Development of self-assembled poly(2-ethyl-2-oxazoline)-b-poly(ε-caprolactone) (petox-b-pcl) copolymeric nanostructures in aqueous solution and evaluation of their morphological transitions

U. U. Ozkose; S. Gulyuz; U. C. Oz; M. A. Tasdelen; O. Alpturk; A. Bozkir; O. Yilmaz

doi:10.3144/expresspolymlett.2020.85

Development of self-assembled poly(2-ethyl-2-oxazoline)-b-poly(ε-caprolactone) (petox-b-pcl) copolymeric nanostructures in aqueous solution and evaluation of their morphological transitions

U. U. Ozkose
, S. Gulyuz
, U. C. Oz
, M. A. Tasdelen
, O. Alpturk
, A. Bozkir
, O. Yilmaz^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University
Scientific and Technological Research Council of Turkey
Piri Reis University
Ankara University
Yalova University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

4 Atıf (Scopus)

Özet

. Amphiphilic block copolymers are known to self-assemble into various morphologies, including ellipsoids, tubular structures, toroids, vesicles, micellar structures. In this paper, we discuss the synthesis of copolymeric nanostructures (CNs) using poly(2-ethyl-2-oxazoline)-block-poly(ε-caprolactone) (PEtOx-b-PCL) amphiphilic block copolymers. Our data indicate that-varying the molecular weight and the number of repeating units dictate the nature of morphology. That is, the formation of self-assembled morphologies from ellipsoid to rod-like architectures are observed in aqueous solution, depending on the mass ratio of the hydrophilic block (f_PEtOx). To best of our knowledge, this is the first report on the morphological transitions of PEtOx-b-PCL amphiphilic block copolymer-based CNs with different f_PEtOx values in the literature.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1048-1062
Sayfa sayısı	15
Dergi	Express Polymer Letters
Hacim	14
Basın numarası	11
DOI'lar	https://doi.org/10.3144/expresspolymlett.2020.85
Yayın durumu	Yayınlandı - Kas 2020

Bibliyografik not

Publisher Copyright:
© BME-PT.

Finansman

The authors would like to thank the Scientific and Technological Research Council of Turkey (TUBITAK) for financial supports with grant number of 213M725.

Finansörler	Finansör numarası
TUBITAK
Türkiye Bilimsel ve Teknolojik Araştırma Kurumu	213M725

Belgeye Erişim

10.3144/expresspolymlett.2020.85

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

Ozkose, U. U., Gulyuz, S., Oz, U. C., Tasdelen, M. A., Alpturk, O., Bozkir, A., & Yilmaz, O. (2020). Development of self-assembled poly(2-ethyl-2-oxazoline)-b-poly(ε-caprolactone) (petox-b-pcl) copolymeric nanostructures in aqueous solution and evaluation of their morphological transitions. Express Polymer Letters, 14(11), 1048-1062. https://doi.org/10.3144/expresspolymlett.2020.85

@article{f0f6258164574843a4490b2f1d8f6c6e,

title = "Development of self-assembled poly(2-ethyl-2-oxazoline)-b-poly(ε-caprolactone) (petox-b-pcl) copolymeric nanostructures in aqueous solution and evaluation of their morphological transitions",

abstract = ". Amphiphilic block copolymers are known to self-assemble into various morphologies, including ellipsoids, tubular structures, toroids, vesicles, micellar structures. In this paper, we discuss the synthesis of copolymeric nanostructures (CNs) using poly(2-ethyl-2-oxazoline)-block-poly(ε-caprolactone) (PEtOx-b-PCL) amphiphilic block copolymers. Our data indicate that-varying the molecular weight and the number of repeating units dictate the nature of morphology. That is, the formation of self-assembled morphologies from ellipsoid to rod-like architectures are observed in aqueous solution, depending on the mass ratio of the hydrophilic block (fPEtOx). To best of our knowledge, this is the first report on the morphological transitions of PEtOx-b-PCL amphiphilic block copolymer-based CNs with different fPEtOx values in the literature.",

