Fullerene-Attached Polymeric Homogeneous/Heterogeneous Photoactivators for Visible-Light-Induced CuAAC Click Reactions

Omer S. Taskin; Gorkem Yilmaz; Yusuf Yagci

doi:10.1021/acsmacrolett.5b00885

Fullerene-Attached Polymeric Homogeneous/Heterogeneous Photoactivators for Visible-Light-Induced CuAAC Click Reactions

Omer S. Taskin
, Gorkem Yilmaz
, Yusuf Yagci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University
Faculty of Sciences, King Abdulaziz University

Araştırma çıktısı: Dergi yayını › Makale › Hakem

34 Atıf (Scopus)

Özet

In this work, a visible-light-induced copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click reaction via an electron transfer reaction employing fullerene (C₆₀) containing linear polystyrene and network polymer as homogeneous and heterogeneous activators, PS-C₆₀ and Gel-C₆₀, respectively, is described. Various low molar mass organic and polymeric azide and alkyne compounds are used to conduct the click reaction, and almost quantitative yields are attained. Compared to the bare C₆₀, the polymers with C₆₀ units exhibited a much higher promoting effect to catalyze CuAAC reactions.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	103-107
Sayfa sayısı	5
Dergi	ACS Macro Letters
Hacim	5
Basın numarası	1
DOI'lar	https://doi.org/10.1021/acsmacrolett.5b00885
Yayın durumu	Yayınlandı - 19 Oca 2016

Bibliyografik not

Publisher Copyright:
© 2015 American Chemical Society.

Belgeye Erişim

10.1021/acsmacrolett.5b00885

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Fullerene-Attached Polymeric Homogeneous/Heterogeneous Photoactivators for Visible-Light-Induced CuAAC Click Reactions",

abstract = "In this work, a visible-light-induced copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click reaction via an electron transfer reaction employing fullerene (C60) containing linear polystyrene and network polymer as homogeneous and heterogeneous activators, PS-C60 and Gel-C60, respectively, is described. Various low molar mass organic and polymeric azide and alkyne compounds are used to conduct the click reaction, and almost quantitative yields are attained. Compared to the bare C60, the polymers with C60 units exhibited a much higher promoting effect to catalyze CuAAC reactions.",

author = "Taskin, \{Omer S.\} and Gorkem Yilmaz and Yusuf Yagci",

note = "Publisher Copyright: {\textcopyright} 2015 American Chemical Society.",

year = "2016",

month = jan,

day = "19",

doi = "10.1021/acsmacrolett.5b00885",

language = "English",

volume = "5",

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journal = "ACS Macro Letters",

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T1 - Fullerene-Attached Polymeric Homogeneous/Heterogeneous Photoactivators for Visible-Light-Induced CuAAC Click Reactions

AU - Taskin, Omer S.

AU - Yilmaz, Gorkem

AU - Yagci, Yusuf

PY - 2016/1/19

Y1 - 2016/1/19

N2 - In this work, a visible-light-induced copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click reaction via an electron transfer reaction employing fullerene (C60) containing linear polystyrene and network polymer as homogeneous and heterogeneous activators, PS-C60 and Gel-C60, respectively, is described. Various low molar mass organic and polymeric azide and alkyne compounds are used to conduct the click reaction, and almost quantitative yields are attained. Compared to the bare C60, the polymers with C60 units exhibited a much higher promoting effect to catalyze CuAAC reactions.

AB - In this work, a visible-light-induced copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) click reaction via an electron transfer reaction employing fullerene (C60) containing linear polystyrene and network polymer as homogeneous and heterogeneous activators, PS-C60 and Gel-C60, respectively, is described. Various low molar mass organic and polymeric azide and alkyne compounds are used to conduct the click reaction, and almost quantitative yields are attained. Compared to the bare C60, the polymers with C60 units exhibited a much higher promoting effect to catalyze CuAAC reactions.

UR - https://www.scopus.com/pages/publications/84955508139

U2 - 10.1021/acsmacrolett.5b00885

DO - 10.1021/acsmacrolett.5b00885

M3 - Article

AN - SCOPUS:84955508139

SN - 2161-1653

VL - 5

SP - 103

EP - 107

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 1

ER -

Fullerene-Attached Polymeric Homogeneous/Heterogeneous Photoactivators for Visible-Light-Induced CuAAC Click Reactions

Özet

Bibliyografik not

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

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