Multiarm star polymers with POSS at the periphery

Eda Gungor; Cigdem Bilir; Gurkan Hizal; Umit Tunca

doi:10.1002/pola.24275

Multiarm star polymers with POSS at the periphery

Eda Gungor
, Cigdem Bilir
, Gurkan Hizal
, Umit Tunca^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

15 Atıf (Scopus)

Özet

Azide end-functionalized polyhedral oligomeric silsesquioxane (POSS-N ₃) was incorporated into the periphery of well-defined alkyne-polystyrene₅₀-poly(divinyl benzene) (alkyne-PS ₅₀-polyDVB) and alkyne-poly(tert-butyl acrylate)₄₃- poly(divinyl benzene) (alkyne-PtBA₄₃-polyDVB) multiarm star polymers via highly efficient azide-alkyne click reaction, resulting in POSS-PS ₅₀-polyDVB and POSS-PtBA₄₃-polyDVB multiarm star block copolymers respectively, in the solution of tetrahydrofuran/N,N-dimethyl formamide, CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA) at room temperature for 24 h. Linear precursors and star polymers obtained in this study were characterized ¹H NMR, gel permeation chromatography (GPC), and triple detection GPC (TD-GPC). Absolute molecular weight, hydrodynamic radius, and intrinsic viscosity ([η]) values for all star polymers were determined by TD-GPC.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	4835-4841
Sayfa sayısı	7
Dergi	Journal of Polymer Science, Part A: Polymer Chemistry
Hacim	48
Basın numarası	21
DOI'lar	https://doi.org/10.1002/pola.24275
Yayın durumu	Yayınlandı - 1 Kas 2010

Belgeye Erişim

10.1002/pola.24275

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{0331f071bb774bb191214970ec1f6e8e,

title = "Multiarm star polymers with POSS at the periphery",

abstract = "Azide end-functionalized polyhedral oligomeric silsesquioxane (POSS-N 3) was incorporated into the periphery of well-defined alkyne-polystyrene50-poly(divinyl benzene) (alkyne-PS 50-polyDVB) and alkyne-poly(tert-butyl acrylate)43- poly(divinyl benzene) (alkyne-PtBA43-polyDVB) multiarm star polymers via highly efficient azide-alkyne click reaction, resulting in POSS-PS 50-polyDVB and POSS-PtBA43-polyDVB multiarm star block copolymers respectively, in the solution of tetrahydrofuran/N,N-dimethyl formamide, CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA) at room temperature for 24 h. Linear precursors and star polymers obtained in this study were characterized 1H NMR, gel permeation chromatography (GPC), and triple detection GPC (TD-GPC). Absolute molecular weight, hydrodynamic radius, and intrinsic viscosity ([η]) values for all star polymers were determined by TD-GPC.",

keywords = "azide-alkyne click reaction, hydrodynamic radius, intrinsic viscosity, living radical polymerization, multiarm star polymer, poly(tert-butyl acrylate), polystyrene, POSS, star polymers, triple detection GPC",

author = "Eda Gungor and Cigdem Bilir and Gurkan Hizal and Umit Tunca",

year = "2010",

month = nov,

day = "1",

doi = "10.1002/pola.24275",

language = "English",

volume = "48",

pages = "4835--4841",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley \& Sons Inc.",

number = "21",

}

TY - JOUR

T1 - Multiarm star polymers with POSS at the periphery

AU - Gungor, Eda

AU - Bilir, Cigdem

AU - Hizal, Gurkan

AU - Tunca, Umit

PY - 2010/11/1

Y1 - 2010/11/1

N2 - Azide end-functionalized polyhedral oligomeric silsesquioxane (POSS-N 3) was incorporated into the periphery of well-defined alkyne-polystyrene50-poly(divinyl benzene) (alkyne-PS 50-polyDVB) and alkyne-poly(tert-butyl acrylate)43- poly(divinyl benzene) (alkyne-PtBA43-polyDVB) multiarm star polymers via highly efficient azide-alkyne click reaction, resulting in POSS-PS 50-polyDVB and POSS-PtBA43-polyDVB multiarm star block copolymers respectively, in the solution of tetrahydrofuran/N,N-dimethyl formamide, CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA) at room temperature for 24 h. Linear precursors and star polymers obtained in this study were characterized 1H NMR, gel permeation chromatography (GPC), and triple detection GPC (TD-GPC). Absolute molecular weight, hydrodynamic radius, and intrinsic viscosity ([η]) values for all star polymers were determined by TD-GPC.

AB - Azide end-functionalized polyhedral oligomeric silsesquioxane (POSS-N 3) was incorporated into the periphery of well-defined alkyne-polystyrene50-poly(divinyl benzene) (alkyne-PS 50-polyDVB) and alkyne-poly(tert-butyl acrylate)43- poly(divinyl benzene) (alkyne-PtBA43-polyDVB) multiarm star polymers via highly efficient azide-alkyne click reaction, resulting in POSS-PS 50-polyDVB and POSS-PtBA43-polyDVB multiarm star block copolymers respectively, in the solution of tetrahydrofuran/N,N-dimethyl formamide, CuBr/N,N,N′,N″,N″-pentamethyldiethylenetriamine (PMDETA) at room temperature for 24 h. Linear precursors and star polymers obtained in this study were characterized 1H NMR, gel permeation chromatography (GPC), and triple detection GPC (TD-GPC). Absolute molecular weight, hydrodynamic radius, and intrinsic viscosity ([η]) values for all star polymers were determined by TD-GPC.

KW - azide-alkyne click reaction

KW - hydrodynamic radius

KW - intrinsic viscosity

KW - living radical polymerization

KW - multiarm star polymer

KW - poly(tert-butyl acrylate)

KW - polystyrene

KW - POSS

KW - star polymers

KW - triple detection GPC

UR - https://www.scopus.com/pages/publications/78649609519

U2 - 10.1002/pola.24275

DO - 10.1002/pola.24275

M3 - Article

AN - SCOPUS:78649609519

SN - 0887-624X

VL - 48

SP - 4835

EP - 4841

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 21

ER -

Multiarm star polymers with POSS at the periphery

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

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