FISCHER-TROPSCH TO OLEFIN REACTION OVER CARBON SUPPORTED IRON CATALYSTS: INVESTIGATION OF UREA DOPED ACTIVATED CARBON IN THE PRESENCE OF SODIUM AND ZINC PROMOTERS

Pınar Şakoğlu; Yasaman Fallahi; Osman Okur; Alper Sarıoğlan; Hüsnü Atakül; Gamze Gümüşlü Gür

FISCHER-TROPSCH TO OLEFIN REACTION OVER CARBON SUPPORTED IRON CATALYSTS: INVESTIGATION OF UREA DOPED ACTIVATED CARBON IN THE PRESENCE OF SODIUM AND ZINC PROMOTERS

Pınar Şakoğlu^*
, Yasaman Fallahi
, Osman Okur
, Alper Sarıoğlan
, Hüsnü Atakül
, Gamze Gümüşlü Gür

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Mühendisliği Bölümü

Araştırma sonucu: Dergiye katkı › Konferans makalesi › bilirkişi

Özet

The Fischer-Tropsch (F-T) reaction has been successfully applied for decades for conventional liquid fuel and wax production. F-T presents a promising direct reaction pathway, for light olefins (formula presented), the building blocks of the plastic industry. However, a catalyst that meets all the criteria of activity, stability, and selectivity has not yet been discovered for light olefin production. There are still unresolved issues like iron-support interaction and the secondary metals contributing to the surface reactions such as CO dissociation, surface-bound (-CHx-) monomers growing, and their termination to give paraffins or olefins. The aim of this study is to modify the physicochemical properties of activated carbon by introducing a heteroatom of nitrogen, e.g. urea, and investigate the effect of promoters on urea-doped activated carbon supported iron catalyst. Thus, a series of catalysts have been prepared and tested under F-T to olefin reaction conditions and their catalytic nature has been interpreted in relation to their physicochemical properties.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1082-1087
Sayfa sayısı	6
Dergi	European Biomass Conference and Exhibition Proceedings
Yayın durumu	Yayınlandı - 2022
Etkinlik	30th European Biomass Conference and Exhibition, EUBCE 2022 - Virtual, Online Süre: 9 May 2022 → 12 May 2022

Bibliyografik not

Publisher Copyright:
© 2022, ETA-Florence Renewable Energies., All rights reserved.

Finansman

This research was supported by the “The Scientific and Technological Research Council of Turkey (TUBITAK)” under the projects “Development of Catalyst and Reactor for Light Olefins' Production from Cleaned Syngas”, project no: 217M924 and “Fabrication of Enhanced Core-Shell Co-ZIF-67@MOx (M = Zn, Mn and K) Nanocomposites via Intermediate Pyrolysis and Plasma Treatment for Fischer Tropsch Synthesis”, project no: 121N102. *Correspondence:[email protected];

Finansörler	Finansör numarası
Türkiye Bilimsel ve Teknolojik Araştırma Kurumu	217M924, 121N102

BM SKH

Bu sonuç, aşağıdaki Sürdürülebilir Kalkınma Hedefine/Hedeflerine katkıda bulunur

SKH 7 Erişilebilir ve Temiz Enerji

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{f86214cb18b54e8ba52e755b7b5e8bd3,

title = "FISCHER-TROPSCH TO OLEFIN REACTION OVER CARBON SUPPORTED IRON CATALYSTS: INVESTIGATION OF UREA DOPED ACTIVATED CARBON IN THE PRESENCE OF SODIUM AND ZINC PROMOTERS",

abstract = "The Fischer-Tropsch (F-T) reaction has been successfully applied for decades for conventional liquid fuel and wax production. F-T presents a promising direct reaction pathway, for light olefins (formula presented), the building blocks of the plastic industry. However, a catalyst that meets all the criteria of activity, stability, and selectivity has not yet been discovered for light olefin production. There are still unresolved issues like iron-support interaction and the secondary metals contributing to the surface reactions such as CO dissociation, surface-bound (-CHx-) monomers growing, and their termination to give paraffins or olefins. The aim of this study is to modify the physicochemical properties of activated carbon by introducing a heteroatom of nitrogen, e.g. urea, and investigate the effect of promoters on urea-doped activated carbon supported iron catalyst. Thus, a series of catalysts have been prepared and tested under F-T to olefin reaction conditions and their catalytic nature has been interpreted in relation to their physicochemical properties.",

