One-pot synthesis of amide-functional main-chain polybenzoxazine precursors

Canan Durukan; Baris Kiskan; Yusuf Yagci

doi:10.3390/polym11040679

One-pot synthesis of amide-functional main-chain polybenzoxazine precursors

Canan Durukan, Baris Kiskan^*, Yusuf Yagci

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

19 Atıf (Scopus)

Özet

Main-chain polybenzoxazines containing amide linkages were successfully prepared in one pot. Three different polymers were synthesized by reacting 3,4-dihydrocoumarine (DHC) and paraformaldehyde with 1,3-diaminopropane or 1,6-diaminohexane or Jeffamine ED-900. The one-pot reaction proceeded through the combination of the ring-opening of DHC with amines, and subsequent Mannich and ring-closure reactions occurring in a cascading manner. The obtained polymer from Jeffamine exhibited good film-forming properties, and free-standing flexible films were easily solventcasted on Teflon plates. All polymeric precursors were characterized by spectroscopic analysis, and their curing behavior and thermal stability were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).

Orijinal dil	İngilizce
Makale numarası	679
Dergi	Polymers
Hacim	11
Basın numarası	4
DOI'lar	https://doi.org/10.3390/polym11040679
Yayın durumu	Yayınlandı - 1 Nis 2019

Bibliyografik not

Publisher Copyright:
© 2019 by the authors.

Finansman

Funding: This research was funded by Istanbul Technical University Research Fund, project ID: TGA-2018-41502.

Finansörler	Finansör numarası
Istanbul Technical University Research Fund	TGA-2018-41502

Belgeye Erişim

10.3390/polym11040679

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "One-pot synthesis of amide-functional main-chain polybenzoxazine precursors",

abstract = "Main-chain polybenzoxazines containing amide linkages were successfully prepared in one pot. Three different polymers were synthesized by reacting 3,4-dihydrocoumarine (DHC) and paraformaldehyde with 1,3-diaminopropane or 1,6-diaminohexane or Jeffamine ED-900. The one-pot reaction proceeded through the combination of the ring-opening of DHC with amines, and subsequent Mannich and ring-closure reactions occurring in a cascading manner. The obtained polymer from Jeffamine exhibited good film-forming properties, and free-standing flexible films were easily solventcasted on Teflon plates. All polymeric precursors were characterized by spectroscopic analysis, and their curing behavior and thermal stability were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).",

keywords = "Benzoxazine, Dihydrocoumarine, Polyamide, Polybenzoxazine, Ring-opening polymerization",

author = "Canan Durukan and Baris Kiskan and Yusuf Yagci",

note = "Publisher Copyright: {\textcopyright} 2019 by the authors.",

year = "2019",

month = apr,

day = "1",

doi = "10.3390/polym11040679",

language = "English",

volume = "11",

journal = "Polymers",

issn = "2073-4360",

publisher = "Multidisciplinary Digital Publishing Institute (MDPI)",

number = "4",

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TY - JOUR

T1 - One-pot synthesis of amide-functional main-chain polybenzoxazine precursors

AU - Durukan, Canan

AU - Kiskan, Baris

AU - Yagci, Yusuf

PY - 2019/4/1

Y1 - 2019/4/1

N2 - Main-chain polybenzoxazines containing amide linkages were successfully prepared in one pot. Three different polymers were synthesized by reacting 3,4-dihydrocoumarine (DHC) and paraformaldehyde with 1,3-diaminopropane or 1,6-diaminohexane or Jeffamine ED-900. The one-pot reaction proceeded through the combination of the ring-opening of DHC with amines, and subsequent Mannich and ring-closure reactions occurring in a cascading manner. The obtained polymer from Jeffamine exhibited good film-forming properties, and free-standing flexible films were easily solventcasted on Teflon plates. All polymeric precursors were characterized by spectroscopic analysis, and their curing behavior and thermal stability were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).

AB - Main-chain polybenzoxazines containing amide linkages were successfully prepared in one pot. Three different polymers were synthesized by reacting 3,4-dihydrocoumarine (DHC) and paraformaldehyde with 1,3-diaminopropane or 1,6-diaminohexane or Jeffamine ED-900. The one-pot reaction proceeded through the combination of the ring-opening of DHC with amines, and subsequent Mannich and ring-closure reactions occurring in a cascading manner. The obtained polymer from Jeffamine exhibited good film-forming properties, and free-standing flexible films were easily solventcasted on Teflon plates. All polymeric precursors were characterized by spectroscopic analysis, and their curing behavior and thermal stability were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA).

KW - Benzoxazine

KW - Dihydrocoumarine

KW - Polyamide

KW - Polybenzoxazine

KW - Ring-opening polymerization

UR - http://www.scopus.com/inward/record.url?scp=85065910594&partnerID=8YFLogxK

U2 - 10.3390/polym11040679

DO - 10.3390/polym11040679

M3 - Article

AN - SCOPUS:85065910594

SN - 2073-4360

VL - 11

JO - Polymers

JF - Polymers

IS - 4

M1 - 679

ER -

One-pot synthesis of amide-functional main-chain polybenzoxazine precursors

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap