Chemical RedOx Properties of a Donor-Acceptor Conjugated Microporous Dithienothiophene-Benzene co-Polymer Formed via Suzuki-Miyaura Cross-coupling

Hakan Bildirir*, Ipek Osken, Johannes Schmidt, Turan Ozturk, Arne Thomas

*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: Dergiye katkıMakalebilirkişi

7 Atıf (Scopus)

Özet

An electron rich conjugated microporous polymer (CMP) was prepared after reacting a dithienothiophene (DTT) derivative and benzene as co-monomers by Suzuki-Miyaura polycondensation. Gas sorption measurements revealed a Brunauer–Emmett–Teller (BET) surface area of 421 m2g−1 for the network. Its chemical oxidation was performed via iodine exposure, which is fully reversible with ammonia treatment resulting in a complete removal of the oxidants. This was observed in a decrease and recovery of the initial porosity due to reversible introduction and removal of iodide within the micropores, which could also be monitored by IR and UV/Vis absorption spectroscopy during the RedOx process.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)748-751
Sayfa sayısı4
DergiChemistrySelect
Hacim1
Basın numarası4
DOI'lar
Yayın durumuYayınlandı - Nis 2016

Bibliyografik not

Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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