Influence of plasma treatment on Ce0.05–Ni–W–B catalyst for hydrogen production by hydrolysis of NaBH4

Cafer Saka; Arzu Ekinci; Ömer Şahin; Asım Balbay

doi:10.1016/j.joei.2015.02.004

Influence of plasma treatment on Ce_0.05–Ni–W–B catalyst for hydrogen production by hydrolysis of NaBH₄

Cafer Saka
, Arzu Ekinci
, Ömer Şahin^*
, Asım Balbay

^*Bu çalışma için yazışmadan sorumlu yazar

Siirt University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

14 Atıf (Scopus)

Özet

The aim of this study was to evaluate the effect of plasma treatment on the surface of Ce_0.05-Ni-W-B catalyst. The Ce_0.05–Ni–W–B catalysts were treated with argon plasma at a different treatment time. Ce was used as a promoter. NaBH₄ concentration, NaOH concentration, temperature, plasma applying time and plasma gases was investigated for the hydrogen generation from the hydrolysis of NaBH₄ with Ce_0.05-Ni-W-B catalyst. The catalysts were characterized using Fourier Transform Infrared spectrometry (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The results of the activity tests indicate that the plasma treatment greatly influence the activity. The activation energies for zero-order of the untreated and plasma treated Ce_0.05-Ni-W-B catalysts were found to be 51.87 and 41.18 kJ mol⁻¹, respectively.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	190-198
Sayfa sayısı	9
Dergi	Journal of the Energy Institute
Hacim	89
Basın numarası	2
DOI'lar	https://doi.org/10.1016/j.joei.2015.02.004
Yayın durumu	Yayınlandı - 1 May 2016
Harici olarak yayınlandı	Evet

Bibliyografik not

Publisher Copyright:
© 2015 Energy Institute

Finansman

The authors are grateful to the Research Foundation of Siirt University for financial support under Project 2013-SİÜMÜH-M5 .

Finansörler	Finansör numarası
Research Foundation of Siirt University	2013-SİÜMÜH-M5

BM SKH

Bu sonuç, aşağıdaki Sürdürülebilir Kalkınma Hedefine/Hedeflerine katkıda bulunur

SKH 7 Erişilebilir ve Temiz Enerji

Belgeye Erişim

10.1016/j.joei.2015.02.004

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Influence of plasma treatment on Ce0.05–Ni–W–B catalyst for hydrogen production by hydrolysis of NaBH4",

abstract = "The aim of this study was to evaluate the effect of plasma treatment on the surface of Ce0.05-Ni-W-B catalyst. The Ce0.05–Ni–W–B catalysts were treated with argon plasma at a different treatment time. Ce was used as a promoter. NaBH4 concentration, NaOH concentration, temperature, plasma applying time and plasma gases was investigated for the hydrogen generation from the hydrolysis of NaBH4 with Ce0.05-Ni-W-B catalyst. The catalysts were characterized using Fourier Transform Infrared spectrometry (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The results of the activity tests indicate that the plasma treatment greatly influence the activity. The activation energies for zero-order of the untreated and plasma treated Ce0.05-Ni-W-B catalysts were found to be 51.87 and 41.18 kJ mol−1, respectively.",

keywords = "Ce-Ni-W-B catalyst, Cold plasma, Hydrogen generation, Sodium borohydride",

author = "Cafer Saka and Arzu Ekinci and {\"O}mer {\c S}ahin and Asım Balbay",

note = "Publisher Copyright: {\textcopyright} 2015 Energy Institute",

year = "2016",

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doi = "10.1016/j.joei.2015.02.004",

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T1 - Influence of plasma treatment on Ce0.05–Ni–W–B catalyst for hydrogen production by hydrolysis of NaBH4

AU - Saka, Cafer

AU - Ekinci, Arzu

AU - Şahin, Ömer

AU - Balbay, Asım

PY - 2016/5/1

Y1 - 2016/5/1

N2 - The aim of this study was to evaluate the effect of plasma treatment on the surface of Ce0.05-Ni-W-B catalyst. The Ce0.05–Ni–W–B catalysts were treated with argon plasma at a different treatment time. Ce was used as a promoter. NaBH4 concentration, NaOH concentration, temperature, plasma applying time and plasma gases was investigated for the hydrogen generation from the hydrolysis of NaBH4 with Ce0.05-Ni-W-B catalyst. The catalysts were characterized using Fourier Transform Infrared spectrometry (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The results of the activity tests indicate that the plasma treatment greatly influence the activity. The activation energies for zero-order of the untreated and plasma treated Ce0.05-Ni-W-B catalysts were found to be 51.87 and 41.18 kJ mol−1, respectively.

AB - The aim of this study was to evaluate the effect of plasma treatment on the surface of Ce0.05-Ni-W-B catalyst. The Ce0.05–Ni–W–B catalysts were treated with argon plasma at a different treatment time. Ce was used as a promoter. NaBH4 concentration, NaOH concentration, temperature, plasma applying time and plasma gases was investigated for the hydrogen generation from the hydrolysis of NaBH4 with Ce0.05-Ni-W-B catalyst. The catalysts were characterized using Fourier Transform Infrared spectrometry (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM) analysis. The results of the activity tests indicate that the plasma treatment greatly influence the activity. The activation energies for zero-order of the untreated and plasma treated Ce0.05-Ni-W-B catalysts were found to be 51.87 and 41.18 kJ mol−1, respectively.

KW - Ce-Ni-W-B catalyst

KW - Cold plasma

KW - Hydrogen generation

KW - Sodium borohydride

UR - https://www.scopus.com/pages/publications/85000789393

U2 - 10.1016/j.joei.2015.02.004

DO - 10.1016/j.joei.2015.02.004

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JO - Journal of the Energy Institute

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