Development of heat storing poly(acrylonitrile) nanofibers by coaxial electrospinning

Ezgi C.B. Noyan; Emel Onder; Nihal Sarier; Refik Arat

doi:10.1016/j.tca.2018.02.008

Development of heat storing poly(acrylonitrile) nanofibers by coaxial electrospinning

Ezgi C.B. Noyan, Emel Onder^*, Nihal Sarier, Refik Arat

^*Bu çalışma için yazışmadan sorumlu yazar

Tekstil Mühendisliği Bölümü

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

34 Atıf (Scopus)

Özet

New thermal energy storage materials were developed as poly(acrylonitrile) (PAN) nanofibers with encapsulated phase change materials (PCMs). Sixteen samples composed of PAN shells and PEG or PEGME cores, and one control sample composed of only a PAN shell, were manufactured by coaxial electrospinning. SEM images revealed the formation of randomly distributed, distinct nanofibers with smooth surfaces and cylindrical shapes along their lengths. FTIR results confirmed bicomponent nanofiber structures and TGA results demonstrated their thermal stabilities. Phase change performances of nanofibers were repeatedly examined by DSC analyzes; heating enthalpies ranged from 38 to 133 J g⁻¹ and from 29 to 60 J g⁻¹ for PAN-PEGs and PAN-PEGME samples, respectively, corresponding to good encapsulation efficiencies. These remarkable thermal energy storages were achieved at different melting temperatures (−1 to 60 °C). Textile based sandwich structures containing three different types of PAN-PCM nanowebs demonstrated enhanced thermal properties and buffering function against temperature changes in surrounding.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	135-148
Sayfa sayısı	14
Dergi	Thermochimica Acta
Hacim	662
DOI'lar	https://doi.org/10.1016/j.tca.2018.02.008
Yayın durumu	Yayınlandı - 10 Nis 2018

Bibliyografik not

Publisher Copyright:
© 2018 Elsevier B.V.

Finansman

This work was supported by the Scientific & Technological Research Council of Turkey [TUBITAK213M281], Istanbul Technical University and Istanbul Kültür University. We wish to thank Arçelik A.Ş for their thermal conductivity measurements. This work was supported by the Scientific & Technological Research Council of Turkey [ TUBITAK213M281 ], Istanbul Technical University and Istanbul Kültür University . We wish to thank Arçelik A.Ş for their thermal conductivity measurements.

Finansörler	Finansör numarası
Scientific & Technological Research Council of Turkey
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	TUBITAK213M281
T.C. İstanbul Kültür Üniversitesi
Istanbul Teknik Üniversitesi

Belgeye Erişim

10.1016/j.tca.2018.02.008

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Development of heat storing poly(acrylonitrile) nanofibers by coaxial electrospinning",

abstract = "New thermal energy storage materials were developed as poly(acrylonitrile) (PAN) nanofibers with encapsulated phase change materials (PCMs). Sixteen samples composed of PAN shells and PEG or PEGME cores, and one control sample composed of only a PAN shell, were manufactured by coaxial electrospinning. SEM images revealed the formation of randomly distributed, distinct nanofibers with smooth surfaces and cylindrical shapes along their lengths. FTIR results confirmed bicomponent nanofiber structures and TGA results demonstrated their thermal stabilities. Phase change performances of nanofibers were repeatedly examined by DSC analyzes; heating enthalpies ranged from 38 to 133 J g−1 and from 29 to 60 J g−1 for PAN-PEGs and PAN-PEGME samples, respectively, corresponding to good encapsulation efficiencies. These remarkable thermal energy storages were achieved at different melting temperatures (−1 to 60 °C). Textile based sandwich structures containing three different types of PAN-PCM nanowebs demonstrated enhanced thermal properties and buffering function against temperature changes in surrounding.",

keywords = "Electrospinning, Energy materials, Nanocomposites, Thermal properties",

author = "Noyan, {Ezgi C.B.} and Emel Onder and Nihal Sarier and Refik Arat",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2018",

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day = "10",

doi = "10.1016/j.tca.2018.02.008",

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T1 - Development of heat storing poly(acrylonitrile) nanofibers by coaxial electrospinning

AU - Noyan, Ezgi C.B.

AU - Onder, Emel

AU - Sarier, Nihal

AU - Arat, Refik

PY - 2018/4/10

Y1 - 2018/4/10

N2 - New thermal energy storage materials were developed as poly(acrylonitrile) (PAN) nanofibers with encapsulated phase change materials (PCMs). Sixteen samples composed of PAN shells and PEG or PEGME cores, and one control sample composed of only a PAN shell, were manufactured by coaxial electrospinning. SEM images revealed the formation of randomly distributed, distinct nanofibers with smooth surfaces and cylindrical shapes along their lengths. FTIR results confirmed bicomponent nanofiber structures and TGA results demonstrated their thermal stabilities. Phase change performances of nanofibers were repeatedly examined by DSC analyzes; heating enthalpies ranged from 38 to 133 J g−1 and from 29 to 60 J g−1 for PAN-PEGs and PAN-PEGME samples, respectively, corresponding to good encapsulation efficiencies. These remarkable thermal energy storages were achieved at different melting temperatures (−1 to 60 °C). Textile based sandwich structures containing three different types of PAN-PCM nanowebs demonstrated enhanced thermal properties and buffering function against temperature changes in surrounding.

AB - New thermal energy storage materials were developed as poly(acrylonitrile) (PAN) nanofibers with encapsulated phase change materials (PCMs). Sixteen samples composed of PAN shells and PEG or PEGME cores, and one control sample composed of only a PAN shell, were manufactured by coaxial electrospinning. SEM images revealed the formation of randomly distributed, distinct nanofibers with smooth surfaces and cylindrical shapes along their lengths. FTIR results confirmed bicomponent nanofiber structures and TGA results demonstrated their thermal stabilities. Phase change performances of nanofibers were repeatedly examined by DSC analyzes; heating enthalpies ranged from 38 to 133 J g−1 and from 29 to 60 J g−1 for PAN-PEGs and PAN-PEGME samples, respectively, corresponding to good encapsulation efficiencies. These remarkable thermal energy storages were achieved at different melting temperatures (−1 to 60 °C). Textile based sandwich structures containing three different types of PAN-PCM nanowebs demonstrated enhanced thermal properties and buffering function against temperature changes in surrounding.

KW - Electrospinning

KW - Energy materials

KW - Nanocomposites

KW - Thermal properties

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DO - 10.1016/j.tca.2018.02.008

M3 - Article

AN - SCOPUS:85042849508

SN - 0040-6031

VL - 662

SP - 135

EP - 148

JO - Thermochimica Acta

JF - Thermochimica Acta

ER -

Development of heat storing poly(acrylonitrile) nanofibers by coaxial electrospinning

Özet

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Finansman

Belgeye Erişim

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