Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate

Yusuf Guner; Levent Toppare; Yesim Hepuzer; Yusuf Yagci

doi:10.1016/j.eurpolymj.2004.03.029

Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate

Yusuf Guner
, Levent Toppare^*
, Yesim Hepuzer
, Yusuf Yagci

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Middle East Technical University
Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

18 Atıf (Scopus)

Özet

Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	1799-1806
Sayfa sayısı	8
Dergi	European Polymer Journal
Hacim	40
Basın numarası	8
DOI'lar	https://doi.org/10.1016/j.eurpolymj.2004.03.029
Yayın durumu	Yayınlandı - Ağu 2004

Finansman

This work was supported by DPT2003K120920-02, METU BAP-2003-01-03-02, Istanbul Technical University Research Fund and Turkish Academy of Sciences (TUBA).

Finansörler	Finansör numarası
METU	BAP-2003-01-03-02
TUBA
Türkiye Bilimler Akademisi
Istanbul Teknik Üniversitesi

Belgeye Erişim

10.1016/j.eurpolymj.2004.03.029

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate",

abstract = "Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).",

keywords = "Conducting copolymers, Electrochemical polymerization, Graft copolymers",

author = "Yusuf Guner and Levent Toppare and Yesim Hepuzer and Yusuf Yagci",

year = "2004",

month = aug,

doi = "10.1016/j.eurpolymj.2004.03.029",

language = "English",

volume = "40",

pages = "1799--1806",

journal = "European Polymer Journal",

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TY - JOUR

T1 - Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate

AU - Guner, Yusuf

AU - Toppare, Levent

AU - Hepuzer, Yesim

AU - Yagci, Yusuf

PY - 2004/8

Y1 - 2004/8

N2 - Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).

AB - Random copolymers of 3-methyl thienylmethacrylate and methyl methacrylate were synthesized via free radical polymerization. Electro-copolymerizations of random copolymers with thiophene and/or pyrrole were carried out in acetonitrile-tetrabutylammonium tetrafluoroborate (TBAFB), water-p-toluene sulfonic acid (PTSA) solvent-electrolyte couples. Oxidative polymerization of thiophene functionalized random copolymer was also achieved by constant current electrolysis and chemical polymerization. The characterizations were done by conductivity measurements, cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), thermal gravimetry analysis (TGA), scanning electron microscopy (SEM).

KW - Conducting copolymers

KW - Electrochemical polymerization

KW - Graft copolymers

UR - https://www.scopus.com/pages/publications/3042734663

U2 - 10.1016/j.eurpolymj.2004.03.029

DO - 10.1016/j.eurpolymj.2004.03.029

M3 - Article

AN - SCOPUS:3042734663

SN - 0014-3057

VL - 40

SP - 1799

EP - 1806

JO - European Polymer Journal

JF - European Polymer Journal

IS - 8

ER -

Conducting graft copolymers of pyrrole and thiophene with random copolymers of methyl methacrylate and 3-methylthienyl methacrylate

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap