New phthalocyanines bearing tetra(hydroxyethylthio) functionalities

Ibrahim Özceşmeci; Ali Ihsan Okur; Ahmet Gül

doi:10.1016/j.dyepig.2006.08.003

New phthalocyanines bearing tetra(hydroxyethylthio) functionalities

Ibrahim Özceşmeci
, Ali Ihsan Okur
, Ahmet Gül^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

51 Atıf (Scopus)

Özet

Zn(II), Co(II), Ni(II) and metal-free phthalocyanines (2-5) bearing a hydroxyethylthio substituent on each benzo group were prepared from 4-(hydroxyethylthio)phthalonitrile (1) and the corresponding divalent metal salt. The reactivity of the hydroxyethyl groups was demonstrated by esterification of phthalocyanine derivatives (2-5) with acetic anhydride at reflux temperature and acetylated phthalocyanine compounds (6-9) were obtained. The new compounds have been characterized by elemental analyses, IR, UV-vis, mass and ¹H NMR spectroscopy.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	761-765
Sayfa sayısı	5
Dergi	Dyes and Pigments
Hacim	75
Basın numarası	3
DOI'lar	https://doi.org/10.1016/j.dyepig.2006.08.003
Yayın durumu	Yayınlandı - 2007

Finansman

This work was supported by the Research Fund of the Technical University of İstanbul and State Planning Organization (DPT). A.G. is grateful to Alexander von Humboldt Foundation for a senior scientist award renewed in 2006 for studies in the laboratory of Professor Markus Albrecht, Institute of Organic Chemistry, RWTH-Aachen, Aachen, Germany.

Finansörler
DPT
Devlet Planlama Örgütü
Istanbul Teknik Üniversitesi

Belgeye Erişim

10.1016/j.dyepig.2006.08.003

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{2d7c5f0d3f9740e79dc1a74a6af5a2b1,

title = "New phthalocyanines bearing tetra(hydroxyethylthio) functionalities",

abstract = "Zn(II), Co(II), Ni(II) and metal-free phthalocyanines (2-5) bearing a hydroxyethylthio substituent on each benzo group were prepared from 4-(hydroxyethylthio)phthalonitrile (1) and the corresponding divalent metal salt. The reactivity of the hydroxyethyl groups was demonstrated by esterification of phthalocyanine derivatives (2-5) with acetic anhydride at reflux temperature and acetylated phthalocyanine compounds (6-9) were obtained. The new compounds have been characterized by elemental analyses, IR, UV-vis, mass and 1H NMR spectroscopy.",

keywords = "Cobalt, Esterification, Nickel, Phthalocyanine, Zinc",

author = "Ibrahim {\"O}zce{\c s}meci and Okur, \{Ali Ihsan\} and Ahmet G{\"u}l",

year = "2007",

doi = "10.1016/j.dyepig.2006.08.003",

language = "English",

volume = "75",

pages = "761--765",

journal = "Dyes and Pigments",

issn = "0143-7208",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - New phthalocyanines bearing tetra(hydroxyethylthio) functionalities

AU - Özceşmeci, Ibrahim

AU - Okur, Ali Ihsan

AU - Gül, Ahmet

PY - 2007

Y1 - 2007

N2 - Zn(II), Co(II), Ni(II) and metal-free phthalocyanines (2-5) bearing a hydroxyethylthio substituent on each benzo group were prepared from 4-(hydroxyethylthio)phthalonitrile (1) and the corresponding divalent metal salt. The reactivity of the hydroxyethyl groups was demonstrated by esterification of phthalocyanine derivatives (2-5) with acetic anhydride at reflux temperature and acetylated phthalocyanine compounds (6-9) were obtained. The new compounds have been characterized by elemental analyses, IR, UV-vis, mass and 1H NMR spectroscopy.

AB - Zn(II), Co(II), Ni(II) and metal-free phthalocyanines (2-5) bearing a hydroxyethylthio substituent on each benzo group were prepared from 4-(hydroxyethylthio)phthalonitrile (1) and the corresponding divalent metal salt. The reactivity of the hydroxyethyl groups was demonstrated by esterification of phthalocyanine derivatives (2-5) with acetic anhydride at reflux temperature and acetylated phthalocyanine compounds (6-9) were obtained. The new compounds have been characterized by elemental analyses, IR, UV-vis, mass and 1H NMR spectroscopy.

KW - Cobalt

KW - Esterification

KW - Nickel

KW - Phthalocyanine

KW - Zinc

UR - https://www.scopus.com/pages/publications/34249820525

U2 - 10.1016/j.dyepig.2006.08.003

DO - 10.1016/j.dyepig.2006.08.003

M3 - Article

AN - SCOPUS:34249820525

SN - 0143-7208

VL - 75

SP - 761

EP - 765

JO - Dyes and Pigments

JF - Dyes and Pigments

IS - 3

ER -

New phthalocyanines bearing tetra(hydroxyethylthio) functionalities

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap