Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization

Ö Pekcan; D. Kaya; M. Erdoan

doi:10.1002/app.1288

Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization

Ö Pekcan^*, D. Kaya, M. Erdoan

^*Bu çalışma için yazışmadan sorumlu yazar

Fizik Mühendisliği Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

6 Atıf (Scopus)

Özet

The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1907-1913
Sayfa sayısı	7
Dergi	Journal of Applied Polymer Science
Hacim	80
Basın numarası	11
DOI'lar	https://doi.org/10.1002/app.1288
Yayın durumu	Yayınlandı - 13 Haz 2001

Belgeye Erişim

10.1002/app.1288

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization",

abstract = "The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.",

keywords = "Fluorescence, Gelation, Monomer consumption, Polymerization rates",

author = "{\"O} Pekcan and D. Kaya and M. Erdoan",

year = "2001",

month = jun,

day = "13",

doi = "10.1002/app.1288",

language = "English",

volume = "80",

pages = "1907--1913",

journal = "Journal of Applied Polymer Science",

issn = "0021-8995",

publisher = "John Wiley & Sons Inc.",

number = "11",

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TY - JOUR

T1 - Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization

AU - Pekcan, Ö

AU - Kaya, D.

AU - Erdoan, M.

PY - 2001/6/13

Y1 - 2001/6/13

N2 - The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.

AB - The steady-state fluorescence (SSF) technique was used to study the polymerization rate in free-radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM). Pyrene (Py) was used as a fluorescent probe for the in situ polymerization experiments. The increase in Py intensity was monitored during FCC. The Stern-Volmer kinetic was employed to determine the MMA consumption rate during gelation process for various EGDM contents and at different temperatures.

KW - Fluorescence

KW - Gelation

KW - Monomer consumption

KW - Polymerization rates

UR - http://www.scopus.com/inward/record.url?scp=0035854130&partnerID=8YFLogxK

U2 - 10.1002/app.1288

DO - 10.1002/app.1288

M3 - Article

AN - SCOPUS:0035854130

SN - 0021-8995

VL - 80

SP - 1907

EP - 1913

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 11

ER -

Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

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