An oxygen-tolerant visible light induced free radical polymerization using mesoporous graphitic carbon nitride

Kerem Kaya; Baris Kiskan; Baris Kumru; Bernhard V.K.J. Schmidt; Yusuf Yagci

doi:10.1016/j.eurpolymj.2019.109410

An oxygen-tolerant visible light induced free radical polymerization using mesoporous graphitic carbon nitride

Kerem Kaya, Baris Kiskan^*, Baris Kumru, Bernhard V.K.J. Schmidt, Yusuf Yagci

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Kimya Bölümü

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

30 Atıf (Scopus)

Özet

A novel oxygen-tolerant visible light photoinitiating system based on in-situ generation of Fenton reagents using mesoporous graphitic carbon nitride (mpg-C₃N₄) in conjunction with FeCl₃·6H₂O, water and oxygen for free radical polymerization is described. A mpg-C₃N₄-catalysed photoinduced electron transfer reactions of water/oxygen and Fe³⁺ were demonstrated to enable generation of hydroxyl radicals that are capable of initiating the polymerization of mono and bifunctional monomers. The efficiency of the photoinitiation is controlled by specific surface area of the carbon nitride. Apparently, non-porous carbon nitrides did not yield polymers under the given conditions. Due to its heterogeneous nature, after the polymerization, although at lower rate, separated mpg-C₃N₄ could be used for further polymerizations.

Orijinal dil	İngilizce
Makale numarası	109410
Dergi	European Polymer Journal
Hacim	122
DOI'lar	https://doi.org/10.1016/j.eurpolymj.2019.109410
Yayın durumu	Yayınlandı - 5 Oca 2020

Bibliyografik not

Publisher Copyright:
© 2019 Elsevier Ltd

Finansman

The authors B.Ki., K.K, and Y.Y thank to the Istanbul Technical University Research Fund for financial support. Y.Y also thanks Alexander von Humboldt Foundationfor financial support by means of Research Award. B.Ku. and B.S. thank the Max Society for financial support. Appendix A

Finansörler	Finansör numarası
Istanbul Technical University Research Fund
Max Society
Alexander von Humboldt-Stiftung

Belgeye Erişim

10.1016/j.eurpolymj.2019.109410

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{4c9525f51b224785a71b4b5e5e8e6e29,

title = "An oxygen-tolerant visible light induced free radical polymerization using mesoporous graphitic carbon nitride",

abstract = "A novel oxygen-tolerant visible light photoinitiating system based on in-situ generation of Fenton reagents using mesoporous graphitic carbon nitride (mpg-C3N4) in conjunction with FeCl3·6H2O, water and oxygen for free radical polymerization is described. A mpg-C3N4-catalysed photoinduced electron transfer reactions of water/oxygen and Fe3+ were demonstrated to enable generation of hydroxyl radicals that are capable of initiating the polymerization of mono and bifunctional monomers. The efficiency of the photoinitiation is controlled by specific surface area of the carbon nitride. Apparently, non-porous carbon nitrides did not yield polymers under the given conditions. Due to its heterogeneous nature, after the polymerization, although at lower rate, separated mpg-C3N4 could be used for further polymerizations.",

keywords = "Fenton reagent, Graphitic carbon nitride, Oxygen inhibition, Photopolymerization, Visible light",

author = "Kerem Kaya and Baris Kiskan and Baris Kumru and Schmidt, {Bernhard V.K.J.} and Yusuf Yagci",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2020",

month = jan,

day = "5",

doi = "10.1016/j.eurpolymj.2019.109410",

language = "English",

volume = "122",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - An oxygen-tolerant visible light induced free radical polymerization using mesoporous graphitic carbon nitride

AU - Kaya, Kerem

AU - Kiskan, Baris

AU - Kumru, Baris

AU - Schmidt, Bernhard V.K.J.

AU - Yagci, Yusuf

PY - 2020/1/5

Y1 - 2020/1/5

N2 - A novel oxygen-tolerant visible light photoinitiating system based on in-situ generation of Fenton reagents using mesoporous graphitic carbon nitride (mpg-C3N4) in conjunction with FeCl3·6H2O, water and oxygen for free radical polymerization is described. A mpg-C3N4-catalysed photoinduced electron transfer reactions of water/oxygen and Fe3+ were demonstrated to enable generation of hydroxyl radicals that are capable of initiating the polymerization of mono and bifunctional monomers. The efficiency of the photoinitiation is controlled by specific surface area of the carbon nitride. Apparently, non-porous carbon nitrides did not yield polymers under the given conditions. Due to its heterogeneous nature, after the polymerization, although at lower rate, separated mpg-C3N4 could be used for further polymerizations.

AB - A novel oxygen-tolerant visible light photoinitiating system based on in-situ generation of Fenton reagents using mesoporous graphitic carbon nitride (mpg-C3N4) in conjunction with FeCl3·6H2O, water and oxygen for free radical polymerization is described. A mpg-C3N4-catalysed photoinduced electron transfer reactions of water/oxygen and Fe3+ were demonstrated to enable generation of hydroxyl radicals that are capable of initiating the polymerization of mono and bifunctional monomers. The efficiency of the photoinitiation is controlled by specific surface area of the carbon nitride. Apparently, non-porous carbon nitrides did not yield polymers under the given conditions. Due to its heterogeneous nature, after the polymerization, although at lower rate, separated mpg-C3N4 could be used for further polymerizations.

KW - Fenton reagent

KW - Graphitic carbon nitride

KW - Oxygen inhibition

KW - Photopolymerization

KW - Visible light

UR - http://www.scopus.com/inward/record.url?scp=85076594524&partnerID=8YFLogxK

U2 - 10.1016/j.eurpolymj.2019.109410

DO - 10.1016/j.eurpolymj.2019.109410

M3 - Article

AN - SCOPUS:85076594524

SN - 0014-3057

VL - 122

JO - European Polymer Journal

JF - European Polymer Journal

M1 - 109410

ER -

An oxygen-tolerant visible light induced free radical polymerization using mesoporous graphitic carbon nitride

Özet

Bibliyografik not

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

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