keywords = "Activated carbon, catalyst, Fischer Tropsch, light olefin, support modification, urea",

author = "Pınar {\c S}akoğlu and Yasaman Fallahi and Osman Okur and Alper Sarıoğlan and H{\"u}sn{\"u} Atak{\"u}l and G{\"u}r, \{Gamze G{\"u}m{\"u}{\c s}l{\"u}\}",

note = "Publisher Copyright: {\textcopyright} 2022, ETA-Florence Renewable Energies., All rights reserved.; 30th European Biomass Conference and Exhibition, EUBCE 2022 ; Conference date: 09-05-2022 Through 12-05-2022",

year = "2022",

language = "English",

pages = "1082--1087",

journal = "European Biomass Conference and Exhibition Proceedings",

issn = "2282-5819",

publisher = "ETA-Florence Renewable Energies",

}

FISCHER-TROPSCH TO OLEFIN REACTION OVER CARBON SUPPORTED IRON CATALYSTS: INVESTIGATION OF UREA DOPED ACTIVATED CARBON IN THE PRESENCE OF SODIUM AND ZINC PROMOTERS. / Şakoğlu, Pınar; Fallahi, Yasaman; Okur, Osman et al.
In: European Biomass Conference and Exhibition Proceedings, 2022, p. 1082-1087.

Araştırma sonucu: Dergiye katkı › Konferans makalesi › bilirkişi

TY - JOUR

T1 - FISCHER-TROPSCH TO OLEFIN REACTION OVER CARBON SUPPORTED IRON CATALYSTS

T2 - 30th European Biomass Conference and Exhibition, EUBCE 2022

AU - Şakoğlu, Pınar

AU - Fallahi, Yasaman

AU - Okur, Osman

AU - Sarıoğlan, Alper

AU - Atakül, Hüsnü

AU - Gür, Gamze Gümüşlü

PY - 2022

Y1 - 2022

N2 - The Fischer-Tropsch (F-T) reaction has been successfully applied for decades for conventional liquid fuel and wax production. F-T presents a promising direct reaction pathway, for light olefins (formula presented), the building blocks of the plastic industry. However, a catalyst that meets all the criteria of activity, stability, and selectivity has not yet been discovered for light olefin production. There are still unresolved issues like iron-support interaction and the secondary metals contributing to the surface reactions such as CO dissociation, surface-bound (-CHx-) monomers growing, and their termination to give paraffins or olefins. The aim of this study is to modify the physicochemical properties of activated carbon by introducing a heteroatom of nitrogen, e.g. urea, and investigate the effect of promoters on urea-doped activated carbon supported iron catalyst. Thus, a series of catalysts have been prepared and tested under F-T to olefin reaction conditions and their catalytic nature has been interpreted in relation to their physicochemical properties.

AB - The Fischer-Tropsch (F-T) reaction has been successfully applied for decades for conventional liquid fuel and wax production. F-T presents a promising direct reaction pathway, for light olefins (formula presented), the building blocks of the plastic industry. However, a catalyst that meets all the criteria of activity, stability, and selectivity has not yet been discovered for light olefin production. There are still unresolved issues like iron-support interaction and the secondary metals contributing to the surface reactions such as CO dissociation, surface-bound (-CHx-) monomers growing, and their termination to give paraffins or olefins. The aim of this study is to modify the physicochemical properties of activated carbon by introducing a heteroatom of nitrogen, e.g. urea, and investigate the effect of promoters on urea-doped activated carbon supported iron catalyst. Thus, a series of catalysts have been prepared and tested under F-T to olefin reaction conditions and their catalytic nature has been interpreted in relation to their physicochemical properties.

KW - Activated carbon

KW - catalyst

KW - Fischer Tropsch

KW - light olefin

KW - support modification

KW - urea

UR - https://www.scopus.com/pages/publications/85142523388

M3 - Conference article

AN - SCOPUS:85142523388

SN - 2282-5819

SP - 1082

EP - 1087

JO - European Biomass Conference and Exhibition Proceedings

JF - European Biomass Conference and Exhibition Proceedings

Y2 - 9 May 2022 through 12 May 2022

ER -

FISCHER-TROPSCH TO OLEFIN REACTION OVER CARBON SUPPORTED IRON CATALYSTS: INVESTIGATION OF UREA DOPED ACTIVATED CARBON IN THE PRESENCE OF SODIUM AND ZINC PROMOTERS

Özet

Bibliyografik not

Finansman

BM SKH

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap