Developing of reticulated ceramic photocatalyst for efficient photocatalytic oxidation of gaseous toluene

Esra Buyukada-Kesici; Memnune Kardeş; Kübra Erturaç Karagöz; Gizem Başaran-Dindaş; Koray Öztürk; H. Cengiz Yatmaz; Derya Y. Koseoglu-Imer

doi:10.1016/j.cej.2022.140672

Developing of reticulated ceramic photocatalyst for efficient photocatalytic oxidation of gaseous toluene

Esra Buyukada-Kesici, Memnune Kardeş, Kübra Erturaç Karagöz, Gizem Başaran-Dindaş, Koray Öztürk, H. Cengiz Yatmaz, Derya Y. Koseoglu-Imer^*

^*Bu çalışma için yazışmadan sorumlu yazar

Çevre Mühendisliği Bölümü

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

10 Atıf (Scopus)

Özet

In this study, a reticulated ceramic photocatalyst was developed to conduct the photocatalytic oxidation of gaseous toluene at high concentration. Toluene was used as a target pollutant to be degraded mainly due to its high toxicity and health effect. It was aimed to prove the potential of reticulated ceramic material with open and interconnected porous structure, high mechanical property, high surface area and low cost for toxic gaseous removal. As a result of immobilizing the TiO₂ catalyst on the reticulated ceramic material with three different sintering temperatures, the best photocatalytic performance was observed at 800 °C of sintering temperature due to the anatase to rutile ratio of TiO₂ catalyst. Photocatalytic oxidation of toluene was conducted at continuous and periodic illumination and resulted in similar removal efficiency of toluene under both conditions. However, the removal efficiency of toluene was found as 71.21 % under continuous illumination, whereas it was 60.55 % under periodic illumination. The ceramic photocatalysts showed excellent stability in the photocatalytic oxidation of toluene for six cycles totally 9120 min.

Orijinal dil	İngilizce
Makale numarası	140672
Dergi	Chemical Engineering Journal
Hacim	455
DOI'lar	https://doi.org/10.1016/j.cej.2022.140672
Yayın durumu	Yayınlandı - 1 Oca 2023

Bibliyografik not

Publisher Copyright:
© 2022 Elsevier B.V.

Finansman

This article has been written within the scope of project numbered TUBITAK 118Y412. Authors are grateful to TUBITAK due to their financial support; Ahmet Nazim from Gebze Technical University for the SEM and XRD analysis; Ayse Busra Ozcan for the reactor drawing; Materials Science and Engineering Laboratory of Gebze Technical University for the production of reticulated ceramic material, and finally to the Environmental Laboratory of the Istanbul Technical University, where the assembly of the photocatalytic reactor and all other work was carried out.

Finansörler	Finansör numarası
Türkiye Bilimsel ve Teknolojik Araştırma Kurumu	118Y412
Istanbul Teknik Üniversitesi
Gebze Teknik Üniversitesi

BM SKH

Bu sonuç, aşağıdaki Sürdürülebilir Kalkınma Hedefine/Hedeflerine katkıda bulunur

Belgeye Erişim

10.1016/j.cej.2022.140672

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{1acfe7455c914a99bcf12ce6715ee774,

title = "Developing of reticulated ceramic photocatalyst for efficient photocatalytic oxidation of gaseous toluene",

abstract = "In this study, a reticulated ceramic photocatalyst was developed to conduct the photocatalytic oxidation of gaseous toluene at high concentration. Toluene was used as a target pollutant to be degraded mainly due to its high toxicity and health effect. It was aimed to prove the potential of reticulated ceramic material with open and interconnected porous structure, high mechanical property, high surface area and low cost for toxic gaseous removal. As a result of immobilizing the TiO2 catalyst on the reticulated ceramic material with three different sintering temperatures, the best photocatalytic performance was observed at 800 °C of sintering temperature due to the anatase to rutile ratio of TiO2 catalyst. Photocatalytic oxidation of toluene was conducted at continuous and periodic illumination and resulted in similar removal efficiency of toluene under both conditions. However, the removal efficiency of toluene was found as 71.21 % under continuous illumination, whereas it was 60.55 % under periodic illumination. The ceramic photocatalysts showed excellent stability in the photocatalytic oxidation of toluene for six cycles totally 9120 min.",

