BODIPY-ortho-carborane-tetraphenylethylene triad: synthesis, characterization, and properties

Ilgin Nar*, Armagan Atsay, Ali Buyruk, Hande Pekbelgin Karaoğlu, Ayfer Kalkan Burat, Esin Hamuryudan

*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: ???type-name???Makalebilirkişi

6 Atıf (Scopus)

Özet

Two new compounds, BODIPY-tetraphenylethylene dyad and BODIPY-o-carborane-tetraphenylethylene triad, were designed and synthesized. This molecular dyad and triad have been characterized by using various spectroscopic methods, including FT-IR, mass, UV-visible absorption and fluorescence emission spectroscopy, and one and two-dimensional homo- and hetero-correlated NMR spectroscopy. Photophysical properties, as well as solvatochromic and aggregation-induced emission (AIE) behavior, have been investigated. Single-crystal X-ray diffraction analysis has unambiguously revealed their structure and provides an explanation for the absence of AIE character. The redox properties showed that an o-carborane addition increased the reduction potential and shifted the oxidation potential to the positive site.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)4471-4476
Sayfa sayısı6
DergiNew Journal of Chemistry
Hacim43
Basın numarası11
DOI'lar
Yayın durumuYayınlandı - 2019

Bibliyografik not

Publisher Copyright:
© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

Finansman

This study was supported by the Research Fund of Istanbul Technical University.

FinansörlerFinansör numarası
Istanbul Teknik Üniversitesi

    Parmak izi

    BODIPY-ortho-carborane-tetraphenylethylene triad: synthesis, characterization, and properties' araştırma başlıklarına git. Birlikte benzersiz bir parmak izi oluştururlar.

    Alıntı Yap