Özet
Aliphatic polycarbonate (PC) copolymer is synthesized by ring opening copolymerization of acrylate- and allyl-functional cyclic carbonate monomers. The post-polymerization functionalization of the resulting copolymer is performed quantitatively using a variety of thiol compounds via sequential Michael addition and photo-induced radical thiol-ene click reactions within relatively short reaction time at ambient temperature. This metal-free click chemistry methodology affords the synthesis of biocompatible PC copolymer with multifunctional groups.
Orijinal dil | İngilizce |
---|---|
Sayfa (başlangıç-bitiş) | 1581-1587 |
Sayfa sayısı | 7 |
Dergi | Journal of Polymer Science, Part A: Polymer Chemistry |
Hacim | 52 |
Basın numarası | 11 |
DOI'lar | |
Yayın durumu | Yayınlandı - 1 Haz 2014 |