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Advanced oxidation of a commercially important nonionic surfactant: Investigation of degradation products and toxicity

  • Akin Karci*
  • , Idil Arslan-Alaton
  • , Miray Bekbolet
  • *Bu çalışma için yazışmadan sorumlu yazar
  • Bogazici University

Araştırma çıktısı: Dergi yayınıMakaleHakem

52 Atıf (Scopus)

Özet

The evolution of degradation products and changes in acute toxicity during advanced oxidation of the nonionic surfactant nonylphenol decaethoxylate (NP-10) with the H2O2/UV-C and photo-Fenton processes were investigated. H2O2/UV-C and photo-Fenton processes ensured complete removal of NP-10, which was accompanied by the generation of polyethylene glycols with 3-8 ethoxy units. Formation of aldehydes and low carbon carboxylic acids was evidenced. According to the acute toxicity tests carried out with Vibrio fischeri, degradation products being more inhibitory than the original NP-10 solution were formed after the H2O2/UV-C process, whereas the photo-Fenton process appeared to be toxicologically safer since acute toxicity did not increase relative to the original NP-10 solution after treatment. Temporal evolution of the acute toxicity was strongly correlated with the identified carboxylic acids being formed during the application of H2O2/UV-C and photo-Fenton processes.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)275-282
Sayfa sayısı8
DergiJournal of Hazardous Materials
Hacim263
DOI'lar
Yayın durumuYayınlandı - 15 Ara 2013

Finansman

The financial support of the Scientific and Technological Research Council of Turkey (TUBITAK, Project No: 111Y145) is gratefully appreciated. Akin Karci kindly thanks Istanbul Technical University, Environmental Engineering Department for providing laboratory facilities.

FinansörlerFinansör numarası
TUBITAK111Y145
Türkiye Bilimsel ve Teknolojik Araştirma Kurumu

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