Allyloxy isoquinolinium salts as initiators for cationic polymerization

Levent Atmaca; Aysen Onen; Yusuf Yagci

doi:10.1016/S0014-3057(00)00160-9

Allyloxy isoquinolinium salts as initiators for cationic polymerization

Levent Atmaca
, Aysen Onen
, Yusuf Yagci

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

14 Atıf (Scopus)

Özet

2-Propenyloxy isoquinolinium hexafluoroantimonate and 2-methyl-2-propenyloxy isoquinolinium hexafluoroantimonate were synthesized and characterized. Their capability to act as initiator and co-initiator for the cationic polymerization of cyclohexene oxide (CHO) was examined. Both thermally and photochemically latent effectiveness of these salts in promoting polymerization of CHO at 70 °C and λ = 350 nm, respectively was investigated. The accelerating effect of thermal and photochemical radical sources were also demonstrated. The contribution of electron transfer and addition-fragmentation mechanisms was discussed.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	677-682
Sayfa sayısı	6
Dergi	European Polymer Journal
Hacim	37
Basın numarası	4
DOI'lar	https://doi.org/10.1016/S0014-3057(00)00160-9
Yayın durumu	Yayınlandı - Nis 2001

Finansman

The authors would like to thank Ciba Specialty Chemicals Inc., Switzerland and Istanbul Technical University Research Fund for the financial support.

Finansörler
Ciba Specialty Chemicals Inc., Switzerland and Istanbul Technical University Research Fund

Belgeye Erişim

10.1016/S0014-3057(00)00160-9

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "Allyloxy isoquinolinium salts as initiators for cationic polymerization",

abstract = "2-Propenyloxy isoquinolinium hexafluoroantimonate and 2-methyl-2-propenyloxy isoquinolinium hexafluoroantimonate were synthesized and characterized. Their capability to act as initiator and co-initiator for the cationic polymerization of cyclohexene oxide (CHO) was examined. Both thermally and photochemically latent effectiveness of these salts in promoting polymerization of CHO at 70 °C and λ = 350 nm, respectively was investigated. The accelerating effect of thermal and photochemical radical sources were also demonstrated. The contribution of electron transfer and addition-fragmentation mechanisms was discussed.",

author = "Levent Atmaca and Aysen Onen and Yusuf Yagci",

year = "2001",

month = apr,

doi = "10.1016/S0014-3057(00)00160-9",

language = "English",

volume = "37",

pages = "677--682",

journal = "European Polymer Journal",

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TY - JOUR

T1 - Allyloxy isoquinolinium salts as initiators for cationic polymerization

AU - Atmaca, Levent

AU - Onen, Aysen

AU - Yagci, Yusuf

PY - 2001/4

Y1 - 2001/4

N2 - 2-Propenyloxy isoquinolinium hexafluoroantimonate and 2-methyl-2-propenyloxy isoquinolinium hexafluoroantimonate were synthesized and characterized. Their capability to act as initiator and co-initiator for the cationic polymerization of cyclohexene oxide (CHO) was examined. Both thermally and photochemically latent effectiveness of these salts in promoting polymerization of CHO at 70 °C and λ = 350 nm, respectively was investigated. The accelerating effect of thermal and photochemical radical sources were also demonstrated. The contribution of electron transfer and addition-fragmentation mechanisms was discussed.

AB - 2-Propenyloxy isoquinolinium hexafluoroantimonate and 2-methyl-2-propenyloxy isoquinolinium hexafluoroantimonate were synthesized and characterized. Their capability to act as initiator and co-initiator for the cationic polymerization of cyclohexene oxide (CHO) was examined. Both thermally and photochemically latent effectiveness of these salts in promoting polymerization of CHO at 70 °C and λ = 350 nm, respectively was investigated. The accelerating effect of thermal and photochemical radical sources were also demonstrated. The contribution of electron transfer and addition-fragmentation mechanisms was discussed.

UR - https://www.scopus.com/pages/publications/0035314247

U2 - 10.1016/S0014-3057(00)00160-9

DO - 10.1016/S0014-3057(00)00160-9

M3 - Article

AN - SCOPUS:0035314247

SN - 0014-3057

VL - 37

SP - 677

EP - 682

JO - European Polymer Journal

JF - European Polymer Journal

IS - 4

ER -

Allyloxy isoquinolinium salts as initiators for cationic polymerization

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap