Desulfurization performance of iron supported on activated carbon

Xiao Li Liu; Jia Xiu Guo; Ying Hao Chu; De Ming Luo; Hua Qiang Yin; Ming Chao Sun; Reha Yavuz

doi:10.1016/j.fuel.2014.01.068

Desulfurization performance of iron supported on activated carbon

Xiao Li Liu, Jia Xiu Guo^*, Ying Hao Chu, De Ming Luo, Hua Qiang Yin, Ming Chao Sun, Reha Yavuz

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Mühendisliği Bölümü

Sichuan University

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

66 Atıf (Scopus)

Özet

Fe catalysts supported on activated carbon untreated and treated by HNO₃ were prepared by an ultrasound-assisted incipient wetness method and characterized using N₂ adsorption/desorption, scanning electron microscopic (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Desulfurization activity was evaluated at a fixed bed reactor under a simulated flue gas. The results showed that the SO₂ adsorption capacity of AC is 74 mg/g; when Fe is loaded on activated carbon untreated by HNO₃, SO₂ adsorption capacity increases to 244 mg/g; and when Fe is loaded on activated carbon treated by HNO₃, SO₂ adsorption capacity increases to 322 mg/g. Fe₃O₄ species exists on the surface of fresh catalysts, but after desulfurization, Fe ₂(SO₄)₃ is detected, indicating that Fe species could react with generated H₂SO₄ in the desulfurization process and may be the main reason of the deactivation of Fe catalysts supported on activated carbon.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	93-100
Sayfa sayısı	8
Dergi	Fuel
Hacim	123
DOI'lar	https://doi.org/10.1016/j.fuel.2014.01.068
Yayın durumu	Yayınlandı - 1 May 2014

Finansman

This work is financially supported by the National Nature Science Youth Fund of China (No. 5110828 ), the National Natural Science Foundation of China (Project No. 51078245 ) and the Sichuan Provincial Science and Technology Agency Public Research Projects (No. 2012GZX0028 ). We would like to thank the Analytical & Testing Center of Sichuan University for the SEM characterization of the catalysts.

Finansörler	Finansör numarası
National Nature Science Youth Fund of China	5110828
Sichuan Provincial Science and Technology Agency	2012GZX0028
National Natural Science Foundation of China	51078245

Belgeye Erişim

10.1016/j.fuel.2014.01.068

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{b1b2f032d7b24156b497e7a4e77c77cd,

title = "Desulfurization performance of iron supported on activated carbon",

abstract = "Fe catalysts supported on activated carbon untreated and treated by HNO3 were prepared by an ultrasound-assisted incipient wetness method and characterized using N2 adsorption/desorption, scanning electron microscopic (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Desulfurization activity was evaluated at a fixed bed reactor under a simulated flue gas. The results showed that the SO2 adsorption capacity of AC is 74 mg/g; when Fe is loaded on activated carbon untreated by HNO3, SO2 adsorption capacity increases to 244 mg/g; and when Fe is loaded on activated carbon treated by HNO3, SO2 adsorption capacity increases to 322 mg/g. Fe3O4 species exists on the surface of fresh catalysts, but after desulfurization, Fe 2(SO4)3 is detected, indicating that Fe species could react with generated H2SO4 in the desulfurization process and may be the main reason of the deactivation of Fe catalysts supported on activated carbon.",

keywords = "Acidic treatment, Activated carbon, Desulfurization, FeO, Surface oxygen groups",

author = "Liu, {Xiao Li} and Guo, {Jia Xiu} and Chu, {Ying Hao} and Luo, {De Ming} and Yin, {Hua Qiang} and Sun, {Ming Chao} and Reha Yavuz",

year = "2014",

month = may,

day = "1",

doi = "10.1016/j.fuel.2014.01.068",

language = "English",

volume = "123",

pages = "93--100",

journal = "Fuel",

issn = "0016-2361",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Desulfurization performance of iron supported on activated carbon

AU - Liu, Xiao Li

AU - Guo, Jia Xiu

AU - Chu, Ying Hao

AU - Luo, De Ming

AU - Yin, Hua Qiang

AU - Sun, Ming Chao

AU - Yavuz, Reha

PY - 2014/5/1

Y1 - 2014/5/1

N2 - Fe catalysts supported on activated carbon untreated and treated by HNO3 were prepared by an ultrasound-assisted incipient wetness method and characterized using N2 adsorption/desorption, scanning electron microscopic (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Desulfurization activity was evaluated at a fixed bed reactor under a simulated flue gas. The results showed that the SO2 adsorption capacity of AC is 74 mg/g; when Fe is loaded on activated carbon untreated by HNO3, SO2 adsorption capacity increases to 244 mg/g; and when Fe is loaded on activated carbon treated by HNO3, SO2 adsorption capacity increases to 322 mg/g. Fe3O4 species exists on the surface of fresh catalysts, but after desulfurization, Fe 2(SO4)3 is detected, indicating that Fe species could react with generated H2SO4 in the desulfurization process and may be the main reason of the deactivation of Fe catalysts supported on activated carbon.

AB - Fe catalysts supported on activated carbon untreated and treated by HNO3 were prepared by an ultrasound-assisted incipient wetness method and characterized using N2 adsorption/desorption, scanning electron microscopic (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Desulfurization activity was evaluated at a fixed bed reactor under a simulated flue gas. The results showed that the SO2 adsorption capacity of AC is 74 mg/g; when Fe is loaded on activated carbon untreated by HNO3, SO2 adsorption capacity increases to 244 mg/g; and when Fe is loaded on activated carbon treated by HNO3, SO2 adsorption capacity increases to 322 mg/g. Fe3O4 species exists on the surface of fresh catalysts, but after desulfurization, Fe 2(SO4)3 is detected, indicating that Fe species could react with generated H2SO4 in the desulfurization process and may be the main reason of the deactivation of Fe catalysts supported on activated carbon.

KW - Acidic treatment

KW - Activated carbon

KW - Desulfurization

KW - FeO

KW - Surface oxygen groups

UR - http://www.scopus.com/inward/record.url?scp=84893913676&partnerID=8YFLogxK

U2 - 10.1016/j.fuel.2014.01.068

DO - 10.1016/j.fuel.2014.01.068

M3 - Article

AN - SCOPUS:84893913676

SN - 0016-2361

VL - 123

SP - 93

EP - 100

JO - Fuel

JF - Fuel

ER -

Desulfurization performance of iron supported on activated carbon

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap