Ionic liquid-assisted synthesis of porous boron-doped graphitic carbon nitride for photocatalytic hydrogen production

This work presents a simple way to prepare boron-doped graphitic carbon nitride (B/g-C₃N₄), exhibiting an enhanced photocatalytic performance to split water for hydrogen production. B/g-C₃N₄ was synthesized via the pyrolysis of urea and 1-ethyl-3-methylimidazolium tetrafluoroborate ([Emim]BF₄), which was adopted as the boron source. The aggregate of B/g-C₃N₄ nanosheets shows a porous structure since some bubbles are generated under the heat decomposition of ionic liquids. The porous structure is conducive to the exposure of more active sites. Moreover, B-doping will form some localized electronic energy levels in the band gap of g-C₃N₄, thereby extending its visible light response. As impacted by the porous structure of B/g-C₃N₄ aggregate and the narrow the band gap, the photocatalytic hydrogen generation rate (901 μmol h⁻¹ g⁻¹) is increased, almost 3 times faster than g-C₃N₄ (309 μmol h⁻¹ g⁻¹). This work proposed a simple method to prepare the aggregate of B/g-C₃N₄ nanosheets exhibiting pores under ionic liquid assistance. It can be a novel method to design porous polymer photocatalysts.