Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Elif Keskin; Nesrin Köken; Nilgün Kızılcan; Ahmet Akar

doi:10.1080/25740881.2023.2250863

Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Elif Keskin, Nesrin Köken^*, Nilgün Kızılcan, Ahmet Akar

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

2 Atıf (Scopus)

Özet

Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	2030-2042
Sayfa sayısı	13
Dergi	Polymer-Plastics Technology and Materials
Hacim	62
Basın numarası	15
DOI'lar	https://doi.org/10.1080/25740881.2023.2250863
Yayın durumu	Yayınlandı - 2023

Bibliyografik not

Publisher Copyright:
© 2023 Taylor & Francis.

Belgeye Erişim

10.1080/25740881.2023.2250863

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber",

abstract = "Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.",

keywords = "Flame-retardant, nanofiber, phosphorous, polyacrylonitrile, vinyl phosphonic acid",

author = "Elif Keskin and Nesrin K{\"o}ken and Nilg{\"u}n Kızılcan and Ahmet Akar",

note = "Publisher Copyright: {\textcopyright} 2023 Taylor & Francis.",

year = "2023",

doi = "10.1080/25740881.2023.2250863",

language = "English",

volume = "62",

pages = "2030--2042",

journal = "Polymer-Plastics Technology and Materials",

issn = "2574-0881",

publisher = "Taylor and Francis Ltd.",

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TY - JOUR

T1 - Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

AU - Keskin, Elif

AU - Köken, Nesrin

AU - Kızılcan, Nilgün

AU - Akar, Ahmet

PY - 2023

Y1 - 2023

N2 - Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

AB - Copolymers and terpolymers of acrylonitrile (AN), methyl acrylate (MA), vinyl acetate (VA), and vinyl phosphonic acid (VPA) were synthesized. Thermal gravimetric analysis studies showed that the decomposition of PANMAVPA and PANVAVPA terpolymers started at lower temperatures than PANMA and PANVA copolymers. VPA and MA caused an increase in the ring formation of pendant nitrile groups and the total ash content of PANMAVPA terpolymer. During the thermal oxidative treatment (TOS) of PANVAVPA, the phosphonic acid moiety accelerated double bond formation via acetic acid elimination. 151–340 nm nanofibers were successfully produced from copolymers and terpolymers.

KW - Flame-retardant

KW - nanofiber

KW - phosphorous

KW - polyacrylonitrile

KW - vinyl phosphonic acid

UR - http://www.scopus.com/inward/record.url?scp=85168885488&partnerID=8YFLogxK

U2 - 10.1080/25740881.2023.2250863

DO - 10.1080/25740881.2023.2250863

M3 - Article

AN - SCOPUS:85168885488

SN - 2574-0881

VL - 62

SP - 2030

EP - 2042

JO - Polymer-Plastics Technology and Materials

JF - Polymer-Plastics Technology and Materials

IS - 15

ER -

Copolymers and terpolymers of vinyl phosphonic acid, acrylonitrile, methyl acrylate, and vinyl acetate. Thermal oxidative stabilization and their nanofiber

Özet

Bibliyografik not

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap