A novel benzoxazine monomer with methacrylate functionality and its thermally curable (co)polymers

Banu Koz; Baris Kiskan; Yusuf Yagci

doi:10.1007/s00289-010-0261-6

A novel benzoxazine monomer with methacrylate functionality and its thermally curable (co)polymers

Banu Koz
, Baris Kiskan
, Yusuf Yagci^*

^*Bu çalışma için yazışmadan sorumlu yazar

Kimya Bölümü

Istanbul Technical University

Araştırma çıktısı: Dergi yayını › Makale › Hakem

67 Atıf (Scopus)

Özet

Benzoxazine monomer with methacrylate functionality, namely 2-(2-(2H-benzo[e][1,3]oxazin-3(4H)-yl)ethoxy) ethyl methacrylate (BEM) was synthesized by simple esterification reaction of hydroxyl containing benzoxazine (B-OH) with methacryloyl chloride, and characterized. BEM was then copolymerized with styrene in 1:4 mol ratio by free radical polymerization using 2,2′-azobis(isobutyronitrile) (AIBN) as initiator. The structure, chemical composition, and molecular weight characteristics of the resulting copolymer were confirmed by FT-IR, ¹H-NMR spectroscopy, and GPC, respectively. The curing behavior and thermal properties of both monomer and copolymer were also studied by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA).

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	165-174
Sayfa sayısı	10
Dergi	Polymer Bulletin
Hacim	66
Basın numarası	2
DOI'lar	https://doi.org/10.1007/s00289-010-0261-6
Yayın durumu	Yayınlandı - Oca 2011

Finansman

The authors thank Henkel AG and Co. KGaA for partial financial support.

Belgeye Erişim

10.1007/s00289-010-0261-6

Diğer Dosyalar ve Linkler

Link to publication in Scopus

Alıntı Yap

@article{006ae67c14ce473f90012274bc312866,

title = "A novel benzoxazine monomer with methacrylate functionality and its thermally curable (co)polymers",

abstract = "Benzoxazine monomer with methacrylate functionality, namely 2-(2-(2H-benzo[e][1,3]oxazin-3(4H)-yl)ethoxy) ethyl methacrylate (BEM) was synthesized by simple esterification reaction of hydroxyl containing benzoxazine (B-OH) with methacryloyl chloride, and characterized. BEM was then copolymerized with styrene in 1:4 mol ratio by free radical polymerization using 2,2′-azobis(isobutyronitrile) (AIBN) as initiator. The structure, chemical composition, and molecular weight characteristics of the resulting copolymer were confirmed by FT-IR, 1H-NMR spectroscopy, and GPC, respectively. The curing behavior and thermal properties of both monomer and copolymer were also studied by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA).",

keywords = "Benzoxazine, Copolymer, Methacrylate, Polybenzoxazine, Thermal curing, Thermoset",

author = "Banu Koz and Baris Kiskan and Yusuf Yagci",

year = "2011",

month = jan,

doi = "10.1007/s00289-010-0261-6",

language = "English",

volume = "66",

pages = "165--174",

journal = "Polymer Bulletin",

issn = "0170-0839",

publisher = "Springer Verlag",

number = "2",

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TY - JOUR

T1 - A novel benzoxazine monomer with methacrylate functionality and its thermally curable (co)polymers

AU - Koz, Banu

AU - Kiskan, Baris

AU - Yagci, Yusuf

PY - 2011/1

Y1 - 2011/1

N2 - Benzoxazine monomer with methacrylate functionality, namely 2-(2-(2H-benzo[e][1,3]oxazin-3(4H)-yl)ethoxy) ethyl methacrylate (BEM) was synthesized by simple esterification reaction of hydroxyl containing benzoxazine (B-OH) with methacryloyl chloride, and characterized. BEM was then copolymerized with styrene in 1:4 mol ratio by free radical polymerization using 2,2′-azobis(isobutyronitrile) (AIBN) as initiator. The structure, chemical composition, and molecular weight characteristics of the resulting copolymer were confirmed by FT-IR, 1H-NMR spectroscopy, and GPC, respectively. The curing behavior and thermal properties of both monomer and copolymer were also studied by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA).

AB - Benzoxazine monomer with methacrylate functionality, namely 2-(2-(2H-benzo[e][1,3]oxazin-3(4H)-yl)ethoxy) ethyl methacrylate (BEM) was synthesized by simple esterification reaction of hydroxyl containing benzoxazine (B-OH) with methacryloyl chloride, and characterized. BEM was then copolymerized with styrene in 1:4 mol ratio by free radical polymerization using 2,2′-azobis(isobutyronitrile) (AIBN) as initiator. The structure, chemical composition, and molecular weight characteristics of the resulting copolymer were confirmed by FT-IR, 1H-NMR spectroscopy, and GPC, respectively. The curing behavior and thermal properties of both monomer and copolymer were also studied by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA).

KW - Benzoxazine

KW - Copolymer

KW - Methacrylate

KW - Polybenzoxazine

KW - Thermal curing

KW - Thermoset

UR - https://www.scopus.com/pages/publications/79751535835

U2 - 10.1007/s00289-010-0261-6

DO - 10.1007/s00289-010-0261-6

M3 - Article

AN - SCOPUS:79751535835

SN - 0170-0839

VL - 66

SP - 165

EP - 174

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 2

ER -

A novel benzoxazine monomer with methacrylate functionality and its thermally curable (co)polymers

Özet

Finansman

Belgeye Erişim

Diğer Dosyalar ve Linkler

Parmak izi

Alıntı Yap