Chemoselective Synthesis of Uniform Sequence-Coded Polyurethanes and Their Use as Molecular Tags

Ufuk Saim Gunay; Benoît Eric Petit; Denise Karamessini; Abdelaziz Al Ouahabi; Jean Arthur Amalian; Christophe Chendo; Michel Bouquey; Didier Gigmes; Laurence Charles; Jean François Lutz

doi:10.1016/j.chempr.2016.06.006

Chemoselective Synthesis of Uniform Sequence-Coded Polyurethanes and Their Use as Molecular Tags

Ufuk Saim Gunay
, Benoît Eric Petit
, Denise Karamessini
, Abdelaziz Al Ouahabi
, Jean Arthur Amalian
, Christophe Chendo
, Michel Bouquey
, Didier Gigmes
, Laurence Charles^*
, Jean François Lutz

^*Bu çalışma için yazışmadan sorumlu yazar

Institut Charles Sadron
Aix-Marseille Université

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

121 Atıf (Scopus)

Özet

Polyurethanes (PUs) constitute a popular class of plastic materials with a wide range of applications in construction, coatings, and the automotive industry. PUs are usually synthesized by step-growth polymerization and, therefore, exhibit non-uniform molecular structures. Here, we show that uniform PUs can be prepared by a facile chemoselective multistep-growth approach. This strategy permits precise control of the chain lengths of the PUs formed and their primary structure, thus making the preparation of coded monomer sequences possible. Furthermore, it was found that these polymers are remarkably easy to analyze by tandem mass spectrometry sequencing. Thus, these precision polymers can potentially be used as molecular barcodes in various applications. As a proof of concept, their use as anti-counterfeiting tags for identification of materials is reported here.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	114-126
Sayfa sayısı	13
Dergi	Chem
Hacim	1
Basın numarası	1
DOI'lar	https://doi.org/10.1016/j.chempr.2016.06.006
Yayın durumu	Yayınlandı - 1 Ara 2016
Harici olarak yayınlandı	Evet

Bibliyografik not

Publisher Copyright:
© 2016 Elsevier Inc.

Finansman

J.F.L. thanks the H2020 program of the European Union (project Euro-Sequences, H2020-MSCA-ITN-2014, grant agreement no. 642083), the Cluster of Excellence Chemistry of Complex Systems (LabEx CSC), and the CNRS for financial support. The PhD positions of D.K. and B.E.P. are supported by the ITN Euro-Sequences and LabEX CSC, respectively. The doctoral visit in Strasbourg of U.S.G. was supported by the Scientific and Technological Research Council of Turkey (TUBITAK 2214-A Program). L.C. acknowledges support from Spectropole, the Analytical Facility of Aix-Marseille University, for allowing special access to instruments purchased with European funding (FEDER OBJ2142-3341). The experimental results of this publication were also obtained with the help of the Polymer Characterization Platform of the Institut Charles Sadron. The authors also thank Mélanie Legros, Huseyin Dogan, and Catherine Foussat for the SEC and TGA measurements and Thomas Hermans (Université de Strasbourg) for providing access to the 3D printer.

Finansörler	Finansör numarası
Cluster of Excellence Chemistry of Complex Systems
ITN Euro-Sequences
Institut Charles Sadron
Horizon 2020 Framework Programme	642083
European Commission	H2020-MSCA-ITN-2014
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu
Centre National de la Recherche Scientifique
European Regional Development Fund	OBJ2142-3341
LabEx Chimie des Systèmes Complexes

