EPR spectra of Cu2+ in KH2PO4 single crystals

Recep Biyik; Recep Tapramaz

doi:10.1016/j.saa.2007.03.029

EPR spectra of Cu²⁺ in KH₂PO₄ single crystals

Recep Biyik^*
, Recep Tapramaz

^*Bu çalışma için yazışmadan sorumlu yazar

Sarayköy Nuclear Research and Training Center
Ondokuz Mayis University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

12 Atıf (Scopus)

Özet

Cu²⁺ doped single crystals of KH₂PO₄ were investigated using EPR technique at room temperature. The spectra of the complex contains large number of overlapping lines. Five sites are resolved and four of them are compatible with the tetragonal symmetry, and the fifth one belongs to an interstitial site. The results are discussed and compared with previous studies. Detailed investigation of the EPR spectra indicate that Cu²⁺ substitute with K⁺ ions. The principal values of the g and hyperfine tensors and the ground state wave function of Cu²⁺ ions are obtained.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	174-177
Sayfa sayısı	4
Dergi	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Hacim	69
Basın numarası	1
DOI'lar	https://doi.org/10.1016/j.saa.2007.03.029
Yayın durumu	Yayınlandı - Oca 2008
Harici olarak yayınlandı	Evet

Belgeye Erişim

10.1016/j.saa.2007.03.029

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "EPR spectra of Cu2+ in KH2PO4 single crystals",

abstract = "Cu2+ doped single crystals of KH2PO4 were investigated using EPR technique at room temperature. The spectra of the complex contains large number of overlapping lines. Five sites are resolved and four of them are compatible with the tetragonal symmetry, and the fifth one belongs to an interstitial site. The results are discussed and compared with previous studies. Detailed investigation of the EPR spectra indicate that Cu2+ substitute with K+ ions. The principal values of the g and hyperfine tensors and the ground state wave function of Cu2+ ions are obtained.",

keywords = "Cu, EPR, Ground state wave function, KDP",

author = "Recep Biyik and Recep Tapramaz",

year = "2008",

month = jan,

doi = "10.1016/j.saa.2007.03.029",

language = "English",

volume = "69",

pages = "174--177",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

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T1 - EPR spectra of Cu2+ in KH2PO4 single crystals

AU - Biyik, Recep

AU - Tapramaz, Recep

PY - 2008/1

Y1 - 2008/1

N2 - Cu2+ doped single crystals of KH2PO4 were investigated using EPR technique at room temperature. The spectra of the complex contains large number of overlapping lines. Five sites are resolved and four of them are compatible with the tetragonal symmetry, and the fifth one belongs to an interstitial site. The results are discussed and compared with previous studies. Detailed investigation of the EPR spectra indicate that Cu2+ substitute with K+ ions. The principal values of the g and hyperfine tensors and the ground state wave function of Cu2+ ions are obtained.

AB - Cu2+ doped single crystals of KH2PO4 were investigated using EPR technique at room temperature. The spectra of the complex contains large number of overlapping lines. Five sites are resolved and four of them are compatible with the tetragonal symmetry, and the fifth one belongs to an interstitial site. The results are discussed and compared with previous studies. Detailed investigation of the EPR spectra indicate that Cu2+ substitute with K+ ions. The principal values of the g and hyperfine tensors and the ground state wave function of Cu2+ ions are obtained.

KW - Cu

KW - EPR

KW - Ground state wave function

KW - KDP

UR - https://www.scopus.com/pages/publications/37349085313

U2 - 10.1016/j.saa.2007.03.029

DO - 10.1016/j.saa.2007.03.029

M3 - Article

C2 - 17466573

AN - SCOPUS:37349085313

SN - 1386-1425

VL - 69

SP - 174

EP - 177

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

IS - 1