Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction

Buşra Bekar Yıldırmaz; Ayşegül Gölcü; Buse Tuğba Zaman; Nursu Aylin Kasa; Emine Gülhan Bakırdere; Sezgin Bakırdere

doi:10.1007/s11696-021-01652-5

Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction

Buşra Bekar Yıldırmaz
, Ayşegül Gölcü^*
, Buse Tuğba Zaman
, Nursu Aylin Kasa
, Emine Gülhan Bakırdere
, Sezgin Bakırdere^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University
Yildiz Technical University
Nun Schools
Turkish Academy of Sciences (TÜBA)

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

7 Atıf (Scopus)

Özet

A green supramolecular solvent-based liquid-phase microextraction (SUPRAs-LPME) strategy was developed and used for the preconcentration of iron in clove tea and tap water samples at trace levels. Complex formation occurred between the iron and a Schiff base ligand obtained from 5-bromosalicylaldehyde and o-phenylenediamine reaction, and the coordinate complex formed was extracted to supramolecular solvent phase. Limit of detection and quantification values was found as 4.3 and 14.2 μgL⁻¹, respectively, under the optimized conditions. When the analytical performance values obtained with SQT-FAAS, SUPRAs-LPME-FAAS and SUPRAs-LPME-SQT-FAAS are compared with FAAS, enhancements in detection power based on the LOD comparisons were calculated as 1.8, 31.4 and 65.8 times, respectively. The presented method was successfully applied to the determination of water-soluble iron in real clove tea in addition to tap water samples at trace levels, and the percent recoveries were obtained as 94.7–103.0% and 96.9–107.6%, respectively.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	4157-4164
Sayfa sayısı	8
Dergi	Chemical Papers
Hacim	75
Basın numarası	8
DOI'lar	https://doi.org/10.1007/s11696-021-01652-5
Yayın durumu	Yayınlandı - Ağu 2021

Bibliyografik not

Publisher Copyright:
© 2021, Institute of Chemistry, Slovak Academy of Sciences.

Belgeye Erişim

10.1007/s11696-021-01652-5

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Parmak izi

Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction' araştırma başlıklarına git. Birlikte benzersiz bir parmak izi oluştururlar.

Alıntı Yap

Yıldırmaz, B. B., Gölcü, A., Zaman, B. T., Kasa, N. A., Bakırdere, E. G., & Bakırdere, S. (2021). Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction. Chemical Papers, 75(8), 4157-4164. https://doi.org/10.1007/s11696-021-01652-5

Yıldırmaz, Buşra Bekar ; Gölcü, Ayşegül ; Zaman, Buse Tuğba et al. / Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction. In: Chemical Papers. 2021 ; Hac. 75, No. 8. pp. 4157-4164.

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title = "Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction",

abstract = "A green supramolecular solvent-based liquid-phase microextraction (SUPRAs-LPME) strategy was developed and used for the preconcentration of iron in clove tea and tap water samples at trace levels. Complex formation occurred between the iron and a Schiff base ligand obtained from 5-bromosalicylaldehyde and o-phenylenediamine reaction, and the coordinate complex formed was extracted to supramolecular solvent phase. Limit of detection and quantification values was found as 4.3 and 14.2 μgL−1, respectively, under the optimized conditions. When the analytical performance values obtained with SQT-FAAS, SUPRAs-LPME-FAAS and SUPRAs-LPME-SQT-FAAS are compared with FAAS, enhancements in detection power based on the LOD comparisons were calculated as 1.8, 31.4 and 65.8 times, respectively. The presented method was successfully applied to the determination of water-soluble iron in real clove tea in addition to tap water samples at trace levels, and the percent recoveries were obtained as 94.7–103.0\% and 96.9–107.6\%, respectively.",

keywords = "Clove tea, FAAS, Iron, SUPRA, Slotted quartz tube, Tap water",

author = "Yıldırmaz, \{Bu{\c s}ra Bekar\} and Ay{\c s}eg{\"u}l G{\"o}lc{\"u} and Zaman, \{Buse Tuğba\} and Kasa, \{Nursu Aylin\} and Bakırdere, \{Emine G{\"u}lhan\} and Sezgin Bakırdere",

