A polymerized vinylene carbonate anode binder enhances performance of lithium-ion batteries

Hui Zhao; Xin Zhou; Sang Jae Park; Feifei Shi; Yanbao Fu; Min Ling; Neslihan Yuca; Vincent Battaglia; Gao Liu

doi:10.1016/j.jpowsour.2014.04.063

A polymerized vinylene carbonate anode binder enhances performance of lithium-ion batteries

Hui Zhao, Xin Zhou, Sang Jae Park, Feifei Shi, Yanbao Fu, Min Ling, Neslihan Yuca, Vincent Battaglia, Gao Liu^*

^*Bu çalışma için yazışmadan sorumlu yazar

Araştırma sonucu: ???type-name??? › Makale › bilirkişi

23 Atıf (Scopus)

Özet

We investigated the use of polymerized vinylene carbonate (polyVC) as a binder for graphite anodes in lithium-ion cells. It functions not only of a traditional binder, but also plays an important role in surface stabilization of graphite in propylene carbonate (PC)-based electrolytes. In an electrolyte with PC content as high as 30 wt%, the polyVC binder enhanced battery performance, with a reversible capacity of ∼170 mAh g^-1 at a delithiation rate of 1 C, whereas a comparable graphite cell fabricated with a polyvinylidene fluoride (PVDF) binder failed to cycle.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	288-295
Sayfa sayısı	8
Dergi	Journal of Power Sources
Hacim	263
DOI'lar	https://doi.org/10.1016/j.jpowsour.2014.04.063
Yayın durumu	Yayınlandı - 1 Eki 2014
Harici olarak yayınlandı	Evet

Finansman

This work is funded by the Assistant Secretary for Energy Efficiency , Vehicle Technologies Office of the U.S. Department of Energy , under the Batteries for Advanced Transportation Technologies (BATT) and Applied Battery Research (ABR) Program. NMR measurements were performed at the Molecular Foundry. Electron microscopy experiments were conducted at the National Center for Electron Microscopy (NCEM). The two facilities are located at Lawrence Berkeley National Laboratory (LBNL), and are supported by the Director, Office of Science, Office of Basic Energy Sciences, of the US Department of Energy under contract no. DE-AC02-05CH11231 .

Finansörler	Finansör numarası
Batteries for Advanced Transportation Technologies
Office of Basic Energy Sciences
US Department of Energy
U.S. Department of Energy
Office of Science

BM SKH

Bu sonuç, aşağıdaki Sürdürülebilir Kalkınma Hedefine/Hedeflerine katkıda bulunur

Belgeye Erişim

10.1016/j.jpowsour.2014.04.063

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Link to publication in Scopus

Alıntı Yap

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title = "A polymerized vinylene carbonate anode binder enhances performance of lithium-ion batteries",

abstract = "We investigated the use of polymerized vinylene carbonate (polyVC) as a binder for graphite anodes in lithium-ion cells. It functions not only of a traditional binder, but also plays an important role in surface stabilization of graphite in propylene carbonate (PC)-based electrolytes. In an electrolyte with PC content as high as 30 wt%, the polyVC binder enhanced battery performance, with a reversible capacity of ∼170 mAh g-1 at a delithiation rate of 1 C, whereas a comparable graphite cell fabricated with a polyvinylidene fluoride (PVDF) binder failed to cycle.",

keywords = "Graphite exfoliation, Lithium-ion battery, Solid electrolyte interphase (SEI), Vinylene carbonate",

author = "Hui Zhao and Xin Zhou and Park, {Sang Jae} and Feifei Shi and Yanbao Fu and Min Ling and Neslihan Yuca and Vincent Battaglia and Gao Liu",

year = "2014",

month = oct,

day = "1",

doi = "10.1016/j.jpowsour.2014.04.063",

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T1 - A polymerized vinylene carbonate anode binder enhances performance of lithium-ion batteries

AU - Zhao, Hui

AU - Zhou, Xin

AU - Park, Sang Jae

AU - Shi, Feifei

AU - Fu, Yanbao

AU - Ling, Min

AU - Yuca, Neslihan

AU - Battaglia, Vincent

AU - Liu, Gao

PY - 2014/10/1

Y1 - 2014/10/1

N2 - We investigated the use of polymerized vinylene carbonate (polyVC) as a binder for graphite anodes in lithium-ion cells. It functions not only of a traditional binder, but also plays an important role in surface stabilization of graphite in propylene carbonate (PC)-based electrolytes. In an electrolyte with PC content as high as 30 wt%, the polyVC binder enhanced battery performance, with a reversible capacity of ∼170 mAh g-1 at a delithiation rate of 1 C, whereas a comparable graphite cell fabricated with a polyvinylidene fluoride (PVDF) binder failed to cycle.

AB - We investigated the use of polymerized vinylene carbonate (polyVC) as a binder for graphite anodes in lithium-ion cells. It functions not only of a traditional binder, but also plays an important role in surface stabilization of graphite in propylene carbonate (PC)-based electrolytes. In an electrolyte with PC content as high as 30 wt%, the polyVC binder enhanced battery performance, with a reversible capacity of ∼170 mAh g-1 at a delithiation rate of 1 C, whereas a comparable graphite cell fabricated with a polyvinylidene fluoride (PVDF) binder failed to cycle.

KW - Graphite exfoliation

KW - Lithium-ion battery

KW - Solid electrolyte interphase (SEI)

KW - Vinylene carbonate

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DO - 10.1016/j.jpowsour.2014.04.063

M3 - Article

AN - SCOPUS:84899861091

SN - 0378-7753

VL - 263

SP - 288

EP - 295

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -

A polymerized vinylene carbonate anode binder enhances performance of lithium-ion batteries

Özet

Finansman

BM SKH

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap