Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Zehra Yildiz; Hacer Aysen Onen; Atilla Gungor; Youjiang Wang; Karl Jacob

doi:10.1080/03602559.2017.1364382

Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Zehra Yildiz
, Hacer Aysen Onen^*
, Atilla Gungor
, Youjiang Wang
, Karl Jacob

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University
Marmara University
Georgia Institute of Technology

Araştırma çıktısı: Dergi yayını › Makale › Hakem

15 Atıf (Scopus)

Özet

A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm⁻¹ was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	935-944
Sayfa sayısı	10
Dergi	Polymer - Plastics Technology and Engineering
Hacim	57
Basın numarası	10
DOI'lar	https://doi.org/10.1080/03602559.2017.1364382
Yayın durumu	Yayınlandı - 3 Tem 2018

Bibliyografik not

Publisher Copyright:
© 2017 Taylor & Francis.

Finansman

This study has been financially supported by Istanbul Technical University Research Fund and The Scientific and Technological Research Council of Turkey (TUBITAK).

Finansörler
Istanbul Technical University Research Fund
TUBITAK
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu

Belgeye Erişim

10.1080/03602559.2017.1364382

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites",

abstract = "A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent.",

keywords = "Adhesion strength, NCO:OH ratio, UV curing, polyester cord, reactive diluent, styrene butadiene rubber",

author = "Zehra Yildiz and Onen, \{Hacer Aysen\} and Atilla Gungor and Youjiang Wang and Karl Jacob",

note = "Publisher Copyright: {\textcopyright} 2017 Taylor \& Francis.",

year = "2018",

month = jul,

day = "3",

doi = "10.1080/03602559.2017.1364382",

language = "English",

volume = "57",

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TY - JOUR

T1 - Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

AU - Yildiz, Zehra

AU - Onen, Hacer Aysen

AU - Gungor, Atilla

AU - Wang, Youjiang

AU - Jacob, Karl

PY - 2018/7/3

Y1 - 2018/7/3

N2 - A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent.

AB - A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103 N cm−1 was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent.

KW - Adhesion strength

KW - NCO:OH ratio

KW - UV curing

KW - polyester cord

KW - reactive diluent

KW - styrene butadiene rubber

UR - https://www.scopus.com/pages/publications/85030572293

U2 - 10.1080/03602559.2017.1364382

DO - 10.1080/03602559.2017.1364382

M3 - Article

AN - SCOPUS:85030572293

SN - 0360-2559

VL - 57

SP - 935

EP - 944

JO - Polymer - Plastics Technology and Engineering

JF - Polymer - Plastics Technology and Engineering

IS - 10

ER -

Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap