Naphthodioxinone-1,3-benzodioxole as photochemically masked one-component type II photoinitiator for free radical polymerization

Volkan Kumbaraci, Binnur Aydogan, Naciye Talinli*, Yusuf Yagci

*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: ???type-name???Makalebilirkişi

51 Atıf (Scopus)

Özet

A 1,3-benzodioxole derivative of naphthodioxinone, namely 2-(benzo[d][1,3]dioxol-5-yl)-9-hydroxy-2-phenyl-4H-naphtho[2,3-d][1,3] dioxin-4-one was synthesized and characterized. Its capability to act as caged one-component Type II photoinitiator for free radical polymerization was examined. Upon irradiation, this photoinitiator releases 5-benzoyl-1,3- benzodioxole possessing both benzophenone and 1,3-dioxole groups in the structure as light absorbing and hydrogen donating sites, respectively. Subsequent photoexcitation of the benzophenone chromophore followed by hydrogen abstraction generates radicals capable of initiating free radical polymerization of appropriate monomers.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)2612-2618
Sayfa sayısı7
DergiJournal of Polymer Science, Part A: Polymer Chemistry
Hacim50
Basın numarası13
DOI'lar
Yayın durumuYayınlandı - 1 Tem 2012

Parmak izi

Naphthodioxinone-1,3-benzodioxole as photochemically masked one-component type II photoinitiator for free radical polymerization' araştırma başlıklarına git. Birlikte benzersiz bir parmak izi oluştururlar.

Alıntı Yap