Bisacylphosphine oxides as bifunctional photoinitiators for block copolymer synthesis

Erol D. Günersel; Yeşim Hepuzer; Yusuf Yaǧci

doi:10.1002/(SICI)1522-9505(19990201)264:1<88::AID-APMC88>3.0.CO;2-O

Bisacylphosphine oxides as bifunctional photoinitiators for block copolymer synthesis

Erol D. Günersel
, Yeşim Hepuzer
, Yusuf Yaǧci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

20 Atıf (Scopus)

Özet

Block copolymers of styrene (St) and methyl methacrylate (MMA) were prepared via a two-step procedure by using bisacylphosphine oxide (BAPO) as photoinitiator. Photolysis of BAPO at λ = 420 nm in the presence of St yielded polymers with monoacylphosphine oxide terminal groups. Subsequent irradiation of the polymers in the presence of MMA at λ = 380 nm produced block copolymers. Block copolymer formation was evidenced by spectral measurements and GPC analysis.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	88-91
Sayfa sayısı	4
Dergi	Angewandte Makromolekulare Chemie
Hacim	264
DOI'lar	https://doi.org/10.1002/(SICI)1522-9505(19990201)264:1<88::AID-APMC88>3.0.CO;2-O
Yayın durumu	Yayınlandı - Şub 1999

Belgeye Erişim

10.1002/(SICI)1522-9505(19990201)264:1<88::AID-APMC88>3.0.CO;2-O

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Bisacylphosphine oxides as bifunctional photoinitiators for block copolymer synthesis",

abstract = "Block copolymers of styrene (St) and methyl methacrylate (MMA) were prepared via a two-step procedure by using bisacylphosphine oxide (BAPO) as photoinitiator. Photolysis of BAPO at λ = 420 nm in the presence of St yielded polymers with monoacylphosphine oxide terminal groups. Subsequent irradiation of the polymers in the presence of MMA at λ = 380 nm produced block copolymers. Block copolymer formation was evidenced by spectral measurements and GPC analysis.",

author = "G{\"u}nersel, \{Erol D.\} and Ye{\c s}im Hepuzer and Yusuf Yaǧci",

year = "1999",

month = feb,

doi = "10.1002/(SICI)1522-9505(19990201)264:1<88::AID-APMC88>3.0.CO;2-O",

language = "English",

volume = "264",

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journal = "Angewandte Makromolekulare Chemie",

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TY - JOUR

T1 - Bisacylphosphine oxides as bifunctional photoinitiators for block copolymer synthesis

AU - Günersel, Erol D.

AU - Hepuzer, Yeşim

AU - Yaǧci, Yusuf

PY - 1999/2

Y1 - 1999/2

N2 - Block copolymers of styrene (St) and methyl methacrylate (MMA) were prepared via a two-step procedure by using bisacylphosphine oxide (BAPO) as photoinitiator. Photolysis of BAPO at λ = 420 nm in the presence of St yielded polymers with monoacylphosphine oxide terminal groups. Subsequent irradiation of the polymers in the presence of MMA at λ = 380 nm produced block copolymers. Block copolymer formation was evidenced by spectral measurements and GPC analysis.

AB - Block copolymers of styrene (St) and methyl methacrylate (MMA) were prepared via a two-step procedure by using bisacylphosphine oxide (BAPO) as photoinitiator. Photolysis of BAPO at λ = 420 nm in the presence of St yielded polymers with monoacylphosphine oxide terminal groups. Subsequent irradiation of the polymers in the presence of MMA at λ = 380 nm produced block copolymers. Block copolymer formation was evidenced by spectral measurements and GPC analysis.

UR - https://www.scopus.com/pages/publications/33646222922

U2 - 10.1002/(SICI)1522-9505(19990201)264:1<88::AID-APMC88>3.0.CO;2-O

DO - 10.1002/(SICI)1522-9505(19990201)264:1<88::AID-APMC88>3.0.CO;2-O

M3 - Article

AN - SCOPUS:33646222922

SN - 0003-3146

VL - 264

SP - 88

EP - 91

JO - Angewandte Makromolekulare Chemie

JF - Angewandte Makromolekulare Chemie

ER -

Bisacylphosphine oxides as bifunctional photoinitiators for block copolymer synthesis

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Belgeye Erişim

Diğer Dosyalar ve Linkler

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