Effect of sonication power on Al2O3 coated LiNi0.5Mn0.3Co0.2O2 cathode material for LIB

Dila Sivlin; Ozgul Keles

doi:10.1007/978-3-319-72362-4_48

Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB

Dila Sivlin, Ozgul Keles^*

^*Bu çalışma için yazışmadan sorumlu yazar

Metalurji ve Malzeme Müh.Böl.

Istanbul Technical University

Araştırma sonucu: Kitap/Rapor/Konferans Bildirisinde Bölüm › Konferans katkısı › bilirkişi

2 Atıf (Scopus)

Özet

Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al₂O₃ coating on LiNi_0.5Mn_0.3Co_0.2O₂ cathode material produced by sol—gel method. The surface modification of LiNi_0.5Mn_0.3Co_0,2O₂ was started by adding LiNi_0.5Mn_0.3Co_0.2O₂ powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al₂O₃ crystallization was done at 600 °C for 4 h. X—ray diffraction (XRD) measurements showed that the material had a well—ordered layered structure and Al was not in the LiNi_0.5Mn_0.3Co_0.2O₂. Al₂O₃ coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al₂O₃ layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.

Orijinal dil	İngilizce
Ana bilgisayar yayını başlığı	Energy Technology 2018 - Carbon Dioxide Management and Other Technologies
Editörler	Sarma Pisupati, Lei Zhang, Allie Anderson, Shadia Ikhmayies, York R. Smith, Mingming Zhang, Xiaofei Guan, Huimin Lu, Amit Pandey, Dirk Verhulst, Ziqi Sun, Neale R. Neelameggham, Elsa Olivetti, Cong Wang, Donna Post Guillen, John A. Howarter, Tao Wang
Yayınlayan	Springer International Publishing
Sayfalar	515-522
Sayfa sayısı	8
ISBN (Basılı)	9783319723617
DOI'lar	https://doi.org/10.1007/978-3-319-72362-4_48
Yayın durumu	Yayınlandı - 2018
Etkinlik	Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018 - Phoenix, United States Süre: 11 Mar 2018 → 15 Mar 2018

Yayın serisi

Adı	Minerals, Metals and Materials Series
Hacim	Part F6
ISSN (Basılı)	2367-1181
ISSN (Elektronik)	2367-1696

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???event.eventtypes.event.conference???	Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018
Ülke/Bölge	United States
Şehir	Phoenix
Periyot	11/03/18 → 15/03/18

Bibliyografik not

Publisher Copyright:
© 2018, The Minerals, Metals & Materials Society.

BM SKH

Bu sonuç, aşağıdaki Sürdürülebilir Kalkınma Hedefine/Hedeflerine katkıda bulunur

Belgeye Erişim

10.1007/978-3-319-72362-4_48

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

Sivlin, D., & Keles, O. (2018). Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. In S. Pisupati, L. Zhang, A. Anderson, S. Ikhmayies, Y. R. Smith, M. Zhang, X. Guan, H. Lu, A. Pandey, D. Verhulst, Z. Sun, N. R. Neelameggham, E. Olivetti, C. Wang, D. P. Guillen, J. A. Howarter, & T. Wang (Eds.), Energy Technology 2018 - Carbon Dioxide Management and Other Technologies (pp. 515-522). (Minerals, Metals and Materials Series; Hac. Part F6). Springer International Publishing. https://doi.org/10.1007/978-3-319-72362-4_48

Sivlin, Dila ; Keles, Ozgul. / Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. Energy Technology 2018 - Carbon Dioxide Management and Other Technologies. editör / Sarma Pisupati ; Lei Zhang ; Allie Anderson ; Shadia Ikhmayies ; York R. Smith ; Mingming Zhang ; Xiaofei Guan ; Huimin Lu ; Amit Pandey ; Dirk Verhulst ; Ziqi Sun ; Neale R. Neelameggham ; Elsa Olivetti ; Cong Wang ; Donna Post Guillen ; John A. Howarter ; Tao Wang. Springer International Publishing, 2018. pp. 515-522 (Minerals, Metals and Materials Series).

@inproceedings{c57d36b9b0bc42f1adbb0af22a8699ad,

title = "Effect of sonication power on Al2O3 coated LiNi0.5Mn0.3Co0.2O2 cathode material for LIB",

abstract = "Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al2O3 coating on LiNi0.5Mn0.3Co0.2O2 cathode material produced by sol—gel method. The surface modification of LiNi0.5Mn0.3Co0,2O2 was started by adding LiNi0.5Mn0.3Co0.2O2 powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al2O3 crystallization was done at 600 °C for 4 h. X—ray diffraction (XRD) measurements showed that the material had a well—ordered layered structure and Al was not in the LiNi0.5Mn0.3Co0.2O2. Al2O3 coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al2O3 layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.",

keywords = "AlO coating, Lithium ion batteries, NMC cathode materials, Surface modification",

author = "Dila Sivlin and Ozgul Keles",

note = "Publisher Copyright: {\textcopyright} 2018, The Minerals, Metals & Materials Society.; Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018 ; Conference date: 11-03-2018 Through 15-03-2018",

