A Theoretical study on Rh(I) catalyzed enantioselective conjugate addition reactions of fluoroalkylated olefins

Keyphrases

• Benzene 100%
• Olefins 100%
• Enantioselective Conjugate Addition 100%
• Electronic Effect 100%
• Rh(I)-catalyzed 100%
• Conjugate Addition Reaction 100%
• Ortho 66%
• Energy Difference 66%
• R-enantiomer 66%
• Steric Effect 66%
• Phenyl 33%
• High Energy 33%
• Reaction Mechanism 33%
• Toluene 33%
• Activation Energy 33%
• Quantum Mechanical Calculations 33%
• B3LYP/6-31G 33%
• Benchmark Calculations 33%
• Energy Barrier 33%
• Substituted Phenyl 33%
• Steric Effect of Substituents 33%
• Enantioselectivity 33%
• Electron-deficient 33%
• Rhodium Catalysis 33%
• 1,4-conjugate Addition Reaction 33%
• Product Formation 33%
• P-atom 33%
• Conjugate Addition 33%
• Cl Atoms 33%
• Phenyl Group 33%
• Para-position 33%
• Effective Core Potential 33%
• Aryl Groups 33%
• LANL2DZ 33%
• BINAP 33%
• High Activation Energy 33%

Chemistry

• Alkene 100%
• Addition Reaction 100%
• electronics 100%
• Benzene 100%
• Reaction Activation Energy 66%
• Steric Effect 66%
• DFT-B3LYP Calculation 33%
• Energy Barrier 33%
• Aryl Group 33%
• Rhodium 33%
• Phenyl Group 33%
• R Isomer 33%
• Enantioselectivity 33%
• formation 33%
• Enantiomer 33%

Chemical Engineering

• Olefin 100%