Coil-globule transition studies of sodium poly(styrene sulfonate) by dynamic light scattering

Ersin Serhatli; Müge Serhatli; Bahattin M. Baysal; Frank E. Karasz

doi:10.1016/S0032-3861(02)00431-7

Coil-globule transition studies of sodium poly(styrene sulfonate) by dynamic light scattering

Ersin Serhatli
, Müge Serhatli
, Bahattin M. Baysal^*
, Frank E. Karasz

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Scientific and Technological Research Council of Turkey
Bogazici University
University of Massachusetts

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

11 Atıf (Scopus)

Özet

The coil-globule transition behavior of sodium poly(styrene sulfonate) (NaPSS) (M_W = 1.2 × 10⁶ g/mol) in 4.17 M aqueous NaCl solution has been studied by dynamic light scattering. The polymer dimensions show a smooth and continuous contraction below the reference temperature (18°C). The hydrodynamic radius (Rh) of NaPSS in this system was reduced from 13.1 nm (18°C) to 9.1 nm at 10°C. At the latter temperature the polymer segment volume fraction was calculated to be 0.58. The contraction for this and other NaPSS samples investigated in this study is somewhat limited because under these high ionic strength conditions the polymer chains already contracted as a result of the screening effect of the ions.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	5439-5445
Sayfa sayısı	7
Dergi	Polymer
Hacim	43
Basın numarası	20
DOI'lar	https://doi.org/10.1016/S0032-3861(02)00431-7
Yayın durumu	Yayınlandı - 12 Ağu 2002

Finansman

This work was supported by TUBITAK Marmara Research Center and the National Science Foundation (NSF Grant INT-9507751). F.E.K. and B.M.B. acknowledge support from AFOSR Grant 99-001, and TUBA-Turkish Academy of Sciences, respectively.

Finansörler	Finansör numarası
TUBA-Turkish Academy of Sciences
TUBITAK Marmara Research Center
National Science Foundation	INT-9507751
Air Force Office of Scientific Research

Belgeye Erişim

10.1016/S0032-3861(02)00431-7

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Coil-globule transition studies of sodium poly(styrene sulfonate) by dynamic light scattering",

abstract = "The coil-globule transition behavior of sodium poly(styrene sulfonate) (NaPSS) (MW = 1.2 × 106 g/mol) in 4.17 M aqueous NaCl solution has been studied by dynamic light scattering. The polymer dimensions show a smooth and continuous contraction below the reference temperature (18°C). The hydrodynamic radius (Rh) of NaPSS in this system was reduced from 13.1 nm (18°C) to 9.1 nm at 10°C. At the latter temperature the polymer segment volume fraction was calculated to be 0.58. The contraction for this and other NaPSS samples investigated in this study is somewhat limited because under these high ionic strength conditions the polymer chains already contracted as a result of the screening effect of the ions.",

keywords = "Coil-globule transition, Dynamic light scattering, Sodium poly(styrene sulfonate)",

author = "Ersin Serhatli and M{\"u}ge Serhatli and Baysal, \{Bahattin M.\} and Karasz, \{Frank E.\}",

year = "2002",

month = aug,

day = "12",

doi = "10.1016/S0032-3861(02)00431-7",

language = "English",

volume = "43",

pages = "5439--5445",

journal = "Polymer",

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number = "20",

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TY - JOUR

T1 - Coil-globule transition studies of sodium poly(styrene sulfonate) by dynamic light scattering

AU - Serhatli, Ersin

AU - Serhatli, Müge

AU - Baysal, Bahattin M.

AU - Karasz, Frank E.

PY - 2002/8/12

Y1 - 2002/8/12

N2 - The coil-globule transition behavior of sodium poly(styrene sulfonate) (NaPSS) (MW = 1.2 × 106 g/mol) in 4.17 M aqueous NaCl solution has been studied by dynamic light scattering. The polymer dimensions show a smooth and continuous contraction below the reference temperature (18°C). The hydrodynamic radius (Rh) of NaPSS in this system was reduced from 13.1 nm (18°C) to 9.1 nm at 10°C. At the latter temperature the polymer segment volume fraction was calculated to be 0.58. The contraction for this and other NaPSS samples investigated in this study is somewhat limited because under these high ionic strength conditions the polymer chains already contracted as a result of the screening effect of the ions.

AB - The coil-globule transition behavior of sodium poly(styrene sulfonate) (NaPSS) (MW = 1.2 × 106 g/mol) in 4.17 M aqueous NaCl solution has been studied by dynamic light scattering. The polymer dimensions show a smooth and continuous contraction below the reference temperature (18°C). The hydrodynamic radius (Rh) of NaPSS in this system was reduced from 13.1 nm (18°C) to 9.1 nm at 10°C. At the latter temperature the polymer segment volume fraction was calculated to be 0.58. The contraction for this and other NaPSS samples investigated in this study is somewhat limited because under these high ionic strength conditions the polymer chains already contracted as a result of the screening effect of the ions.

KW - Coil-globule transition

KW - Dynamic light scattering

KW - Sodium poly(styrene sulfonate)

UR - https://www.scopus.com/pages/publications/0037068181

U2 - 10.1016/S0032-3861(02)00431-7

DO - 10.1016/S0032-3861(02)00431-7

M3 - Article

AN - SCOPUS:0037068181

SN - 0032-3861

VL - 43

SP - 5439

EP - 5445

JO - Polymer

JF - Polymer

IS - 20

ER -

Coil-globule transition studies of sodium poly(styrene sulfonate) by dynamic light scattering

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

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