Counteranion sensitization approach to photoinitiated free radical polymerization

Gorkem Yilmaz; Gokhan Acik; Yusuf Yagci

doi:10.1021/ma3000169

Counteranion sensitization approach to photoinitiated free radical polymerization

Gorkem Yilmaz
, Gokhan Acik
, Yusuf Yagci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

78 Atıf (Scopus)

Özet

A novel polymeric type II photoinitiator, namely poly(ethylene oxide) dimethylammonium thioxanthonemethyl-carboxylate (PEO-NH ⁺(Me) ₂ TX-CH ₂COO ^-), possessing both photochromophoric and hydrogen donating groups in the structure was synthesized and characterized. In contrast to existing type II photoinitiators, the present photoinitiator initiates free radical polymerization by counteranion excitation even in the absence of added hydrogen donors. The photoinitiator can be applied to the polymerization of monomers soluble in organic solvents or water.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	2219-2224
Sayfa sayısı	6
Dergi	Macromolecules
Hacim	45
Basın numarası	5
DOI'lar	https://doi.org/10.1021/ma3000169
Yayın durumu	Yayınlandı - 13 Mar 2012

Belgeye Erişim

10.1021/ma3000169

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Link to publication in Scopus

Alıntı Yap

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title = "Counteranion sensitization approach to photoinitiated free radical polymerization",

abstract = "A novel polymeric type II photoinitiator, namely poly(ethylene oxide) dimethylammonium thioxanthonemethyl-carboxylate (PEO-NH +(Me) 2 TX-CH 2COO -), possessing both photochromophoric and hydrogen donating groups in the structure was synthesized and characterized. In contrast to existing type II photoinitiators, the present photoinitiator initiates free radical polymerization by counteranion excitation even in the absence of added hydrogen donors. The photoinitiator can be applied to the polymerization of monomers soluble in organic solvents or water.",

author = "Gorkem Yilmaz and Gokhan Acik and Yusuf Yagci",

year = "2012",

month = mar,

day = "13",

doi = "10.1021/ma3000169",

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volume = "45",

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journal = "Macromolecules",

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T1 - Counteranion sensitization approach to photoinitiated free radical polymerization

AU - Yilmaz, Gorkem

AU - Acik, Gokhan

AU - Yagci, Yusuf

PY - 2012/3/13

Y1 - 2012/3/13

N2 - A novel polymeric type II photoinitiator, namely poly(ethylene oxide) dimethylammonium thioxanthonemethyl-carboxylate (PEO-NH +(Me) 2 TX-CH 2COO -), possessing both photochromophoric and hydrogen donating groups in the structure was synthesized and characterized. In contrast to existing type II photoinitiators, the present photoinitiator initiates free radical polymerization by counteranion excitation even in the absence of added hydrogen donors. The photoinitiator can be applied to the polymerization of monomers soluble in organic solvents or water.

AB - A novel polymeric type II photoinitiator, namely poly(ethylene oxide) dimethylammonium thioxanthonemethyl-carboxylate (PEO-NH +(Me) 2 TX-CH 2COO -), possessing both photochromophoric and hydrogen donating groups in the structure was synthesized and characterized. In contrast to existing type II photoinitiators, the present photoinitiator initiates free radical polymerization by counteranion excitation even in the absence of added hydrogen donors. The photoinitiator can be applied to the polymerization of monomers soluble in organic solvents or water.

UR - https://www.scopus.com/pages/publications/84858213544

U2 - 10.1021/ma3000169

DO - 10.1021/ma3000169

M3 - Article

AN - SCOPUS:84858213544

SN - 0024-9297

VL - 45

SP - 2219

EP - 2224

JO - Macromolecules

JF - Macromolecules

IS - 5

ER -

Counteranion sensitization approach to photoinitiated free radical polymerization

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