BM SKH

Bu sonuç, aşağıdaki Sürdürülebilir Kalkınma Hedefine/Hedeflerine katkıda bulunur

SKH 9 Sanayi, Yenilikçilik ve Altyapı

Belgeye Erişim

10.1016/j.chempr.2016.06.006

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Chemoselective Synthesis of Uniform Sequence-Coded Polyurethanes and Their Use as Molecular Tags",

abstract = "Polyurethanes (PUs) constitute a popular class of plastic materials with a wide range of applications in construction, coatings, and the automotive industry. PUs are usually synthesized by step-growth polymerization and, therefore, exhibit non-uniform molecular structures. Here, we show that uniform PUs can be prepared by a facile chemoselective multistep-growth approach. This strategy permits precise control of the chain lengths of the PUs formed and their primary structure, thus making the preparation of coded monomer sequences possible. Furthermore, it was found that these polymers are remarkably easy to analyze by tandem mass spectrometry sequencing. Thus, these precision polymers can potentially be used as molecular barcodes in various applications. As a proof of concept, their use as anti-counterfeiting tags for identification of materials is reported here.",

keywords = "SDG12: Responsible consumption and production, SDG9: Industry, innovation, and infrastructure",

author = "Gunay, \{Ufuk Saim\} and Petit, \{Beno{\^i}t Eric\} and Denise Karamessini and \{Al Ouahabi\}, Abdelaziz and Amalian, \{Jean Arthur\} and Christophe Chendo and Michel Bouquey and Didier Gigmes and Laurence Charles and Lutz, \{Jean Fran{\c c}ois\}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier Inc.",

year = "2016",

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day = "1",

doi = "10.1016/j.chempr.2016.06.006",

language = "English",

volume = "1",

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T1 - Chemoselective Synthesis of Uniform Sequence-Coded Polyurethanes and Their Use as Molecular Tags

AU - Gunay, Ufuk Saim

AU - Petit, Benoît Eric

AU - Karamessini, Denise

AU - Al Ouahabi, Abdelaziz

AU - Amalian, Jean Arthur

AU - Chendo, Christophe

AU - Bouquey, Michel

AU - Gigmes, Didier

AU - Charles, Laurence

AU - Lutz, Jean François

PY - 2016/12/1

Y1 - 2016/12/1

N2 - Polyurethanes (PUs) constitute a popular class of plastic materials with a wide range of applications in construction, coatings, and the automotive industry. PUs are usually synthesized by step-growth polymerization and, therefore, exhibit non-uniform molecular structures. Here, we show that uniform PUs can be prepared by a facile chemoselective multistep-growth approach. This strategy permits precise control of the chain lengths of the PUs formed and their primary structure, thus making the preparation of coded monomer sequences possible. Furthermore, it was found that these polymers are remarkably easy to analyze by tandem mass spectrometry sequencing. Thus, these precision polymers can potentially be used as molecular barcodes in various applications. As a proof of concept, their use as anti-counterfeiting tags for identification of materials is reported here.

AB - Polyurethanes (PUs) constitute a popular class of plastic materials with a wide range of applications in construction, coatings, and the automotive industry. PUs are usually synthesized by step-growth polymerization and, therefore, exhibit non-uniform molecular structures. Here, we show that uniform PUs can be prepared by a facile chemoselective multistep-growth approach. This strategy permits precise control of the chain lengths of the PUs formed and their primary structure, thus making the preparation of coded monomer sequences possible. Furthermore, it was found that these polymers are remarkably easy to analyze by tandem mass spectrometry sequencing. Thus, these precision polymers can potentially be used as molecular barcodes in various applications. As a proof of concept, their use as anti-counterfeiting tags for identification of materials is reported here.

KW - SDG12: Responsible consumption and production

KW - SDG9: Industry, innovation, and infrastructure

UR - https://www.scopus.com/pages/publications/85006835132

U2 - 10.1016/j.chempr.2016.06.006

DO - 10.1016/j.chempr.2016.06.006

M3 - Article

AN - SCOPUS:85006835132

SN - 2451-9294

VL - 1

SP - 114

EP - 126

JO - Chem

JF - Chem

IS - 1

ER -

Chemoselective Synthesis of Uniform Sequence-Coded Polyurethanes and Their Use as Molecular Tags

Özet

Bibliyografik not

Finansman

BM SKH

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap