A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization

Yusuf Yagci; Suat Yildirim; Aysen Onen

doi:10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2

A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization

Yusuf Yagci^*
, Suat Yildirim
, Aysen Onen

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

21 Atıf (Scopus)

Özet

A novel addition-fragmentation agent (AFA), namely, 2-benzyl-2-(N,N-dimethyl-2-ethoxycarbonyl-1-propenyl) ammonium hexaflouroantimonate-1-(4-morpholinophenyl)-butane-1-one, for photoinitiated cationic polymerization was synthesized and characterized. With this compound, it is possible to initiate the cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinylcarbazole (NVC) photochemically at λ = 380 nm. The mechanism involves the formation of radicals from the alkylphenone moiety and the addition of these radicals to the allylic site and fragmentation of the AFA.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	527-531
Sayfa sayısı	5
Dergi	Macromolecular Chemistry and Physics
Hacim	202
Basın numarası	4
DOI'lar	https://doi.org/10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2
Yayın durumu	Yayınlandı - 28 Şub 2001

Belgeye Erişim

10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

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title = "A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization",

abstract = "A novel addition-fragmentation agent (AFA), namely, 2-benzyl-2-(N,N-dimethyl-2-ethoxycarbonyl-1-propenyl) ammonium hexaflouroantimonate-1-(4-morpholinophenyl)-butane-1-one, for photoinitiated cationic polymerization was synthesized and characterized. With this compound, it is possible to initiate the cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinylcarbazole (NVC) photochemically at λ = 380 nm. The mechanism involves the formation of radicals from the alkylphenone moiety and the addition of these radicals to the allylic site and fragmentation of the AFA.",

author = "Yusuf Yagci and Suat Yildirim and Aysen Onen",

year = "2001",

month = feb,

day = "28",

doi = "10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2",

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TY - JOUR

T1 - A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization

AU - Yagci, Yusuf

AU - Yildirim, Suat

AU - Onen, Aysen

PY - 2001/2/28

Y1 - 2001/2/28

N2 - A novel addition-fragmentation agent (AFA), namely, 2-benzyl-2-(N,N-dimethyl-2-ethoxycarbonyl-1-propenyl) ammonium hexaflouroantimonate-1-(4-morpholinophenyl)-butane-1-one, for photoinitiated cationic polymerization was synthesized and characterized. With this compound, it is possible to initiate the cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinylcarbazole (NVC) photochemically at λ = 380 nm. The mechanism involves the formation of radicals from the alkylphenone moiety and the addition of these radicals to the allylic site and fragmentation of the AFA.

AB - A novel addition-fragmentation agent (AFA), namely, 2-benzyl-2-(N,N-dimethyl-2-ethoxycarbonyl-1-propenyl) ammonium hexaflouroantimonate-1-(4-morpholinophenyl)-butane-1-one, for photoinitiated cationic polymerization was synthesized and characterized. With this compound, it is possible to initiate the cationic polymerization of cyclohexene oxide (CHO), butyl vinyl ether (BVE) and N-vinylcarbazole (NVC) photochemically at λ = 380 nm. The mechanism involves the formation of radicals from the alkylphenone moiety and the addition of these radicals to the allylic site and fragmentation of the AFA.

UR - https://www.scopus.com/pages/publications/0035961826

U2 - 10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2

DO - 10.1002/1521-3935(20010201)202:4<527::AID-MACP527>3.0.CO;2-2

M3 - Article

AN - SCOPUS:0035961826

SN - 1022-1352

VL - 202

SP - 527

EP - 531

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

IS - 4

ER -

A novel bifunctional addition-fragmentation agent for photoinitiated cationic polymerization

Özet

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

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