Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Elif Keskin; Nesrin Köken; Nilgün Kızılcan; Ahmet Akar

doi:10.1080/25740881.2023.2250863

Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Elif Keskin
, Nesrin Köken^*
, Nilgün Kızılcan
, Ahmet Akar

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

2 Atıf (Scopus)

Özet

Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	2030-2042
Sayfa sayısı	13
Dergi	Polymer-Plastics Technology and Materials
Hacim	62
Basın numarası	15
DOI'lar	https://doi.org/10.1080/25740881.2023.2250863
Yayın durumu	Yayınlandı - 2023

Bibliyografik not

Publisher Copyright:
© 2023 Taylor & Francis.

Finansman

The work was supported by the the Scientific and Technical Research Council of Turkey (TUBITAK) 2244 Industrial Ph.D. Program -Istanbul Technical University-Arcelik Project No: 118C104. [ITU BAP; Project No.: TDK-2021-43296]. The authors would like to thank the Scientific and Technical Research Council of Turkey (TUBITAK) 2244 Industrial Ph.D. Program -Istanbul Technical University-Arçelik Project No: 118C104. The authors acknowledge funding from the Research Fund of the Istanbul Technical University, Turkey (ITU BAP; Project No.: TDK-2021-43296). The authors would like to thank the Scientific and Technical Research Council of Turkey (TUBITAK) 2244 Industrial Ph.D. Program -Istanbul Technical University-Arçelik Project No: 118C104. The authors acknowledge funding from the Research Fund of the Istanbul Technical University, Turkey (ITU BAP; Project No.: TDK-2021-43296).

Finansörler	Finansör numarası
Istanbul Technical University, Turkey
Istanbul Technical University-Arcelik
Istanbul Technical University-Arçelik	118C104
Türkiye Bilimsel ve Teknolojik Araştırma Kurumu
Bilimsel Araştırma Projeleri Birimi, İstanbul Teknik Üniversitesi	TDK-2021-43296

Belgeye Erişim

10.1080/25740881.2023.2250863

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber",

abstract = "Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.",

keywords = "Flame-retardant, nanofiber, phosphorous, polyacrylonitrile, vinyl phosphonic acid",

author = "Elif Keskin and Nesrin K{\"o}ken and Nilg{\"u}n Kızılcan and Ahmet Akar",

note = "Publisher Copyright: {\textcopyright} 2023 Taylor \& Francis.",

year = "2023",

doi = "10.1080/25740881.2023.2250863",

language = "English",

volume = "62",

pages = "2030--2042",

journal = "Polymer-Plastics Technology and Materials",

issn = "2574-0881",

publisher = "Taylor and Francis Ltd.",

number = "15",

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TY - JOUR

T1 - Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

AU - Keskin, Elif

AU - Köken, Nesrin

AU - Kızılcan, Nilgün

AU - Akar, Ahmet

PY - 2023

Y1 - 2023

N2 - Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

AB - Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

KW - Flame-retardant

KW - nanofiber

KW - phosphorous

KW - polyacrylonitrile

KW - vinyl phosphonic acid

UR - https://www.scopus.com/pages/publications/85168885488

U2 - 10.1080/25740881.2023.2250863

DO - 10.1080/25740881.2023.2250863

M3 - Article

AN - SCOPUS:85168885488

SN - 2574-0881

VL - 62

SP - 2030

EP - 2042

JO - Polymer-Plastics Technology and Materials

JF - Polymer-Plastics Technology and Materials

IS - 15

ER -

Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

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