keywords = "Gaseous toluene, Photocatalytic oxidation, Reticulated ceramic photocatalyst, VOC",

author = "Esra Buyukada-Kesici and Memnune Karde{\c s} and {Ertura{\c c} Karag{\"o}z}, K{\"u}bra and Gizem Ba{\c s}aran-Dinda{\c s} and Koray {\"O}zt{\"u}rk and {Cengiz Yatmaz}, H. and Koseoglu-Imer, {Derya Y.}",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier B.V.",

year = "2023",

month = jan,

day = "1",

doi = "10.1016/j.cej.2022.140672",

language = "English",

volume = "455",

journal = "Chemical Engineering Journal",

issn = "1385-8947",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Developing of reticulated ceramic photocatalyst for efficient photocatalytic oxidation of gaseous toluene

AU - Buyukada-Kesici, Esra

AU - Kardeş, Memnune

AU - Erturaç Karagöz, Kübra

AU - Başaran-Dindaş, Gizem

AU - Öztürk, Koray

AU - Cengiz Yatmaz, H.

AU - Koseoglu-Imer, Derya Y.

PY - 2023/1/1

Y1 - 2023/1/1

N2 - In this study, a reticulated ceramic photocatalyst was developed to conduct the photocatalytic oxidation of gaseous toluene at high concentration. Toluene was used as a target pollutant to be degraded mainly due to its high toxicity and health effect. It was aimed to prove the potential of reticulated ceramic material with open and interconnected porous structure, high mechanical property, high surface area and low cost for toxic gaseous removal. As a result of immobilizing the TiO2 catalyst on the reticulated ceramic material with three different sintering temperatures, the best photocatalytic performance was observed at 800 °C of sintering temperature due to the anatase to rutile ratio of TiO2 catalyst. Photocatalytic oxidation of toluene was conducted at continuous and periodic illumination and resulted in similar removal efficiency of toluene under both conditions. However, the removal efficiency of toluene was found as 71.21 % under continuous illumination, whereas it was 60.55 % under periodic illumination. The ceramic photocatalysts showed excellent stability in the photocatalytic oxidation of toluene for six cycles totally 9120 min.

AB - In this study, a reticulated ceramic photocatalyst was developed to conduct the photocatalytic oxidation of gaseous toluene at high concentration. Toluene was used as a target pollutant to be degraded mainly due to its high toxicity and health effect. It was aimed to prove the potential of reticulated ceramic material with open and interconnected porous structure, high mechanical property, high surface area and low cost for toxic gaseous removal. As a result of immobilizing the TiO2 catalyst on the reticulated ceramic material with three different sintering temperatures, the best photocatalytic performance was observed at 800 °C of sintering temperature due to the anatase to rutile ratio of TiO2 catalyst. Photocatalytic oxidation of toluene was conducted at continuous and periodic illumination and resulted in similar removal efficiency of toluene under both conditions. However, the removal efficiency of toluene was found as 71.21 % under continuous illumination, whereas it was 60.55 % under periodic illumination. The ceramic photocatalysts showed excellent stability in the photocatalytic oxidation of toluene for six cycles totally 9120 min.

KW - Gaseous toluene

KW - Photocatalytic oxidation

KW - Reticulated ceramic photocatalyst

KW - VOC

UR - http://www.scopus.com/inward/record.url?scp=85145316134&partnerID=8YFLogxK

U2 - 10.1016/j.cej.2022.140672

DO - 10.1016/j.cej.2022.140672

M3 - Article

AN - SCOPUS:85145316134

SN - 1385-8947

VL - 455

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

M1 - 140672

ER -

Developing of reticulated ceramic photocatalyst for efficient photocatalytic oxidation of gaseous toluene

Özet

Bibliyografik not

Finansman

BM SKH

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap