesis
KW - interpolymer complex
KW - matrix polymerization
KW - polypyrrole
KW - water soluble polypyrrole
UR - http://www.scopus.com/inward/record.url?scp=0003377804&partnerID=8YFLogxK
U2 - 10.1002/pola.1995.080331004
DO - 10.1002/pola.1995.080331004
M3 - Article
AN - SCOPUS:0003377804
SN - 0887-624X
VL - 33
SP - 1581
EP - 1587
JO - Journal of Polymer Science, Part A: Polymer Chemistry
JF - Journal of Polymer Science, Part A: Polymer Chemistry
IS - 10
ER -