Fluorescent chemosensor for Ag(I) based on amplified fluorescence quenching of a new phthalocyanine bearing derivative of benzofuran

Mehmet Kandaz; Orhan Güney; Filiz B. Senkal

doi:10.1016/j.poly.2009.06.058

Fluorescent chemosensor for Ag(I) based on amplified fluorescence quenching of a new phthalocyanine bearing derivative of benzofuran

Mehmet Kandaz^*
, Orhan Güney
, Filiz B. Senkal

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Sakarya University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

62 Atıf (Scopus)

Özet

A fluorescent chemosensor for Ag(I) as a new family of peripherally functionalized zinc-phthalocyanine, 2(3),9(10),16(17),23(24)-tetrakis-{6-(-benzofuran-2-carboxylate)-hexylth io} phthalocyaninatozinc(II) {Zn[Pc(β-S(CH₂)₆OCOBz-furan)₄], (ZnPcBzF), (3), which was derivated from 6-(3,4-dicyanophenylthio)-hexyl-2-benzofuranate (BzF), (2), has been synthesized and fully characterized by elemental analysis, FT-IR, ¹H and ¹³C NMR, MS (ESI and Maldi-TOF). An optical silver ion (Ag(I)) sensor based on the fluorescence quenching of benzofuran moiety and ZnPc core was developed. Both absorbance and fluorescence spectra of ZnPcBzF, (3) exhibit distinct changes in visible region in response to treatment with Ag(I) ion in solution. Such properties make compound ZnPcBzF, (3) intriguing candidates for incorporation into the transducer layer in optically based chemical sensors.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	3110-3114
Sayfa sayısı	5
Dergi	Polyhedron
Hacim	28
Basın numarası	14
DOI'lar	https://doi.org/10.1016/j.poly.2009.06.058
Yayın durumu	Yayınlandı - 23 Eyl 2009

Finansman

We thank the Research Funds of TUBİTAK (TBAG: Project No: 108T094) and ITU (BAP: Project No: 31472).

Finansörler	Finansör numarası
TUBİTAK	108T094
International Technological University	31472

Belgeye Erişim

10.1016/j.poly.2009.06.058

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{a02c2305adf84aff9afcd5d02ee2ccb6,

title = "Fluorescent chemosensor for Ag(I) based on amplified fluorescence quenching of a new phthalocyanine bearing derivative of benzofuran",

abstract = "A fluorescent chemosensor for Ag(I) as a new family of peripherally functionalized zinc-phthalocyanine, 2(3),9(10),16(17),23(24)-tetrakis-\{6-(-benzofuran-2-carboxylate)-hexylth io\} phthalocyaninatozinc(II) \{Zn[Pc(β-S(CH2)6OCOBz-furan)4], (ZnPcBzF), (3), which was derivated from 6-(3,4-dicyanophenylthio)-hexyl-2-benzofuranate (BzF), (2), has been synthesized and fully characterized by elemental analysis, FT-IR, 1H and 13C NMR, MS (ESI and Maldi-TOF). An optical silver ion (Ag(I)) sensor based on the fluorescence quenching of benzofuran moiety and ZnPc core was developed. Both absorbance and fluorescence spectra of ZnPcBzF, (3) exhibit distinct changes in visible region in response to treatment with Ag(I) ion in solution. Such properties make compound ZnPcBzF, (3) intriguing candidates for incorporation into the transducer layer in optically based chemical sensors.",

keywords = "Fluorescence quenching, Optical metal sensor, Phthalocyanine, Silver ion, Zinc aggregation",

author = "Mehmet Kandaz and Orhan G{\"u}ney and Senkal, \{Filiz B.\}",

year = "2009",

month = sep,

day = "23",

doi = "10.1016/j.poly.2009.06.058",

language = "English",

volume = "28",

pages = "3110--3114",

journal = "Polyhedron",

issn = "0277-5387",

number = "14",

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TY - JOUR

T1 - Fluorescent chemosensor for Ag(I) based on amplified fluorescence quenching of a new phthalocyanine bearing derivative of benzofuran

AU - Kandaz, Mehmet

AU - Güney, Orhan

AU - Senkal, Filiz B.

PY - 2009/9/23

Y1 - 2009/9/23

N2 - A fluorescent chemosensor for Ag(I) as a new family of peripherally functionalized zinc-phthalocyanine, 2(3),9(10),16(17),23(24)-tetrakis-{6-(-benzofuran-2-carboxylate)-hexylth io} phthalocyaninatozinc(II) {Zn[Pc(β-S(CH2)6OCOBz-furan)4], (ZnPcBzF), (3), which was derivated from 6-(3,4-dicyanophenylthio)-hexyl-2-benzofuranate (BzF), (2), has been synthesized and fully characterized by elemental analysis, FT-IR, 1H and 13C NMR, MS (ESI and Maldi-TOF). An optical silver ion (Ag(I)) sensor based on the fluorescence quenching of benzofuran moiety and ZnPc core was developed. Both absorbance and fluorescence spectra of ZnPcBzF, (3) exhibit distinct changes in visible region in response to treatment with Ag(I) ion in solution. Such properties make compound ZnPcBzF, (3) intriguing candidates for incorporation into the transducer layer in optically based chemical sensors.

AB - A fluorescent chemosensor for Ag(I) as a new family of peripherally functionalized zinc-phthalocyanine, 2(3),9(10),16(17),23(24)-tetrakis-{6-(-benzofuran-2-carboxylate)-hexylth io} phthalocyaninatozinc(II) {Zn[Pc(β-S(CH2)6OCOBz-furan)4], (ZnPcBzF), (3), which was derivated from 6-(3,4-dicyanophenylthio)-hexyl-2-benzofuranate (BzF), (2), has been synthesized and fully characterized by elemental analysis, FT-IR, 1H and 13C NMR, MS (ESI and Maldi-TOF). An optical silver ion (Ag(I)) sensor based on the fluorescence quenching of benzofuran moiety and ZnPc core was developed. Both absorbance and fluorescence spectra of ZnPcBzF, (3) exhibit distinct changes in visible region in response to treatment with Ag(I) ion in solution. Such properties make compound ZnPcBzF, (3) intriguing candidates for incorporation into the transducer layer in optically based chemical sensors.

KW - Fluorescence quenching

KW - Optical metal sensor

KW - Phthalocyanine

KW - Silver ion

KW - Zinc aggregation

UR - https://www.scopus.com/pages/publications/69649105836

U2 - 10.1016/j.poly.2009.06.058

DO - 10.1016/j.poly.2009.06.058

M3 - Article

AN - SCOPUS:69649105836

SN - 0277-5387

VL - 28

SP - 3110

EP - 3114

JO - Polyhedron

JF - Polyhedron

IS - 14

ER -

Fluorescent chemosensor for Ag(I) based on amplified fluorescence quenching of a new phthalocyanine bearing derivative of benzofuran

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap