Coupling of ferrocenyl chromium carbene complex with cyclobutenediones

Metin Zora; Baris Yucel; N. Bekir Peynircioglu

doi:10.1016/S0022-328X(02)01403-1

Coupling of ferrocenyl chromium carbene complex with cyclobutenediones

Metin Zora, Baris Yucel, N. Bekir Peynircioglu

Middle East Technical University

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

32 Atıf (Scopus)

Özet

The coupling of ferrocenyl chromium carbene complex with cyclobutenediones leads to ferrocenyl-substituted 5-alkylidenefuranones and 4-cyclopentene- 1,3-diones, methyl ferrocenoate and acetylferrocene in varying amounts. The scope and limitations of these processes are investigated. In comparison with the phenyl analog, ferrocenyl chromium carbene complex has been found to be less reactive. This is also supported by PM3 calculations.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	11-17
Sayfa sayısı	7
Dergi	Journal of Organometallic Chemistry
Hacim	656
Basın numarası	1-2
DOI'lar	https://doi.org/10.1016/S0022-328X(02)01403-1
Yayın durumu	Yayınlandı - 15 Ağu 2002
Harici olarak yayınlandı	Evet

Finansman

We thank the Scientific and Technical Research Council of Turkey (TBAG-1892), the State Planning Organization of Turkey (DPT-2000K120390), and the Research Board of Middle East Technical University (AFP-98-01-03-06) for support of this research.

Finansörler	Finansör numarası
Research Board of Middle East Technical University	AFP-98-01-03-06
State Planning Organization of Turkey	DPT-2000K120390
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu	TBAG-1892

Belgeye Erişim

10.1016/S0022-328X(02)01403-1

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Coupling of ferrocenyl chromium carbene complex with cyclobutenediones",

abstract = "The coupling of ferrocenyl chromium carbene complex with cyclobutenediones leads to ferrocenyl-substituted 5-alkylidenefuranones and 4-cyclopentene- 1,3-diones, methyl ferrocenoate and acetylferrocene in varying amounts. The scope and limitations of these processes are investigated. In comparison with the phenyl analog, ferrocenyl chromium carbene complex has been found to be less reactive. This is also supported by PM3 calculations.",

keywords = "Alkylidenefuranone, Coupling, Cyclobutenedione, Cyclopentenedione, Ferrocene, Ferrocenyl carbene, Fischer carbene",

author = "Metin Zora and Baris Yucel and {Bekir Peynircioglu}, N.",

year = "2002",

month = aug,

day = "15",

doi = "10.1016/S0022-328X(02)01403-1",

language = "English",

volume = "656",

pages = "11--17",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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TY - JOUR

T1 - Coupling of ferrocenyl chromium carbene complex with cyclobutenediones

AU - Zora, Metin

AU - Yucel, Baris

AU - Bekir Peynircioglu, N.

PY - 2002/8/15

Y1 - 2002/8/15

N2 - The coupling of ferrocenyl chromium carbene complex with cyclobutenediones leads to ferrocenyl-substituted 5-alkylidenefuranones and 4-cyclopentene- 1,3-diones, methyl ferrocenoate and acetylferrocene in varying amounts. The scope and limitations of these processes are investigated. In comparison with the phenyl analog, ferrocenyl chromium carbene complex has been found to be less reactive. This is also supported by PM3 calculations.

AB - The coupling of ferrocenyl chromium carbene complex with cyclobutenediones leads to ferrocenyl-substituted 5-alkylidenefuranones and 4-cyclopentene- 1,3-diones, methyl ferrocenoate and acetylferrocene in varying amounts. The scope and limitations of these processes are investigated. In comparison with the phenyl analog, ferrocenyl chromium carbene complex has been found to be less reactive. This is also supported by PM3 calculations.

KW - Alkylidenefuranone

KW - Coupling

KW - Cyclobutenedione

KW - Cyclopentenedione

KW - Ferrocene

KW - Ferrocenyl carbene

KW - Fischer carbene

UR - http://www.scopus.com/inward/record.url?scp=0037103008&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(02)01403-1

DO - 10.1016/S0022-328X(02)01403-1

M3 - Article

AN - SCOPUS:0037103008

SN - 0022-328X

VL - 656

SP - 11

EP - 17

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Coupling of ferrocenyl chromium carbene complex with cyclobutenediones

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap