Modification of reinforced hollow fiber membranes with WO₃ nanosheets for treatment of textile wastewater by membrane bioreactor

In this study, performance of braid reinforced hollow fiber membrane containing polyvinylidene fluoride (PVDF) embedded with tungsten trioxide (WO₃) nanosheets in a membrane bioreactor (MBR) was examined for textile wastewater treatment. The WO₃ nanosheets was synthesized and blended at different concentrations (0.1–0.02 wt%) in casting solutions of the membranes. The WO₃ nanosheets characterized using various tests such as XRD, FTIR, SEM, EDS, dot-mapping, and TEM. Furthermore, the effects of the increased WO₃ nanosheets into the PVDF matrix on the membrane morphology, hydrophilicity, permeability, antifouling, and COD and color removal efficiency was investigated. The addition of 0.1 wt% of the nanosheets reduces the water contact angle from 69.3° to 62.5° while increasing overall porosity from 37.5 to 43.2%. COD and color removal for PVDF/0.10 wt% WO₃ membrane was between 86-89% and 72–76%, respectively. While the TMP of modified WO₃ membranes did not significantly increase due to antimicrobial properties of the WO₃ nanosheets, the TMP of the pure PVDF membrane increase, indicating considerable cake layer fouling. The results of this study showed that modification of PVDF braid reinforced hollow fiber membrane using WO₃ nanosheets is promising membrane for MBR systems.