A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

Mehmet Kandaz; Seher Zerrin Çoruhlu; Ismail Yilmaz; Ali Riza Özkaya

doi:10.1023/A:1021359012365

A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

Mehmet Kandaz^*
, Seher Zerrin Çoruhlu
, Ismail Yilmaz
, Ali Riza Özkaya

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Sakarya University
Marmara University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

30 Atıf (Scopus)

Özet

A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of Ni^II, Cu^II, Co^II and Fe^II have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and tri-nuclear complexes was achieved with U^IVO₂ and Cu^II depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, ¹H-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	877-883
Sayfa sayısı	7
Dergi	Transition Metal Chemistry
Hacim	27
Basın numarası	8
DOI'lar	https://doi.org/10.1023/A:1021359012365
Yayın durumu	Yayınlandı - Kas 2002

Finansman

We thank the Research Fund of Sakarya University (Project no: 2000-013) and the Technical University of Istanbul for financial Support (project no: 1404).

Finansörler	Finansör numarası
Istanbul Teknik Üniversitesi	1404

Belgeye Erişim

10.1023/A:1021359012365

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Parmak izi

A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes' araştırma başlıklarına git. Birlikte benzersiz bir parmak izi oluştururlar.

Alıntı Yap

Kandaz, M., Çoruhlu, S. Z., Yilmaz, I., & Özkaya, A. R. (2002). A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes. Transition Metal Chemistry, 27(8), 877-883. https://doi.org/10.1023/A:1021359012365

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title = "A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes",

abstract = "A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of NiII, CuII, CoII and FeII have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and tri-nuclear complexes was achieved with UIVO2 and CuII depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, 1H-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.",

author = "Mehmet Kandaz and {\c C}oruhlu, \{Seher Zerrin\} and Ismail Yilmaz and {\"O}zkaya, \{Ali Riza\}",

year = "2002",

month = nov,

doi = "10.1023/A:1021359012365",

language = "English",

volume = "27",

pages = "877--883",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

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number = "8",

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Kandaz, M, Çoruhlu, SZ, Yilmaz, I & Özkaya, AR 2002, 'A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes', Transition Metal Chemistry, hac. 27, no. 8, pp. 877-883. https://doi.org/10.1023/A:1021359012365

A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes. / Kandaz, Mehmet; Çoruhlu, Seher Zerrin; Yilmaz, Ismail et al.
In: Transition Metal Chemistry, Hac. 27, No. 8, 11.2002, p. 877-883.

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

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T1 - A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

AU - Kandaz, Mehmet

AU - Çoruhlu, Seher Zerrin

AU - Yilmaz, Ismail

AU - Özkaya, Ali Riza

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AB - A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E,E′)-dichloroglyoxime. Mononuclear transition metal complexes of NiII, CuII, CoII and FeII have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and tri-nuclear complexes was achieved with UIVO2 and CuII depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, 1H-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.

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