Effects of molecular weight, stereo configuration of PLA, and processing on the dispersion of multiwalled carbon nanotubes and properties of corresponding nanocomposites

Mojtaba Mohammadi, Yingjie Li, Jed Randall, Mohammadreza Nofar, Marie Claude Heuzey*, Pierre J. Carreau*

*Bu çalışma için yazışmadan sorumlu yazar

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Özet

Multiwalled carbon nanotubes (MWCNTs) were dispersed and distributed via a co-rotating twin-screw extruder (TSE) in high (h)- and low (l)-molecular-weight amorphous and semicrystalline polylactides (PLAs) (aPLA and scPLA, respectively). Effects of PLA molecular weight and D-lactic acid equivalents content (D-content), as well as processing parameters, were examined on the MWCNT dispersion quality in PLA. The effectiveness of the MWCNT dispersion in various PLA matrices was investigated using scanning electron microscopy (SEM) and small-amplitude oscillatory and transient shear flow rheometry in the molten state. The results showed a better dispersion of MWCNTs in the low-molecular-weight PLA grades (aPLAl and scPLAl). In addition, better MWCNT dispersion was observed in aPLA grades when processed at a higher temperature of 190°C than at 150°C. At 150°C, while MWCNT bundles in aPLAl could be broken down, a good dispersion could not be achieved in aPLAh due to the lower molecular mobility at such a temperature. The electrical conductivity of the samples was also shown to increase as the MWCNT dispersion was improved. The existence of crystallites in scPLA-based nanocomposites, however, disrupted the connectivity of the MWCNTs and decreased the final electrical conductivity. The lower molecular weight aPLAl prepared at 190°C showed the highest electrical conductivity (~10−5 S/m) at a low loading of 0.5 wt.% MWCNTs.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)5729-5742
Sayfa sayısı14
DergiCanadian Journal of Chemical Engineering
Hacim101
Basın numarası10
DOI'lar
Yayın durumuYayınlandı - Eki 2023

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Publisher Copyright:
© 2023 The Authors. The Canadian Journal of Chemical Engineering published by Wiley Periodicals LLC on behalf of Canadian Society for Chemical Engineering.

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