Ffast transient fluorescence technique to study critical exponents at the glass transition

Demet Kaya, Önder Pekcan, Yaşar Yilmaz*

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19 Atıf (Scopus)

Özet

The fast transient fluorescence (FTRF) technique was used to study critical exponents at the glass transition in free-radical crosslinking copolymerization (FCC) for two different monomeric systems, methyl methacrylate (MMA) and styrene (S). Pyrene (Py) was used as a fluorescence probe. The fluorescence lifetimes of Py from its decay traces were measured and used to monitor the gelation process. Changes in the viscosity of the pregel solutions due to glass formation dramatically enhance the fluorescent yield of aromatic molecules. This effect is used to study the glass transition upon gelation of MMA and S monomeric systems as a function of time, at various temperatures and crosslinker concentrations. The results arc interpreted in the view of percolation theory. The gel fraction and weight average degree of polymerization exponents β and γ are found to be 0.37 ± 0.02 and 1.66 ± 0.07 in agreement with percolation results.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)543-556
Sayfa sayısı14
DergiPhase Transitions
Hacim76
Basın numarası6
DOI'lar
Yayın durumuYayınlandı - 2003

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