year = "2018",

doi = "10.1007/978-3-319-72362-4_48",

language = "English",

isbn = "9783319723617",

series = "Minerals, Metals and Materials Series",

publisher = "Springer International Publishing",

pages = "515--522",

editor = "Sarma Pisupati and Lei Zhang and Allie Anderson and Shadia Ikhmayies and Smith, {York R.} and Mingming Zhang and Xiaofei Guan and Huimin Lu and Amit Pandey and Dirk Verhulst and Ziqi Sun and Neelameggham, {Neale R.} and Elsa Olivetti and Cong Wang and Guillen, {Donna Post} and Howarter, {John A.} and Tao Wang",

booktitle = "Energy Technology 2018 - Carbon Dioxide Management and Other Technologies",

address = "Switzerland",

}

Sivlin, D & Keles, O 2018, Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. in S Pisupati, L Zhang, A Anderson, S Ikhmayies, YR Smith, M Zhang, X Guan, H Lu, A Pandey, D Verhulst, Z Sun, NR Neelameggham, E Olivetti, C Wang, DP Guillen, JA Howarter & T Wang (eds), Energy Technology 2018 - Carbon Dioxide Management and Other Technologies. Minerals, Metals and Materials Series, hac. Part F6, Springer International Publishing, pp. 515-522, Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018, Phoenix, United States, 11/03/18. https://doi.org/10.1007/978-3-319-72362-4_48

Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. / Sivlin, Dila; Keles, Ozgul.
Energy Technology 2018 - Carbon Dioxide Management and Other Technologies. ed. / Sarma Pisupati; Lei Zhang; Allie Anderson; Shadia Ikhmayies; York R. Smith; Mingming Zhang; Xiaofei Guan; Huimin Lu; Amit Pandey; Dirk Verhulst; Ziqi Sun; Neale R. Neelameggham; Elsa Olivetti; Cong Wang; Donna Post Guillen; John A. Howarter; Tao Wang. Springer International Publishing, 2018. p. 515-522 (Minerals, Metals and Materials Series; Hac. Part F6).

Araştırma sonucu: Kitap/Rapor/Konferans Bildirisinde Bölüm › Konferans katkısı › bilirkişi

TY - GEN

T1 - Effect of sonication power on Al2O3 coated LiNi0.5Mn0.3Co0.2O2 cathode material for LIB

AU - Sivlin, Dila

AU - Keles, Ozgul

PY - 2018

Y1 - 2018

N2 - Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al2O3 coating on LiNi0.5Mn0.3Co0.2O2 cathode material produced by sol—gel method. The surface modification of LiNi0.5Mn0.3Co0,2O2 was started by adding LiNi0.5Mn0.3Co0.2O2 powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al2O3 crystallization was done at 600 °C for 4 h. X—ray diffraction (XRD) measurements showed that the material had a well—ordered layered structure and Al was not in the LiNi0.5Mn0.3Co0.2O2. Al2O3 coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al2O3 layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.

AB - Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al2O3 coating on LiNi0.5Mn0.3Co0.2O2 cathode material produced by sol—gel method. The surface modification of LiNi0.5Mn0.3Co0,2O2 was started by adding LiNi0.5Mn0.3Co0.2O2 powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al2O3 crystallization was done at 600 °C for 4 h. X—ray diffraction (XRD) measurements showed that the material had a well—ordered layered structure and Al was not in the LiNi0.5Mn0.3Co0.2O2. Al2O3 coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al2O3 layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.

KW - AlO coating

KW - Lithium ion batteries

KW - NMC cathode materials

KW - Surface modification

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U2 - 10.1007/978-3-319-72362-4_48

DO - 10.1007/978-3-319-72362-4_48

M3 - Conference contribution

AN - SCOPUS:85042288508

SN - 9783319723617

T3 - Minerals, Metals and Materials Series

SP - 515

EP - 522

BT - Energy Technology 2018 - Carbon Dioxide Management and Other Technologies

A2 - Pisupati, Sarma

A2 - Zhang, Lei

A2 - Anderson, Allie

A2 - Ikhmayies, Shadia

A2 - Smith, York R.

A2 - Zhang, Mingming

A2 - Guan, Xiaofei

A2 - Lu, Huimin

A2 - Pandey, Amit

A2 - Verhulst, Dirk

A2 - Sun, Ziqi

A2 - Neelameggham, Neale R.

A2 - Olivetti, Elsa

A2 - Wang, Cong

A2 - Guillen, Donna Post

A2 - Howarter, John A.

A2 - Wang, Tao

PB - Springer International Publishing

T2 - Energy Technologies Symposium organized in conjunction with the Annual Meeting and Exhibition, TMS 2018

Y2 - 11 March 2018 through 15 March 2018

ER -

Sivlin D, Keles O. Effect of sonication power on Al₂O₃ coated LiNi_0.5Mn_0.3Co_0.2O₂ cathode material for LIB. In Pisupati S, Zhang L, Anderson A, Ikhmayies S, Smith YR, Zhang M, Guan X, Lu H, Pandey A, Verhulst D, Sun Z, Neelameggham NR, Olivetti E, Wang C, Guillen DP, Howarter JA, Wang T, editörler, Energy Technology 2018 - Carbon Dioxide Management and Other Technologies. Springer International Publishing. 2018. p. 515-522. (Minerals, Metals and Materials Series). doi: 10.1007/978-3-319-72362-4_48