keywords = "Amphiphilic block copolymers, Morphological transition, Nanomaterials, Poly(2-ethyl-2-oxazoline), Self-assembly",

author = "Ozkose, \{U. U.\} and S. Gulyuz and Oz, \{U. C.\} and Tasdelen, \{M. A.\} and O. Alpturk and A. Bozkir and O. Yilmaz",

note = "Publisher Copyright: {\textcopyright} BME-PT.",

year = "2020",

month = nov,

doi = "10.3144/expresspolymlett.2020.85",

language = "English",

volume = "14",

pages = "1048--1062",

journal = "Express Polymer Letters",

issn = "1788-618X",

publisher = "BME-PT and GTE",

number = "11",

}

Ozkose, UU, Gulyuz, S, Oz, UC, Tasdelen, MA, Alpturk, O, Bozkir, A & Yilmaz, O 2020, 'Development of self-assembled poly(2-ethyl-2-oxazoline)-b-poly(ε-caprolactone) (petox-b-pcl) copolymeric nanostructures in aqueous solution and evaluation of their morphological transitions', Express Polymer Letters, hac. 14, no. 11, pp. 1048-1062. https://doi.org/10.3144/expresspolymlett.2020.85

TY - JOUR

T1 - Development of self-assembled poly(2-ethyl-2-oxazoline)-b-poly(ε-caprolactone) (petox-b-pcl) copolymeric nanostructures in aqueous solution and evaluation of their morphological transitions

AU - Ozkose, U. U.

AU - Gulyuz, S.

AU - Oz, U. C.

AU - Tasdelen, M. A.

AU - Alpturk, O.

AU - Bozkir, A.

AU - Yilmaz, O.

PY - 2020/11

Y1 - 2020/11

N2 - . Amphiphilic block copolymers are known to self-assemble into various morphologies, including ellipsoids, tubular structures, toroids, vesicles, micellar structures. In this paper, we discuss the synthesis of copolymeric nanostructures (CNs) using poly(2-ethyl-2-oxazoline)-block-poly(ε-caprolactone) (PEtOx-b-PCL) amphiphilic block copolymers. Our data indicate that-varying the molecular weight and the number of repeating units dictate the nature of morphology. That is, the formation of self-assembled morphologies from ellipsoid to rod-like architectures are observed in aqueous solution, depending on the mass ratio of the hydrophilic block (fPEtOx). To best of our knowledge, this is the first report on the morphological transitions of PEtOx-b-PCL amphiphilic block copolymer-based CNs with different fPEtOx values in the literature.

AB - . Amphiphilic block copolymers are known to self-assemble into various morphologies, including ellipsoids, tubular structures, toroids, vesicles, micellar structures. In this paper, we discuss the synthesis of copolymeric nanostructures (CNs) using poly(2-ethyl-2-oxazoline)-block-poly(ε-caprolactone) (PEtOx-b-PCL) amphiphilic block copolymers. Our data indicate that-varying the molecular weight and the number of repeating units dictate the nature of morphology. That is, the formation of self-assembled morphologies from ellipsoid to rod-like architectures are observed in aqueous solution, depending on the mass ratio of the hydrophilic block (fPEtOx). To best of our knowledge, this is the first report on the morphological transitions of PEtOx-b-PCL amphiphilic block copolymer-based CNs with different fPEtOx values in the literature.

KW - Amphiphilic block copolymers

KW - Morphological transition

KW - Nanomaterials

KW - Poly(2-ethyl-2-oxazoline)

KW - Self-assembly

UR - https://www.scopus.com/pages/publications/85093888970

U2 - 10.3144/expresspolymlett.2020.85

DO - 10.3144/expresspolymlett.2020.85

M3 - Article

AN - SCOPUS:85093888970

SN - 1788-618X

VL - 14

SP - 1048

EP - 1062

JO - Express Polymer Letters

JF - Express Polymer Letters

IS - 11

ER -

Development of self-assembled poly(2-ethyl-2-oxazoline)-b-poly(ε-caprolactone) (petox-b-pcl) copolymeric nanostructures in aqueous solution and evaluation of their morphological transitions

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap