Özet
A new aryl amide type podand (AAP), 1,8-bis(o-amidophenoxy)-3,6-dioxaoctane, was synthesized and its mercury ion binding property was elucidated by electrochemical and fluorescence measurements. The effects of supporting electrolyte, pH and scan rate on the electroreduction of AAP and on cyclic voltommogram of mercury ion were investigated by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). It was observed that the complex formation between AAP and mercury ion exhibited pH-dependent behavior in different electrolyte solutions. Elucidation of such properties makes the AAP intriguing candidates as a modifying agent in sensor application for determination of mercury ion in mixture of aqueous solution.
Orijinal dil | İngilizce |
---|---|
Sayfa (başlangıç-bitiş) | 2879-2892 |
Sayfa sayısı | 14 |
Dergi | Analytical Letters |
Hacim | 42 |
Basın numarası | 17 |
DOI'lar | |
Yayın durumu | Yayınlandı - Oca 2009 |
Finansman
Received 4 October 2008; accepted 14 July 2009. This article is dedicated to the late Prof. Dr. C¸ akıl Erk who inspired this research. This work has been supported by the Scientific and Technical Research Council of Turkey (TUBITAK project no. 104T079). Address correspondence to Gülcemal Yıldız, Istanbul Technical University, Faculty of Science and the Letters, Chemistry Department, Istanbul Technical University, Faculty of Science and Letters, Chemical Department, Maslak-Sary´yer, Istanbul 34469, Turkey. E-mail: [email protected]
Finansörler | Finansör numarası |
---|---|
TUBITAK | 104T079 |
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu |