Oxidative copolymerization of pyrrole and N-methyl pyrrole

Belkis Ustamehmetoǧlu; Eda Kelleboz; A. Sezai Saraç

doi:10.1080/10236660304882

Oxidative copolymerization of pyrrole and N-methyl pyrrole

Belkis Ustamehmetoǧlu^*
, Eda Kelleboz
, A. Sezai Saraç

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma çıktısı: Dergi yayını › Makale › Hakem

11 Atıf (Scopus)

Özet

Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10^-4-10^-2 S cm^-1. Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole]^0.87 [N-methyl pyrrole]^0.06 [CAN]^0.11 [H₂SO₄]^1.28 from gravimetric determination.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	255-268
Sayfa sayısı	14
Dergi	International Journal of Polymer Analysis and Characterization
Hacim	8
Basın numarası	4
DOI'lar	https://doi.org/10.1080/10236660304882
Yayın durumu	Yayınlandı - Tem 2003

Belgeye Erişim

10.1080/10236660304882

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Link to publication in Scopus

Alıntı Yap

@article{c1eacfc46e4d4ef292eba50421be5b84,

title = "Oxidative copolymerization of pyrrole and N-methyl pyrrole",

abstract = "Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10-4-10-2 S cm-1. Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole]0.87 [N-methyl pyrrole]0.06 [CAN]0.11 [H2SO4]1.28 from gravimetric determination.",

keywords = "Ceric salt, Chemical polymerization, Copolymerization of pyrrole and N-methyl pyrrole",

author = "Belkis Ustamehmetoǧlu and Eda Kelleboz and Sara{\c c}, \{A. Sezai\}",

year = "2003",

month = jul,

doi = "10.1080/10236660304882",

language = "English",

volume = "8",

pages = "255--268",

journal = "International Journal of Polymer Analysis and Characterization",

issn = "1023-666X",

publisher = "Taylor and Francis Ltd.",

number = "4",

}

TY - JOUR

T1 - Oxidative copolymerization of pyrrole and N-methyl pyrrole

AU - Ustamehmetoǧlu, Belkis

AU - Kelleboz, Eda

AU - Saraç, A. Sezai

PY - 2003/7

Y1 - 2003/7

N2 - Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10-4-10-2 S cm-1. Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole]0.87 [N-methyl pyrrole]0.06 [CAN]0.11 [H2SO4]1.28 from gravimetric determination.

AB - Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10-4-10-2 S cm-1. Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole]0.87 [N-methyl pyrrole]0.06 [CAN]0.11 [H2SO4]1.28 from gravimetric determination.

KW - Ceric salt

KW - Chemical polymerization

KW - Copolymerization of pyrrole and N-methyl pyrrole

UR - https://www.scopus.com/pages/publications/0141519113

U2 - 10.1080/10236660304882

DO - 10.1080/10236660304882

M3 - Article

AN - SCOPUS:0141519113

SN - 1023-666X

VL - 8

SP - 255

EP - 268

JO - International Journal of Polymer Analysis and Characterization

JF - International Journal of Polymer Analysis and Characterization

IS - 4

ER -

Oxidative copolymerization of pyrrole and N-methyl pyrrole

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