One-pot synthesis of poly(triazole-graft-caprolactone) via ring-opening polymerization combined with click chemistry as a novel strategy for graft copolymers

Fusun Seyma Gungor, Baris Kiskan*

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Araştırma sonucu: ???type-name???Makalebilirkişi

22 Atıf (Scopus)

Özet

The one-pot construction of polytriazole grafted with poly(ε- caprolactone) via the polymerization of 4-azido-1-(prop-2-yn-1-yloxy)butan-2-ol (N3hydroxypropargyl) and ε-caprolactone monomers is reported. For this purpose, a click reaction and ring-opening polymerization (ROP) were combined and carried out simultaneously. N3hydroxypropargyl served as both the ROP initiator and a monomer for the click polymerization. Thus, an in situ "grafting-through and from" strategy was established in one pot. CuBr and Sn(Oct)2 were utilized as dual catalysts, and the polymerization reactions were carried out at 120 C under a N2 atmosphere.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)51-55
Sayfa sayısı5
DergiReactive and Functional Polymers
Hacim75
Basın numarası1
DOI'lar
Yayın durumuYayınlandı - Şub 2014

Finansman

The authors thank to Istanbul Technical University Research Fund for financial support (Project No. 36167 ) and Prof. Dr. Yusuf Yagci for providing infrastructure.

FinansörlerFinansör numarası
Istanbul Teknik Üniversitesi36167

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