Fructose as a reducing agent for in situ generation of Cu(I) species via an electron-transfer reaction in copper-catalyzed living/controlled radical polymerization of styrene

Aydan Dag; Humeyra Mert; Bart Dervaux; Filip E. Du Prez; Umit Tunca; Gurkan Hizal

doi:10.1163/156855507781833594

Fructose as a reducing agent for in situ generation of Cu(I) species via an electron-transfer reaction in copper-catalyzed living/controlled radical polymerization of styrene

Aydan Dag, Humeyra Mert, Bart Dervaux, Filip E. Du Prez, Umit Tunca, Gurkan Hizal^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

7 Atıf (Scopus)

Özet

Copper-catalyzed living radical polymerization (LRP) of styrene was carried out in the presence of fructose as a reducing agent for Cu(II) by using either 1-chloro-1-phenyl ethane (1-PECl), ethyl-2-bromoisobutyrate (EiBr) or methyl-2-bromopropionate (MBP) as an initiator and N,N,N′,N″, N″-pentamethyldiethylenetriamine (PMDETA) as ligand at 110°C. Kinetic experiments were carried out in order to reveal the effect of fructose concentration on copper-catalyzed LRP of St. This technique was successfully applied for the preparation of homo-polymers (linear and star-type polystyrene (PS)) and corresponding block co-polymers (PS-b-PMMA). The polymers thus obtained were characterized using GPC, ¹H-NMR and MALDI-TOF measurements.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	425-438
Sayfa sayısı	14
Dergi	Designed Monomers and Polymers
Hacim	10
Basın numarası	5
DOI'lar	https://doi.org/10.1163/156855507781833594
Yayın durumu	Yayınlandı - 2007

Finansman

The authors would like to thank “The Research Fund of Istanbul Technical Universi ty” and “The Scientific & Technological Research Council of Turkey (TUBITAK)” for financial support of this work. B. D. thanks the FWO (Fund for scientific research-Flanders, Belgium) for a PhD scholarship. F. Du P. thanks the Belgian Programme on Interuniversity Attraction Poles initiated by the Belgian State, Prime Minister’s office, for financial support.

Finansörler	Finansör numarası
Istanbul Technical Universi
Scientific & Technological Research Council of Turkey
TUBITAK
Fonds Wetenschappelijk Onderzoek

Belgeye Erişim

10.1163/156855507781833594

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Fructose as a reducing agent for in situ generation of Cu(I) species via an electron-transfer reaction in copper-catalyzed living/controlled radical polymerization of styrene",

abstract = "Copper-catalyzed living radical polymerization (LRP) of styrene was carried out in the presence of fructose as a reducing agent for Cu(II) by using either 1-chloro-1-phenyl ethane (1-PECl), ethyl-2-bromoisobutyrate (EiBr) or methyl-2-bromopropionate (MBP) as an initiator and N,N,N′,N″, N″-pentamethyldiethylenetriamine (PMDETA) as ligand at 110°C. Kinetic experiments were carried out in order to reveal the effect of fructose concentration on copper-catalyzed LRP of St. This technique was successfully applied for the preparation of homo-polymers (linear and star-type polystyrene (PS)) and corresponding block co-polymers (PS-b-PMMA). The polymers thus obtained were characterized using GPC, 1H-NMR and MALDI-TOF measurements.",

keywords = "Atom-transfer radical polymerization, Electron-transfer reaction, Fructose",

author = "Aydan Dag and Humeyra Mert and Bart Dervaux and {Du Prez}, {Filip E.} and Umit Tunca and Gurkan Hizal",

year = "2007",

doi = "10.1163/156855507781833594",

language = "English",

volume = "10",

pages = "425--438",

journal = "Designed Monomers and Polymers",

issn = "1385-772X",

publisher = "Taylor and Francis Ltd.",

number = "5",

}

TY - JOUR

T1 - Fructose as a reducing agent for in situ generation of Cu(I) species via an electron-transfer reaction in copper-catalyzed living/controlled radical polymerization of styrene

AU - Dag, Aydan

AU - Mert, Humeyra

AU - Dervaux, Bart

AU - Du Prez, Filip E.

AU - Tunca, Umit

AU - Hizal, Gurkan

PY - 2007

Y1 - 2007

N2 - Copper-catalyzed living radical polymerization (LRP) of styrene was carried out in the presence of fructose as a reducing agent for Cu(II) by using either 1-chloro-1-phenyl ethane (1-PECl), ethyl-2-bromoisobutyrate (EiBr) or methyl-2-bromopropionate (MBP) as an initiator and N,N,N′,N″, N″-pentamethyldiethylenetriamine (PMDETA) as ligand at 110°C. Kinetic experiments were carried out in order to reveal the effect of fructose concentration on copper-catalyzed LRP of St. This technique was successfully applied for the preparation of homo-polymers (linear and star-type polystyrene (PS)) and corresponding block co-polymers (PS-b-PMMA). The polymers thus obtained were characterized using GPC, 1H-NMR and MALDI-TOF measurements.

AB - Copper-catalyzed living radical polymerization (LRP) of styrene was carried out in the presence of fructose as a reducing agent for Cu(II) by using either 1-chloro-1-phenyl ethane (1-PECl), ethyl-2-bromoisobutyrate (EiBr) or methyl-2-bromopropionate (MBP) as an initiator and N,N,N′,N″, N″-pentamethyldiethylenetriamine (PMDETA) as ligand at 110°C. Kinetic experiments were carried out in order to reveal the effect of fructose concentration on copper-catalyzed LRP of St. This technique was successfully applied for the preparation of homo-polymers (linear and star-type polystyrene (PS)) and corresponding block co-polymers (PS-b-PMMA). The polymers thus obtained were characterized using GPC, 1H-NMR and MALDI-TOF measurements.

KW - Atom-transfer radical polymerization

KW - Electron-transfer reaction

KW - Fructose

UR - http://www.scopus.com/inward/record.url?scp=34548755193&partnerID=8YFLogxK

U2 - 10.1163/156855507781833594

DO - 10.1163/156855507781833594

M3 - Article

AN - SCOPUS:34548755193

SN - 1385-772X

VL - 10

SP - 425

EP - 438

JO - Designed Monomers and Polymers

JF - Designed Monomers and Polymers

IS - 5

ER -

Fructose as a reducing agent for in situ generation of Cu(I) species via an electron-transfer reaction in copper-catalyzed living/controlled radical polymerization of styrene

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

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