Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method

Nurseli Uyanik; Candan Erbil

doi:10.1016/S0014-3057(00)00045-8

Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method

Nurseli Uyanik
, Candan Erbil

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

17 Atıf (Scopus)

Özet

Itaconic acid (methylene succinic acid)-acrylamide (IA-AAm) copolymers were synthesized with solution polymerization by using potassium persulphate. The potentiometric titration method was used to determine the copolymer compositions. The results were evaluated by various methods. The monomer reactivity ratios were found to be r_IA = 0.99±0.04, r_AAm = 0.58±0.02 with the Fineman-Ross, r_IA = 1.05±0.10, r_AAm = 0.62±0.06 with the Kelen-Tudos, and r_IA = 1.36±0.11, r_AAm = 0.77±0.06 with the Tidwell-Mortimer methods. As expected, IA is found to be the more reactive monomer in IA-AAm copolymers.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	2651-2654
Sayfa sayısı	4
Dergi	European Polymer Journal
Hacim	36
Basın numarası	12
DOI'lar	https://doi.org/10.1016/S0014-3057(00)00045-8
Yayın durumu	Yayınlandı - Ara 2000

Belgeye Erişim

10.1016/S0014-3057(00)00045-8

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Alıntı Yap

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title = "Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method",

abstract = "Itaconic acid (methylene succinic acid)-acrylamide (IA-AAm) copolymers were synthesized with solution polymerization by using potassium persulphate. The potentiometric titration method was used to determine the copolymer compositions. The results were evaluated by various methods. The monomer reactivity ratios were found to be rIA = 0.99±0.04, rAAm = 0.58±0.02 with the Fineman-Ross, rIA = 1.05±0.10, rAAm = 0.62±0.06 with the Kelen-Tudos, and rIA = 1.36±0.11, rAAm = 0.77±0.06 with the Tidwell-Mortimer methods. As expected, IA is found to be the more reactive monomer in IA-AAm copolymers.",

author = "Nurseli Uyanik and Candan Erbil",

year = "2000",

month = dec,

doi = "10.1016/S0014-3057(00)00045-8",

language = "English",

volume = "36",

pages = "2651--2654",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd",

number = "12",

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TY - JOUR

T1 - Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method

AU - Uyanik, Nurseli

AU - Erbil, Candan

PY - 2000/12

Y1 - 2000/12

N2 - Itaconic acid (methylene succinic acid)-acrylamide (IA-AAm) copolymers were synthesized with solution polymerization by using potassium persulphate. The potentiometric titration method was used to determine the copolymer compositions. The results were evaluated by various methods. The monomer reactivity ratios were found to be rIA = 0.99±0.04, rAAm = 0.58±0.02 with the Fineman-Ross, rIA = 1.05±0.10, rAAm = 0.62±0.06 with the Kelen-Tudos, and rIA = 1.36±0.11, rAAm = 0.77±0.06 with the Tidwell-Mortimer methods. As expected, IA is found to be the more reactive monomer in IA-AAm copolymers.

AB - Itaconic acid (methylene succinic acid)-acrylamide (IA-AAm) copolymers were synthesized with solution polymerization by using potassium persulphate. The potentiometric titration method was used to determine the copolymer compositions. The results were evaluated by various methods. The monomer reactivity ratios were found to be rIA = 0.99±0.04, rAAm = 0.58±0.02 with the Fineman-Ross, rIA = 1.05±0.10, rAAm = 0.62±0.06 with the Kelen-Tudos, and rIA = 1.36±0.11, rAAm = 0.77±0.06 with the Tidwell-Mortimer methods. As expected, IA is found to be the more reactive monomer in IA-AAm copolymers.

UR - https://www.scopus.com/pages/publications/0033672061

U2 - 10.1016/S0014-3057(00)00045-8

DO - 10.1016/S0014-3057(00)00045-8

M3 - Article

AN - SCOPUS:0033672061

SN - 0014-3057

VL - 36

SP - 2651

EP - 2654

JO - European Polymer Journal

JF - European Polymer Journal

IS - 12

ER -

Monomer reactivity ratios of itaconic acid and acrylamide copolymers determined by using potentiometric titration method

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