Manganese(II), cobalt(II) and nickel(II) complexes constructed from a pyridyloxy-functionalized hexapodal cyclophosphazene ligand: Structural and magnetic studies

Derya Davarcı*, Nurcan Doğan, İlker Cabacı, Yunus Zorlu

*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: ???type-name???Makalebilirkişi

1 Atıf (Scopus)

Özet

Herein, the coordination behaviour of a hexapodal building block, 2,2,4,4,6,6-hexakis((6-methylpyridin-3-yl)oxy) cyclotriphosphazene (MeHPCP), towards divalent metal ions (Mn, Co and Ni) is described. Three new coordination compounds, namely the molecular complex [Mn(MeHPCP)(Cl)2(H2O)2] (1) and the one-dimensional (1D) zig-zag chain coordination polymers {Co2(MeHPCP)(Cl)4(H2O)2](MeCN)(H2O)3}n (2) and {[Ni(MeHPCP)(Cl)2(H2O)]}n (3), were structurally characterized by FT-IR spectroscopy and single crystal X-ray diffraction analysis. Thermogravimetric analyses show that all the compounds have high thermal stability (>350 °C). The magnetic properties of 2 and 3 were analyzed by electron spin resonance (ESR) and the physical properties measurement system (PPMS) technique and these complexes exhibited paramagnetic behavior.

Orijinal dilİngilizce
Makale numarası115557
DergiPolyhedron
Hacim211
DOI'lar
Yayın durumuYayınlandı - 1 Oca 2022
Harici olarak yayınlandıEvet

Bibliyografik not

Publisher Copyright:
© 2021

Parmak izi

Manganese(II), cobalt(II) and nickel(II) complexes constructed from a pyridyloxy-functionalized hexapodal cyclophosphazene ligand: Structural and magnetic studies' araştırma başlıklarına git. Birlikte benzersiz bir parmak izi oluştururlar.

Alıntı Yap