note = "Publisher Copyright: {\textcopyright} 2021, Institute of Chemistry, Slovak Academy of Sciences.",

year = "2021",

month = aug,

doi = "10.1007/s11696-021-01652-5",

language = "English",

volume = "75",

pages = "4157--4164",

journal = "Chemical Papers",

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Yıldırmaz, BB, Gölcü, A, Zaman, BT, Kasa, NA, Bakırdere, EG & Bakırdere, S 2021, 'Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction', Chemical Papers, hac. 75, no. 8, pp. 4157-4164. https://doi.org/10.1007/s11696-021-01652-5

Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction. / Yıldırmaz, Buşra Bekar; Gölcü, Ayşegül; Zaman, Buse Tuğba et al.
In: Chemical Papers, Hac. 75, No. 8, 08.2021, p. 4157-4164.

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

TY - JOUR

T1 - Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction

AU - Yıldırmaz, Buşra Bekar

AU - Gölcü, Ayşegül

AU - Zaman, Buse Tuğba

AU - Kasa, Nursu Aylin

AU - Bakırdere, Emine Gülhan

AU - Bakırdere, Sezgin

PY - 2021/8

Y1 - 2021/8

N2 - A green supramolecular solvent-based liquid-phase microextraction (SUPRAs-LPME) strategy was developed and used for the preconcentration of iron in clove tea and tap water samples at trace levels. Complex formation occurred between the iron and a Schiff base ligand obtained from 5-bromosalicylaldehyde and o-phenylenediamine reaction, and the coordinate complex formed was extracted to supramolecular solvent phase. Limit of detection and quantification values was found as 4.3 and 14.2 μgL−1, respectively, under the optimized conditions. When the analytical performance values obtained with SQT-FAAS, SUPRAs-LPME-FAAS and SUPRAs-LPME-SQT-FAAS are compared with FAAS, enhancements in detection power based on the LOD comparisons were calculated as 1.8, 31.4 and 65.8 times, respectively. The presented method was successfully applied to the determination of water-soluble iron in real clove tea in addition to tap water samples at trace levels, and the percent recoveries were obtained as 94.7–103.0% and 96.9–107.6%, respectively.

AB - A green supramolecular solvent-based liquid-phase microextraction (SUPRAs-LPME) strategy was developed and used for the preconcentration of iron in clove tea and tap water samples at trace levels. Complex formation occurred between the iron and a Schiff base ligand obtained from 5-bromosalicylaldehyde and o-phenylenediamine reaction, and the coordinate complex formed was extracted to supramolecular solvent phase. Limit of detection and quantification values was found as 4.3 and 14.2 μgL−1, respectively, under the optimized conditions. When the analytical performance values obtained with SQT-FAAS, SUPRAs-LPME-FAAS and SUPRAs-LPME-SQT-FAAS are compared with FAAS, enhancements in detection power based on the LOD comparisons were calculated as 1.8, 31.4 and 65.8 times, respectively. The presented method was successfully applied to the determination of water-soluble iron in real clove tea in addition to tap water samples at trace levels, and the percent recoveries were obtained as 94.7–103.0% and 96.9–107.6%, respectively.

KW - Clove tea

KW - FAAS

KW - Iron

KW - SUPRA

KW - Slotted quartz tube

KW - Tap water

UR - https://www.scopus.com/pages/publications/85104703200

U2 - 10.1007/s11696-021-01652-5

DO - 10.1007/s11696-021-01652-5

M3 - Article

AN - SCOPUS:85104703200

SN - 0366-6352

VL - 75

SP - 4157

EP - 4164

JO - Chemical Papers

JF - Chemical Papers

IS - 8

ER -

Yıldırmaz BB, Gölcü A, Zaman BT, Kasa NA, Bakırdere EG, Bakırdere S. Accurate and sensitive analytical method for trace iron determination in clove tea and tap water samples by slotted quartz tube-flame atomic absorption spectrometry after its preconcentration with supramolecular solvent-based liquid-phase microextraction. Chemical Papers. 2021 Ağu;75(8):4157-4164. doi: 10.1007/s11696-021-01652-5